中文
相关论文

相关论文: A flexible multi-reference perturbation theory by …

200 篇论文

Operating just once the naive Foldy-Wouthuysen-Tani transformation on the Schr\"odinger equation for $Q\bar q$ bound states described by a hamiltonian, we systematically develop a perturbation theory in $1/m_Q$ which enables one to solve…

高能物理 - 唯象学 · 物理学 2015-06-25 Takayuki Matsuki

We revisit the extraction of $\alpha_s(M_\tau^2)$ from the QCDperturbative corrections to the hadronic $\tau$ branching ratio, using an improved fixed-order perturbation theory based on the explicit summation of all renormalization-group…

高能物理 - 唯象学 · 物理学 2012-05-22 Gauhar Abbas , B. Ananthanarayan , Irinel Caprini

We explore the possibility of calculating electronic excited states by using perturbation theory along a range-separated adiabatic connection. Starting from the energies of a partially interacting Hamiltonian, a first-order correction is…

化学物理 · 物理学 2014-12-15 Elisa Rebolini , Julien Toulouse , Andrew M. Teale , Trygve Helgaker , Andreas Savin

A finite-temperature many-body perturbation theory is presented that expands in power series the electronic grand potential, chemical potential, internal energy, and entropy on an equal footing. Sum-over-states and sum-over-orbitals…

化学物理 · 物理学 2020-07-15 So Hirata , Punit K. Jha

The perturbative expansion introduced by Zwanzig [R. W. Zwanzig, J. Chem. Phys. {\bf 22}, 1420 (1954)] expresses the difference in Helmholtz free energy between a system of interest and that of a reference system as series of cumulants…

计算物理 · 物理学 2020-10-01 C. W. Greeff

The concept of Dyall zeroth-order Hamiltonian [Dyall, K. G. J. Chem. Phys., 102, 4909-4918 (1995)] has been instrumental in the development of intruder- and parameter-free multireference perturbation theories for the efficient treatment of…

化学物理 · 物理学 2024-11-19 Alexander Yu. Sokolov

Third-order approximate solutions for surface gravity waves in the finite water depth are studied in the context of potential flow theory. This solution provides explicit expressions for the surface elevation, free-surface velocity…

流体动力学 · 物理学 2021-09-15 Zhe Gao , Z. C Sun , S. X Liang

A diagrammatic multi-reference generalization of many-body perturbation theory was recently introduced [J. Phys. Chem. Lett., 2025, 16, 3047]. This framework allows us to extend single-reference (SR) Green's function methods defined at the…

量子物理 · 物理学 2025-07-29 Yuqi Wang , Wei-Hai Fang , Zhendong Li

Second-order M{\o}ller-Plesset perturbation theory (MP2) often breaks down catastrophically in small-gap systems, leaving much to be desired in its performance for myriad chemical applications such as noncovalent interactions,…

化学物理 · 物理学 2023-07-05 Kevin Carter-Fenk , Martin Head-Gordon

The practical utility of M{\o}ller-Plesset (MP) perturbation theory is severely constrained by the use of Hartree-Fock (HF) orbitals. It has recently been shown that use of regularized orbital-optimized MP2 orbitals and scaling of MP3…

化学物理 · 物理学 2021-01-06 Adam Rettig , Diptarka Hait , Luke W. Bertels , Martin Head-Gordon

Relativistic third-order MBPT is applied to obtain energies of ions with two valence electrons in the no virtual-pair approximation (NVPA). A total of 302 third-order Goldstone diagrams are organized into 12 one-body and 23 two-body terms.…

原子物理 · 物理学 2009-11-11 H. C. Ho , W. R. Johnson , S. A. Blundell , M. S. Safronova

Quantum chemical methods dealing with challenging systems while retaining low computational costs have attracted attention. In particular, many efforts have been devoted to developing new methods based on the second-order perturbation that…

化学物理 · 物理学 2023-10-30 Nhan Tri Tran , Hoang Thanh Nguyen , Lan Nguyen Tran

To first order in the deviation from scale invariance the inflationary potential and its first two derivatives can be expressed in terms of the spectral indices of the scalar and tensor perturbations, $n$ and $n_T$, and their contributions…

天体物理学 · 物理学 2014-10-13 Andrew R Liddle , Michael S Turner

Based on the external perturbation that disturbs the system only slightly from its equilibrium position we make the Taylor expansion of the pressure of a quark gas. It turns out that the first term was used in the literature to construct a…

高能物理 - 唯象学 · 物理学 2011-09-19 Najmul Haque , Munshi G. Mustafa

Despite its simplicity and relatively low computational cost, second-order M{\o}ller-Plesset perturbation theory (MP2) is well-known to overbind noncovalent interactions between polarizable monomers and some organometallic bonds. In such…

化学物理 · 物理学 2023-11-09 Kevin Carter-Fenk , James Shee , Martin Head-Gordon

A precise calculation of the ground-state energy of the complex PT-symmetric Hamiltonian $H=p^2+{1/4}x^2+i \lambda x^3$, is performed using high-order Rayleigh-Schr\"odinger perturbation theory. The energy spectrum of this Hamiltonian has…

量子物理 · 物理学 2009-10-31 Carl M. Bender , Gerald V. Dunne

We study the Hamiltonian truncation for the two-dimensional $\lambda\phi^4$ theory within the framework of Hamiltonian truncation effective theory, where truncation artifacts are mitigated through a systematic inclusion of corrective terms…

高能物理 - 唯象学 · 物理学 2026-02-16 Andrea Maestri , Simone Rodini , Barbara Pasquini

The idea of adaptive perturbation theory is to divide a Hamiltonian into a solvable part and a perturbation part. The solvable part contains the non-interacting sector and the diagonal elements of Fock space from the interacting terms. The…

量子物理 · 物理学 2021-06-14 Xin Guo

The similarities between Hartree-Fock (HF) theory and the density-matrix renormalization group (DMRG) are explored. Both methods can be formulated as the variational optimization of a wave-function ansatz. Linearization of the…

强关联电子 · 物理学 2013-08-13 Sebastian Wouters , Naoki Nakatani , Dimitri Van Neck , Garnet Kin-Lic Chan

The second-order formula of Minkowski functionals in weakly non-Gaussian fields is compared with the numerical $N$-body simulations. Recently, weakly non-Gaussian formula of Minkowski functionals is extended to include the second-order…

宇宙学与河外天体物理 · 物理学 2020-12-03 Takahiko Matsubara , Chiaki Hikage , Satoshi Kuriki