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The Bogoliubov-Dirac-Fock (BDF) model allows to describe relativistic electrons interacting with the Dirac sea. It can be seen as a mean-field approximation of Quantum Electro-dynamics (QED) where photons are neglected. This paper treats…
We study the reduced Bogoliubov-Dirac-Fock (BDF) energy which allows to describe relativistic electrons interacting with the Dirac sea, in an external electrostatic potential. The model can be seen as a mean-field approximation of Quantum…
The Bogoliubov-Dirac-Fock (BDF) model is a no-photon, mean-field approxi- mation of quantum electrodynamics. It describes relativistic electrons in the Dirac sea. In this model, a state is fully characterized by its one-body density matrix,…
The Bogoliubov-Dirac-Fock (BDF) model is a no-photon approximation of quantum electrodynamics. It allows to study relativistic electrons in interaction with the Dirac sea. A state is fully characterized by its one-body density matrix, an…
We study the mean-field approximation of Quantum Electrodynamics, by means of a thermodynamic limit. The QED Hamiltonian is written in Coulomb gauge and does not contain any normal-ordering or choice of bare electron/positron subspaces.…
We study the Bogoliubov-Dirac-Fock (BDF) model, a no-photon, mean-field approxi- mation of quantum electrodynamics that allows to study relativistic electrons interacting with the vacuum. It is a variational model in which states are…
According to Dirac's ideas, the vacuum consists of infinitely many virtual electrons which completely fill up the negative part of the spectrum of the free Dirac operator $D^0$. In the presence of an external field, these virtual particles…
We study the Bogoliubov-Dirac-Fock model which is a mean-field approximation of QED. It allows to consider relativistic electrons interacting with the Dirac sea. We study the system of two electrons in the vacuum: it has been shown in a…
We study the Bogoliubov-Dirac-Fock model introduced by Chaix and Iracane ({\it J. Phys. B.}, 22, 3791--3814, 1989) which is a mean-field theory deduced from no-photon QED. The associated functional is bounded from below. In the presence of…
Building upon the works of Bach, Breteaux, and Tzaneteas (2013) and of Bach and Hach (2022), the Bogolubov-Hartree-Fock (BHF) energy of the Pauli-Fierz Hamiltonian is investigated. Upper and lower bounds on the BHF energy are derived, which…
Whereas many different models exist in the mathematical and physics literature for ground states of non-relativistic crystals, the relativistic case has been much less studied and we are not aware of any mathematical result on a fully…
The Dirac-Fock (DF) model replaces the Hartree-Fock (HF) approximation in quantum chemistry when relativistic effects cannot be neglected. Since the Dirac operator is not bounded from below, the notion of ground state is problematic in this…
We study the ground state solutions of the Dirac-Fock model in the case of weak electronic repulsion, using bifurcation theory. They are solutions of a min-max problem. Then we investigate a max-min problem coming from the electron-positron…
In this note we establish the existence of ground states for atoms within several restricted Hartree-Fock theories. It is shown, for example, that there exists a ground state for closed shell atoms with $N$ electrons and nuclear charge $Z…
We study the energy of relativistic electrons and positrons interacting via the second quantized Coulomb potential in the field of a nucleus of charge Z within the Hartree-Fock approximation. We show that the associated functional has a…
We prove the existence of minimizers for Hartree-Fock-Bogoliubov (HFB) energy functionals with attractive two-body interactions given by Newtonian gravity. This class of HFB functionals serves as model problem for self-gravitating…
In nuclear physics, the relativistic mean-field theory describes the nucleus as a system of Dirac nucleons which interact via meson fields. In a static case and without nonlinear self-coupling of the $\sigma$ meson, the relativistic…
The multiconfiguration Dirac-Fock (MCDF) model uses a linear combination of Slater determinants to approximate the electronic $N$-body wave function of a relativistic molecular system, resulting in a coupled system of nonlinear eigenvalue…
In this article, we set up a functional setting for mean-field electronic structure models of Hartree-Fock or Kohn-Sham types for disordered crystals. The electrons are quantum particles and the nuclei are classical point-like articles…
Within the framework of nonrelativisitic quantum electrodynamics we consider a single nucleus and $N$ electrons coupled to the radiation field. Since the total momentum $P$ is conserved, the Hamiltonian $H$ admits a fiber decomposition with…