相关论文: Clausius vs. Boltzmann-Gibbs entropies
Based on the property of extensivity (mathematically, homogeneity of first degree), we derive in a mathematically consistent manner the explicit expressions of the chemical potential $\mu$ and the Clausius entropy $S$ for the case of…
The Boltzmann-Gibbs density, a central result of equilibrium statistical mechanics, relates the energy of a system in contact with a thermal bath to its equilibrium statistics. This relation is lost for non-thermal systems such as cold…
We consider an isolated system in an arbitrary state and provide a general formulation using first principles for an additive and non-negative statistical quantity that is shown to reproduce the equilibrium thermodynamic entropy of the…
We consider a situation where an $N$-level system (NLS) is coupled to a heat bath without being necessarily thermalized. For this situation we derive general Jarzinski-type equations and conclude that heat and entropy is flowing from the…
Small systems consisting of a few particles are increasingly technologically relevant. In such systems, an intense debate in microcanonical statistical mechanics has been about the correctness of Boltzmann's surface entropy versus Gibbs'…
The long standing contrast between Boltzmann's and Gibbs' approach to statistical thermodynamics has been recently rekindled by Dunkel and Hilbert [1], who criticize the notion of negative absolute temperature (NAT), as a misleading…
A question that is currently highly debated is whether the microcanonical entropy should be expressed as the logarithm of the phase volume (volume entropy, also known as the Gibbs entropy) or as the logarithm of the density of states…
Despite well over a century of effort, the proper expression for the classical entropy in statistical mechanics remains a subject of debate. The Boltzmann entropy (calculated from a surface in phase space) has been criticized as not being…
The Boltzmann-Gibbs celebrated entropy $S_{BG}=-k\sum_ip_i \ln p_i$ is {\it concave} (with regard to all probability distributions $\{p_i\}$) and {\it stable} (under arbitrarily small deformations of any given probability distribution). It…
We consider a situation where an $N$-level system (NLS) is coupled successively to two heat baths with different temperatures without being necessarily thermalized and approaches a steady state. For this situation we apply a general…
We study a particle immersed in a heat bath, in the presence of an external force which decays at least as rapidly as $1/x$, for example a particle interacting with a surface through a Lennard-Jones or a logarithmic potential. As time…
Nonadditive Tsallis $q$-statistics has successfully been applied for a plethora of systems in natural sciences and other branches of knowledge. Nevertheless, its foundations have been severely criticised by some authors based on the…
There is the Gibbs theorem in thermodynamics, according to which the entropy of the mixture of ideal gases is equal to the sum of the entropies of the components of the mixture. J. W. Gibbs proved this by a mathematical derivation from the…
The division by N! in the expression of statistical entropy is usually justified to students by the statement that classical particles should be counted as indistinguishable. Sometimes, quantum indistinguishability is invoked to explain it.…
We show through a nonlinear Fokker-Planck formalism, and confirm by molecular dynamics simulations, that the overdamped motion of interacting particles at T=0, where T is the temperature of a thermal bath connected to the system, can be…
The issue of the thermodynamics of a system of distinguishable particles is discussed in this paper. In constructing the statistical mechanics of distinguishable particles from the definition of Boltzmann entropy, it is found that the…
We have studied finite $N$-body $D$-dimensional nonextensive ideal gases and harmonic oscillators, by using the maximum-entropy methods with the $q$- and normal averages ($q$: the entropic index). The validity range, specific heat and…
Clausius introduced, in the 1860s, a thermodynamical quantity which he named {\it entropy} $S$. This thermodynamically crucial quantity was proposed to be {\it extensive}, i.e., in contemporary terms, $S(N) \propto N$ in the thermodynamic…
The second Tisza-Callen postulate of equilibrium thermodynamics states that for any system exists a function of the system's extensive parameters, called entropy, defined for all equilibrium states and having the property that the values…
In recent papers, several authors have claimed that a definition of the thermodynamic entropy in terms of the logarithm of a volume in phase space, originally suggested by Gibbs, is the only valid definition. Arguing from the Gibbs entropy,…