相关论文: Reaction Kinetics of Clustered Impurities
We study diffusion-controlled single-species annihilation with sparse initial conditions. In this random process, particles undergo Brownian motion, and when two particles meet, both disappear. We focus on sparse initial conditions where…
We consider a reaction-diffusion model incorporating the reactions A -> 0, A -> 2A and 2A -> 3A. Depending on the relative rates for sexual and asexual reproduction of the quantity A, the model exhibits either a continuous or first-order…
We consider a single-species diffusion-limited annihilation reaction with reactants confined to a two-dimensional surface with one arbitrarily large dimension and the other comparable in size to interparticle distances. This situation could…
We investigate the kinetics of diffusion-controlled heterogeneous single-species annihilation, where the diffusivity of each particle may be different. The concentration of the species with the smallest diffusion coefficient has the same…
Diffusion-limited reactions (DLR) are usually described within the Smoluchowski theory, which neglects interactions between the diffusing components. We propose a first extension of such frame- work that incorporates excluded-volume…
We study fluctuation effects in a two species reaction-diffusion system, with three competing reactions $A+A\rightarrow\emptyset$, $B+B\rightarrow\emptyset$, and $A+B\rightarrow\emptyset$. Asymptotic density decay rates are calculated for…
Reactions in solution require "contact" between the reagents. We can predict the rate at which reagents come into "contact" (at least in dilute conditions), but if the initial collision does not lead to reaction, what happens then? The…
The dynamics of interacting domain walls, regarded as a system of particles which are biased to move towards their nearest neighbours and annihilate when they meet, have been studied in the recent past. We study the effect of the presence…
We study diffusion-limited coalescence, A+A<-->A, in one dimension, in the presence of a diffusing trap. The system may be regarded as a generalization of von Smoluchowski's model for reaction rates, in that: (a) it includes reactions…
We consider a diffusion-limited reaction in case the reacting entities are not available simultaneously. Due to the fact that the reaction takes place after a spatiotemporal accumulation of reactants, the underlying rate equation has to be…
We study a ballistic agglomeration process in the reaction-controlled limit. Cluster densities obey an infinite set of Smoluchowski rate equations, with rates dependent on the average particle energy. The latter is the same for all cluster…
We study diffusion-controlled two-species annihilation with a finite number of particles. In this stochastic process, particles move diffusively, and when two particles of opposite type come into contact, the two annihilate. We focus on the…
The critical behaviour of semi-infinite $d$-dimensional systems with short-range interactions and an O(n) invariant Hamiltonian is investigated at an $m$-axial Lifshitz point with an isotropic wave-vector instability in an $m$-dimensional…
The Smoluchowski approach to diffusion-controlled reactions is generalized to interacting substrate particles by including the osmotic pressure and hydrodynamic interactions of the nonideal particles in the Smoluchoswki equation within a…
I argue that the system of interacting bosons at zero temperature and in random external potential possesses a simple critical point which describes the proliferation of disorder-induced topological defects in the superfluid ground state,…
The kinetics of single-species annihilation, $A+A\to 0$, is investigated in which each particle has a fixed velocity which may be either $\pm v$ with equal probability, and a finite diffusivity. In one dimension, the interplay between…
Evolution of a system of diffusing and proliferating mortal reactants is analyzed in the presence of randomly moving catalysts. While the continuum description of the problem predicts reactant extinction as the average growth rate becomes…
Many non-equilibrium systems display dynamic phase transitions from active to absorbing states, where fluctuations cease entirely. Based on a field theory representation of the master equation, the critical behavior can be analyzed by means…
We study the behavior of the random walk on the infinite cluster of independent long range percolation in dimensions $d=1,2$, where $x$ and $y$ a re connected with probability $\sim\beta/\|x-y\|^{-s}$. We show that when $d<s<2d$ the walk is…
In this paper we compute new reaction rates of the Smoluchowski equation which takes into account correlations. The new rate K = KMF + KC is the sum of two terms. The first term is the known Smoluchowski rate with the mean-field…