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A nonperturbative electron transfer rate theory is developed based on the reduced density matrix dynamics, which can be evaluated readily for the Debye solvent model without further approximation. Not only does it recover for reaction rates…

量子物理 · 物理学 2007-05-23 Ping Han , Rui-Xue Xu , Baiqing Li , Jian Xu , Ping Cui , Yan Mo , YiJing Yan

We study the entropy production of Gibbs (equilibrium) measures for chaotic dynamical systems with folding of the phase space. The dynamical chaotic model is that generated by a hyperbolic non-invertible map $f$ on a general basic (possibly…

动力系统 · 数学 2011-04-14 Eugen Mihailescu

We extend results on quadratic pressure and convergence of Gibbs mesures from previous joined work of the authors to the Curie-Weiss-Potts model. We define the notion of equilibrium state for the quadratic pressure and show that under some…

动力系统 · 数学 2020-04-17 R. Leplaideur , F. Watbled

We study thermodynamic formalism for topologically transitive partially hyperbolic systems in which the center-stable bundle satisfies a bounded expansion property, and show that every potential function satisfying the Bowen property has a…

动力系统 · 数学 2020-12-24 Vaughn Climenhaga , Yakov Pesin , Agnieszka Zelerowicz

A lattice system of interacting temperature loops, which is used in the Euclidean approach to describe equilibrium thermodynamic properties of an infinite system of interacting quantum particles performing anharmonic oscillations (quantum…

数学物理 · 物理学 2007-05-23 Yuri Kozitsky , Tatiana Pasurek

We derive the entropy production for transport of multi-phase fluids in a non-deformable, porous medium exposed to differences in pressure, temperature, and chemical potentials. Thermodynamic extensive variables on the macro-scale are…

流体动力学 · 物理学 2020-12-03 Signe Kjelstrup , Dick Bedeaux , Alex Hansen , Bjørn Hafskjold , Olav Galteland

We prove that certain Gibbs measures on subshifts of finite type are nonsingular and ergodic for certain countable equivalence relations, including the orbit relation of the adic transformation (the same as equality after a permutation of…

动力系统 · 数学 2016-09-06 Karl Petersen , Klaus Schmidt

We consider transfer operators for topological Markov shift (TMS) with countable states and with holes which are $2$-cylinders. As main results, if the closed system of the shift has finitely irreducible transition matrix and the potential…

动力系统 · 数学 2024-03-29 Haruyoshi Tanaka

A generalization of the Gibbs entropy postulate is proposed based on the BBGKY hierarchy as the nonequilibrium entropy for a system of N interacting particles. This entropy satisfies the basic principles of thermodynamics in the sense that…

统计力学 · 物理学 2007-05-23 A. Perez-Madrid

We propose a definition of phase transitions in finite systems based on topology anomalies of the event distribution in the space of observations. This generalizes all the definitions based on the curvature anomalies of thermodynamical…

统计力学 · 物理学 2009-10-31 Ph. Chomaz , F. Gulminelli , V. Duflot

Let $(\Sigma_T,\sigma)$ be a subshift of finite type with primitive adjacency matrix $T$, $\psi:\Sigma_T \rightarrow \mathbb{R}$ a H\"older continuous potential, and $\mathcal{A}:\Sigma_T \rightarrow \mathrm{GL}_d(\mathbb{R})$ a 1-typical,…

动力系统 · 数学 2024-09-10 Tom Rush

In this article we prove estimates for the topological pressure of the set of points whose Birkhoff time averages are far from the space averages corresponding to the unique equilibrium state that has a weak Gibbs property. In particular,…

动力系统 · 数学 2015-10-21 Thiago Bomfim , Paulo Varandas

We study suspension flows defined over sub-shifts of finite type with continuous roof functions. We prove the existence of suspension flows with uncountably many ergodic measures of maximal entropy. More generally, we prove that any…

动力系统 · 数学 2021-08-16 Godofredo Iommi , Anibal Velozo

Perturbation theory is a kind of estimation method based on theorem of Taylor expansion, and is useful to investigate electromagnetic solutions of small changes. By considering a sharp boundary as a limit of smoothed systems, previous study…

计算物理 · 物理学 2020-11-30 Di Yu , Xiaomin Lv , Boyu Fan , Ju Gao , Jingdao Tang , Nan Xu , You Wang , Haizhi Song , Qiang Zhou , Guangwei Deng

A point process on the topological space S is at most countable subset without a random accumulation point in S. In studies of the point processes, there is a problem of seeing the properties of rigidity and tolerance, and this problem is…

概率论 · 数学 2019-09-05 Yuta Arai

We generalize several results of the classical theory of Thermodynamic Formalism by considering a compact metric space $M$ as the state space. We analyze the shift acting on $M^\mathbb{N}$ and consider a general a-priori probability for…

动力系统 · 数学 2015-08-05 Artur O. Lopes , Jairo K. Mengue , Joana Mohr , Rafael R. Souza

Consider a compact metric space $(M, d_M)$ and $X = M^{\mathbb{N}}$. We prove a Ruelle's Perron Frobenius Theorem for a class of compact subshifts with Markovian structure introduced in [Bull. Braz. Math. Soc. 45 (2014), pp. 53-72] which…

动力系统 · 数学 2021-11-12 Rafael Rigão Souza , Victor Vargas

We study a model of spatial random permutations over a discrete set of points. Formally, a permutation $\sigma$ is sampled proportionally to the weight $\exp\{-\alpha \sum_x V(\sigma(x)-x)\},$ where $\alpha>0$ is the temperature and $V$ is…

概率论 · 数学 2019-04-09 Inés Armendáriz , Pablo A. Ferrari , Nicolás Frevenza

Consider a statistical physical model on the $d$-regular infinite tree $T_{d}$ described by a set of interactions $\Phi$. Let $\{G_{n}\}$ be a sequence of finite graphs with vertex sets $V_n$ that locally converge to $T_{d}$. From $\Phi$…

概率论 · 数学 2018-03-14 Tim Austin , Moumanti Podder

Analysis of network dynamics became a focal point to understand and predict changes of complex systems. Here we introduce Turbine, a generic framework enabling fast simulation of any algorithmically definable dynamics on very large…

分子网络 · 定量生物学 2013-10-28 Kristof Z. Szalay , Peter Csermely