相关论文: Eigenvalue asymptotics of M\"uller minimizers for …

The one-particle density matrix $\gamma(x, y)$ for a bound state of an atom or molecule is one of the key objects in the quantum-mechanical approximation schemes. We prove the asymptotic formula $\lambda_k \sim (Ak)^{-8/3}$, $A \ge 0$, as…

For bound states of atoms and molecules of $N$ electrons we consider the corresponding $K$-particle reduced density matrices, $\Gamma^{(K)}$, for $1 \le K \le N-1$. Previously, eigenvalue bounds were obtained in the case of $K=1$ and…

We show that the molecular relativistic Thomas-Fermi-Weizs\"acker functional consisting of atoms of atomic numbers $Z_1,...,Z_k$ has a minimizer, if the particle number $N$ is constrained to a number less or equal to the total nuclear…

We investigate minimizers defined on a bounded domain in $\mathbb{R}^2$ for the Maier--Saupe Q--tensor energy used to characterize nematic liquid crystal configurations. The energy density is singular, as in Ball and Mujamdar's modification…

We analyze the semiclassical $d$-dimensional Schr\"{o}dinger operator in the continuum $ \frac{1}{2} \Delta + \lambda_N^2 V$ discretized on a mesh with spacing proportional to $1/N$. The semi-classical parameter $\lambda_N$ is chosen as…

In this paper we show that any increasing functional of the first k eigenvalues of the Dirichlet Laplacian admits a (quasi-)open minimizer among the subsets of R^N of unit measure. In particular, there exists such a minimizer which is…

We consider minimizers of \[ F(\lambda_1(\Omega),\ldots,\lambda_N(\Omega)) + |\Omega|, \] where $F$ is a function nondecreasing in each parameter, and $\lambda_k(\Omega)$ is the $k$-th Dirichlet eigenvalue of $\Omega$. This includes, in…

For integers $m\geq 3$ and $1\leq\ell\leq m-1$, we study the eigenvalue problem $-u^{\prime\prime}(z)+[(-1)^{\ell}(iz)^m-P(iz)]u(z)=\lambda u(z)$ with the boundary conditions that $u(z)$ decays to zero as $z$ tends to infinity along the…

Consider a bound state (an eigenfunction) $\psi$ of an atom with $N$ electrons. We study the spectra of the one-particle density matrix $\gamma$ and of the one-particle kinetic energy density matrix $\tau$ associated with $\psi$. The paper…

We study electron densities of eigenfunctions of atomic Schroedinger operators. We prove the existence of rho~'''(0), the third derivative of the spherically averaged atomic density rho~ at the nucleus. For eigenfunctions with corresponding…

We investigate regularity properties of minimizers for non-autonomous convex variational integrands $F(x, \mathrm{D} u)$ with linear growth, defined on bounded Lipschitz domains $\Omega \subset \mathbb{R}^n$. Assuming appropriate…

We consider compact Hankel operators realized in $ \ell^2(\mathbb Z_+)$ as infinite matrices $\Gamma$ with matrix elements $h(j+k)$. Roughly speaking, we show that if $h(j)\sim (b_{1}+ (-1)^j b_{-1}) j^{-1}(\log j)^{-\alpha}$ as $j\to…

We study the ionization problem in the Thomas-Fermi-Dirac-von Weizs\"acker theory for atoms and molecules. We prove the nonexistence of minimizers for the energy functional when the number of electrons is large and the total nuclear charge…

We study a class of Landau-de Gennes energy functionals with a sextic bulk energy density in a three-dimensional domain. We examine the asymptotic behavior of uniformly bounded minimizers in two distinct scenarios: one where their energy…

We consider the Hamiltonian of a system of three quantum mechanical particles (two identical fermions and boson)on the three-dimensional lattice $\Z^3$ and interacting by means of zero-range attractive potentials. We describe the location…

We strengthen and generalise a result of Kirsch and Simon on the behaviour of the function $N_L(E)$, the number of bound states of the operator $L = \Delta+V$ in $\R^d$ below $-E$. Here $V$ is a bounded potential behaving asymptotically…

We investigate a semiclassical momentum density energy functional for atoms and show that it yields the same value as the well-known Thomas-Fermi functional. In fact, we show an explicit relation between the minimizers of the two…

We study planar graphs with large negative curvature outside of a finite set and the spectral theory of Schr{\"o}dinger operators on these graphs. We obtain estimates on the first and second order term of the eigenvalue asymptotics.…

We study the asymptotic behavior of the smallest eigenvalue, $\lambda_{N}$, of the Hankel (or moments) matrix denoted by $\mathcal{H}_{N}=\left(\mu_{m+n}\right)_{0\leq m,n\leq N}$, with respect to the weight $w(x)=x^{\alpha}{\rm…

We consider the Brown--Ravenhall model of a relativistic atom with N electrons and a nucleus of charge Z and prove the existence of an infinite number of discrete eigenvalues for N <= Z. As an intermediate result we prove a HVZ-type theorem…