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We calculate thermodynamic and structural quantities of a fluid of hard spheres of diameter $\sigma$ in a quasi-one-dimensional pore with accessible pore width $W $ smaller than $\sigma$ by applying a perturbative method worked out earlier…

软凝聚态物质 · 物理学 2024-07-04 Thomas Franosch , Rolf Schilling

In this paper, some equations are derived to describe the out-of-equilibrium thermodynamics of colloidal suspensions. These results are obtained assuming that the properties of the colloids essentially come from their surfaces which are…

软凝聚态物质 · 物理学 2013-03-29 Pierre de Thier

The authors present a study of the non equilibrium statistical properties of a one dimensional hard-rod fluid dissipating energy via inelastic collisions and subject to the action of a Gaussian heat bath, simulating an external driving…

材料科学 · 物理学 2009-11-13 Umberto Marini-Bettolo-Marconi , Pedro Tarazona , Fabio Cecconi

We discuss phase coexistence of polydisperse colloidal suspensions in the presence of adhesion forces. The combined effect of polydispersity and Baxter's sticky-hard-sphere (SHS) potential, describing hard spheres interacting via strong and…

统计力学 · 物理学 2009-11-11 Domenico Gazzillo , Achille Giacometti , Riccardo Fantoni

A hydrodynamic mechanism of interactions of colloidal particles is considered. The mechanism is based on the assumption of tiny background flows in the experimental cells during measurements by Grier at al. [1-6]. Both trivial (shear flow)…

软凝聚态物质 · 物理学 2007-05-23 Yuri O. Popov

Rheological properties, especially 'shear-thinning', of dense colloidal dispersions are discussed on three different levels. A generalized phenomonological Maxwell model gives a broad framework connecting glassy dynamics to the linear and…

软凝聚态物质 · 物理学 2007-05-23 Matthias Fuchs , Matthias Ballauff

In this paper, we introduce a new extended version of the shallow water equations with surface tension which is skew-symmetric with respect to the L2 scalar product and allows for large gradients of fluid height. This result is a…

We study the Kern-Frenkel model for patchy colloids using Barker-Henderson second-order thermodynamic perturbation theory. The model describes a fluid where hard sphere particles are decorated with one patch, so that they interact via a…

软凝聚态物质 · 物理学 2012-03-27 Christoph Gögelein , Flavio Romano , Francesco Sciortino , Achille Giacometti

In this paper we develop statistical mechanical tools to describe the intermediate- and long-time collective- and self-diffusion properties of a liquid of strongly-interacting hollow spherical particles (shells), each bearing a smaller…

软凝聚态物质 · 物理学 2014-07-24 L. E. Sanchez Diaz , E. C. Cortes-Morales , X. Li , Wei-Ren Chen , M. Medina-Noyola

In the present paper we propose the van der Waals-like model, which allows a purely analytical study of fluid properties including the equation of state, phase behavior and supercritical fluctuations. We take a square-well system as an…

软凝聚态物质 · 物理学 2015-06-18 V. V. Brazhkin , Yu. D. Fomin , V. N. Ryzhov , E. E. Tareyeva , E. N. Tsiok

We study a system of few colloids confined in a small spherical cavity by event driven molecular dynamics simulations in the canonical ensemble. The colloidal particles interact through a short range square-well potential, which takes into…

软凝聚态物质 · 物理学 2015-04-10 Iván Paganini , Claudio Pastorino , Ignacio Urrutia

The normal modes and relaxation rates of weak colloidal gels are investigated in computations employing different models of the hydrodynamic interactions between colloids. The eigenspectrum is computed for freely draining,…

流体动力学 · 物理学 2018-01-17 Zsigmond Varga , James W. Swan

We derive analytical solutions for hydrodynamic sources and sinks to granular temperature in moderately dense suspensions of elastic particles at finite Reynolds numbers. Modeling the neighbor-induced drag disturbances with a Langevin…

软凝聚态物质 · 物理学 2022-05-25 Aaron M. Lattanzi , Vahid Tavanashad , Shankar Subramaniam , Jesse Capecelatro

Phoretic colloids self-propel thanks to surface flows generated in response to surface gradients (thermal, electrical, or chemical), that are self-induced and/or generated by other particles. Here we present a scalable and versatile…

软凝聚态物质 · 物理学 2024-07-29 Blaise Delmotte , Florencio Balboa Usabiaga

This work deals with the evaluation of the flow curve of colloidal systems that develop fluid phases with different mechanical properties, namely shear-banding fluids. The problem involved is that, as different fluid phases coexist in the…

软凝聚态物质 · 物理学 2007-05-23 Daniel Quemada , Claudio L. A. Berli

In the vicinity of their glass transition, dense colloidal suspensions acquire elastic properties over experimental timescales. We investigate the possibility of a visco-elastic flow instability in curved geometry for such materials. To…

软凝聚态物质 · 物理学 2015-08-21 Alexandre Nicolas , Matthias Fuchs

We present a systematic study of the self-diffusion coefficient for a fluid of particles interacting via the square-well pair potential by means of molecular dynamics simulations in the canonical (N,V,T) ensemble. The discrete nature of the…

软凝聚态物质 · 物理学 2018-11-14 Alexis Torres-Carbajal , Victor M. Trejos , Luz Adriana Nicasio-Collazo

Closed analytical expressions for scattering intensity and other global structure factors are derived for a new solvable model of polydisperse sticky hard spheres. The starting point is the exact solution of the ``mean spherical…

统计力学 · 物理学 2009-10-31 Domenico Gazzillo , Achille Giacometti

The three-dimensional Gaussian core model (GCM) for soft-matter systems has repulsive interparticle interaction potential $\phi (r) = \varepsilon\, {\rm exp}\left[ -(r/\sigma)^{2} \right]$, with $r$ the distance between a pair of atoms, and…

软凝聚态物质 · 物理学 2021-01-18 George Ruppeiner , Peter Mausbach , Helge-Otmar May

We combine experiments and simulations to study the link between criticality and gelation in sticky spheres. We employ confocal microscopy to image colloid-polymer mixtures, and Monte Carlo simulations of the square-well (SW) potential as a…

软凝聚态物质 · 物理学 2018-08-17 David Richard , James Hallett , Thomas Speck , C. Patrick Royall