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The standard Large Deviation Theory (LDT) is mathematically illustrated by the Boltzmann-Gibbs factor which describes the thermal equilibrium of short-range-interacting many-body Hamiltonian systems, the velocity distribution of which is…

统计力学 · 物理学 2021-12-24 Ugur Tirnakli , Constantino Tsallis , Nihat Ay

The theory of large deviations constitutes a mathematical cornerstone in the foundations of Boltzmann-Gibbs statistical mechanics, based on the additive entropy $S_{BG}=- k_B\sum_{i=1}^W p_i \ln p_i$. Its optimization under appropriate…

统计力学 · 物理学 2011-10-31 Guiomar Ruiz , Constantino Tsallis

The correlated probabilistic model introduced and analytically discussed in Hanel et al (2009) is based on a self-dual transformation of the index $q$ which characterizes a current generalization of Boltzmann-Gibbs statistical mechanics,…

统计力学 · 物理学 2022-11-23 Dario Javier Zamora , Constantino Tsallis

Maxwell's velocity distribution is known to be universally valid across systems and phases. Here we present a new and general derivation that uses the central limit theorem (CLT) of the probability theory. This essentially uses the idea…

统计力学 · 物理学 2022-06-13 Sangita Mondal , Biman Bagchi

Many complex systems are characterized by non-Boltzmann distribution functions of their statistical variables. If one wants to -- justified or not -- hold on to the maximum entropy principle for complex statistical systems (non-Boltzmann)…

统计力学 · 物理学 2009-11-13 Stefan Thurner , Rudolf Hanel

Large deviation theory (LDT) provides a mathematical framework to quantify the probabilities of rare events in stochastic systems. In this study, we applied LDT to model a chemical reaction system and demonstrated that the fluctuation…

化学物理 · 物理学 2025-01-22 Tatsuaki Tsuruyama

We generalize the usual exponential Boltzmann factor to any reasonable and potentially observable distribution function, $B(E)$. By defining generalized logarithms $\Lambda$ as inverses of these distribution functions, we are led to a…

统计力学 · 物理学 2007-05-23 Rudolf Hanel , Stefan Thurner

Boltzmann-Gibbs statistical mechanics applies satisfactorily to a plethora of systems. It fails however for complex systems generically involving strong space-time entanglement. Its generalization based on nonadditive $q$-entropies…

统计力学 · 物理学 2021-01-15 R. M. de Oliveira , Samuraí Brito , L. R. da Silva , Constantino Tsallis

The paper that is commented by Touchette contains a computational study which opens the door to a desirable generalization of the standard large deviation theory (applicable to a set of $N$ nearly independent random variables) to systems…

统计力学 · 物理学 2015-06-12 Guiomar Ruiz , Constantino Tsallis

We establish large deviation principles (LDPs) for empirical measures associated with a sequence of Gibbs distributions on $n$-particle configurations, each of which is defined in terms of an inverse temperature $% \beta_n$ and an energy…

概率论 · 数学 2020-01-07 Paul Dupuis , Vaios Laschos , Kavita Ramanan

We numerically study a one-dimensional system of $N$ classical localized planar rotators coupled through interactions which decay with distance as $1/r^\alpha$ ($\alpha \ge 0$). The approach is a first principle one (\textit{i.e.}, based on…

统计力学 · 物理学 2013-11-05 Leonardo J. L. Cirto , Vladimir R. V. Assis , Constantino Tsallis

We consider probabilistic models of N identical distinguishable, binary random variables. If these variables are strictly or asymptotically independent, then, for N>>1, (i) the attractor in distribution space is, according to the standard…

统计力学 · 物理学 2009-11-11 John A. Marsh , Miguel A. Fuentes , Luis G. Moyano , Constantino Tsallis

The cornerstone of Boltzmann-Gibbs ($BG$) statistical mechanics is the Boltzmann-Gibbs-Jaynes-Shannon entropy $S_{BG} \equiv -k\int dx f(x)\ln f(x)$, where $k$ is a positive constant and $f(x)$ a probability density function. This theory…

物理与社会 · 物理学 2009-11-11 Silvio M. Duarte Queiros , Celia Anteneodo , Constantino Tsallis

On a fine grained scale the Gibbs entropy of an isolated system remains constant throughout its dynamical evolution. This is a consequence of Liouville's theorem for Hamiltonian systems and appears to contradict the second law of…

统计力学 · 物理学 2017-07-05 Renato Pakter , Yan Levin

The thermodynamic maximum principle for the Boltzmann-Gibbs-Shannon (BGS) entropy is reconsidered by combining elements from group and measure theory. Our analysis starts by noting that the BGS entropy is a special case of relative entropy.…

统计力学 · 物理学 2008-11-26 Jörn Dunkel , Peter Talkner , Peter Hänggi

The standard formulation of thermostatistics, being based on the Boltzmann-Gibbs distribution and logarithmic Shannon entropy, describes idealized uncorrelated systems with extensive energies and short-range interactions. In this letter, we…

统计力学 · 物理学 2020-07-01 S. N. Saadatmand , Tim Gould , E. G. Cavalcanti , J. A. Vaccaro

In the theory of extended irreversible thermodynamics (EIT), the flux-dependent entropy function plays a key role and has a fundamental distinction from the usual flux-independent entropy function adopted by classical irreversible…

概率论 · 数学 2021-01-01 Liu Hong , Hong Qian

The Large Deviation Principle (LDP) and the Central Limit Theorem (CLT) are central pillars of probability theory. While their formulations are established under the i.i.d. assumption, the probabilistic foundation for power-law…

概率论 · 数学 2026-04-22 Hiroki Suyari , Antonio M. Scarfone

We develop a relativistic lattice Boltzmann (LB) model, providing a more accurate description of dissipative phenomena in relativistic hydrodynamics than previously available with existing LB schemes. The procedure applies to the…

计算物理 · 物理学 2015-06-12 M. Mendoza , I. Karlin , S. Succi , H. J. Herrmann

Increasing the number $N$ of elements of a system typically makes the entropy to increase. The question arises on {\it what particular entropic form} we have in mind and {\it how it increases} with $N$. Thermodynamically speaking it makes…

统计力学 · 物理学 2009-11-11 Constantino Tsallis
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