相关论文: Clausius vs. Boltzmann-Gibbs entropies

We prove a proposition that the entropy of the system composed of finite $N$ molecules of ideal gas is the $q$-entropy or Havrda-Charv\'at-Tsallis entropy, which is also known as Tsallis entropy, with the entropic index…

Statistical formulations of thermodynamic entropy, such as those by Boltzmann and Gibbs, were originally developed for classical systems and are well understood in that context. However, the foundational aspects of quantum statistical…

We brief{}ly review the connection between statistical mechanics and thermodynamics. We show that, in order to satisfy thermodynamics and its Legendre transformation mathematical frame, the celebrated Boltzmann-Gibbs~(BG) statistical…

An unified thermodynamical framework based in the use of a generalized Massieu-Planck thermodynamic potential is proposed and a new formulation of Boltzmann-Gibbs Statistical Mechanics is established. Under this philosophy a generalization…

Dunkel and Hilbert, "Consistent thermostatistics forbids negative absolute temperatures," Nature Physics, {\bf 10}, 67 (2014), and Hilbert, H\"anggi, and Dunkel, "Thermodynamic laws in isolated systems," Phys. Rev. E {\bf 90}, 062116 (2014)…

The Brownian motion of a quantum particle in a harmonic confining potential and coupled to a harmonic quantum thermal bath is exactly solvable. It is shown that at low enough temperatures the stationary state is non-Gibbsian due to an…

Regardless of studies and debates over a century, the statistical origin of the second law of thermodynamics still remains illusive. One essential obstacle is the lack of a proper theoretical formalism for non-equilibrium entropy. Here I…

We show how statistical thermodynamics can be formulated in situations in which thermodynamics applies, while equilibrium statistical mechanics does not. A typical case is, in the words of Landau and Lifshitz, that of partial (or…

Conventional thermo-statistics address infinite homogeneous systems within the canonical ensemble. (Only in this case this is equivalent to the fundamental microcanonical ensemble.) However, some 170 years ago the original motivation of…

A classical (non-quantum-mechanical) relativistic ideal gas in thermodynamic equilibrium in a uniformly accelerated frame of reference is studied using Gibbs's microcanonical and grand canonical formulations of statistical mechanics. Using…

This paper is accountable only to explicitly stated physical assumptions and strict logical inference. Its goal is to run a rigorous stress test of second-law claims within the Clausius framework. We work directly with \textbf{Clausius's…

The Bousso entropy bound, in its generalized form, is investigated for the case of perfect fluids at local thermodynamic equilibrium and evidence is found that the bound is satisfied if and only if a certain local thermodynamic property…

We derive Tsallis entropy, Sq, from universal thermostat independence and obtain the functional form of the corresponding generalized entropy-probability relation. Our result for finite thermostats interprets thermodynamically the subsystem…

Several results of black holes thermodynamics can be considered as firmly founded and formulated in a very general manner. From this starting point we analyse in which way these results may give us the opportunity to gain a better…

Equilibrium statistics of Hamiltonian systems is correctly described by the microcanonical ensemble. Classically this is the manifold of all points in the N-body phase space with the given total energy. Due to Boltzmann's principle,…

Very recently, the validity of the concept of negative temperature has been challenged by several authors since they consider Boltzmann's entropy (that allows negative temperatures) inconsistent from a mathematical and statistical point of…

In this study, we model a harmonic oscillator that enters an interferometer partially coupled to a thermal bath of oscillatory fields by employing a Brownian-type Lindblad master equation. More specifically, we investigate the dynamics and…

We consider the dynamics of a quantum system immersed in a dilute gas at thermodynamics equilibrium using a quantum Markovian master equation derived by applying the low-density limit technique. It is shown that the Gibbs state at the bath…

We show that a natural realization of the thermostatistics of q-bosons can be built on the formalism of q-calculus and that the entire structure of thermodynamics is preserved if we use an appropriate Jackson derivative in place of the…

Recently, Gross claims that Boltzmann entropy $S=k\ln W$ is valid for any system at equilibrium, so that Tsallis entropy is useless in this case. I comment on some arguments forwarded to reach this conclusion and argue that the additive…