相关论文: Clausius vs. Boltzmann-Gibbs entropies
We prove the Gibbs variational formula in terms of quantum relative entropy density that characterizes translation invariant thermal equilibrium states in quantum lattice systems. It is a natural quantum extension of the similar statement…
Gibbsian statistical mechanics is extended into the domain of non-negligible {though non-specified} correlations in phase space while respecting the fundamental laws of thermodynamics. The appropriate Gibbsian probability distribution is…
In ordinary Boltzmann-Gibbs thermostatistics, the relative entropy expression plays the role of generalized free energy, providing the difference between the off-equilibrium and equilibrium free energy terms associated with Boltzmann-Gibbs…
We consider the homogeneous mean-field Bose gas at temperatures proportional to the critical temperature of its Bose-Einstein condensation phase transition. We prove a trace norm approximation for the grand canonical Gibbs state in terms of…
The second law of thermodynamics is a fundamental law of Nature. It is almost universally associated with the Clausius inequality that lower bounds a change in entropy by the ratio of supplied heat and temperature. However, this result…
Previous results on Renyi and Wang's formalism of the Tsallis thermostatics are founded by using an extensive variable z connected to the entropic parameter q. It is shown that in the thermodynamical limit both the Tsallis and Renyi…
We consider a boson gas on the stretched horizon of the Schwartzschild and Kerr black holes. It is shown that the gas is in a Bose-Einstein condensed state with the Hawking temperature $T_c=T_H$ if the particle number of the system be equal…
It was recently published by M. Nauenberg [1] a quite long list of objections about the physical validity for thermal statistics of the theory sometimes referred to in the literature as {\it nonextensive statistical mechanics}. This…
The statistical mechanics of self-gravitating systems has not been well understood, and still remains an open question so far. In a previous study by Kang & He, we showed that the fluid approximation may give a clue to further investigate…
It is by now well known that the Boltzmann-Gibbs (BG) entropy $S_{BG}=-k\sum_{i=1}^W p_i \ln p_i$ can be usefully generalized into the entropy $S_q=k (1-\sum_{i=1}^Wp_i^{q}) / (q-1)$ ($q\in \mathcal{R}; S_1=S_{BG}$). Microscopic dynamics…
Microcanonical thermodynamics allows the application of statistical mechanics both to finite and even small systems and also to the largest, self-gravitating ones. However, one must reconsider the fundamental principles of statistical…
As well known, Boltzmann-Gibbs statistics is the correct way of thermostatistically approaching ergodic systems. On the other hand, nontrivial ergodicity breakdown and strong correlations typically drag the system into out-of-equilibrium…
The issue of the Gibbs paradox is that when considering mixing of two gases within classical thermodynamics, the entropy of mixing appears to be a discontinuous function of the difference between the gases: it is finite for whatever small…
The article reveals the error that in classical thermodynamics leads to the Gibbs paradox. The essence of the error lies in the fact that the entropy of an ideal gas is attributed to additive quantities, but it is not correct. The value of…
Generalization through novel interpretations of the inner logic of the century-old Gibbs' statistical thermodynamics is presented: i) Identifying $k_B\to 0$ as classical energetics, one directly derives a pair of thermodynamic variational…
The Gibbs paradox of the first kind (GP1) refers to the false increase in entropy which, in statistical mechanics, is calculated from the process of combining two gas systems S1 and S2 consisting of distinguishable particles. Presented in a…
Boltzmann defined the entropy of a macroscopic system in a macrostate $M$ as the $\log$ of the volume of phase space (number of microstates) corresponding to $M$. This agrees with the thermodynamic entropy of Clausius when $M$ specifies the…
A generalized entropy arising in the context of superstatistics is obtained for an ideal gas. The curvature scalar associated to the thermodynamic space generated by this modified entropy is calculated using two formalisms of the geometric…
Boltzmann's principle S(E,N,V)=k\ln W relates the entropy to the geometric area e^{S(E,N,V)} of the manifold of constant energy in the N-body phase space. From the principle all thermodynamics and especially all phenomena of phase…
The cornerstone of Boltzmann-Gibbs ($BG$) statistical mechanics is the Boltzmann-Gibbs-Jaynes-Shannon entropy $S_{BG} \equiv -k\int dx f(x)\ln f(x)$, where $k$ is a positive constant and $f(x)$ a probability density function. This theory…