相关论文: From diffusion to reaction via Gamma-convergence
We study a singular-limit problem arising in the modelling of chemical reactions. At finite {\epsilon} > 0, the system is described by a Fokker-Planck convection-diffusion equation with a double-well convection potential. This potential is…
We derive Kramers' formula as singular limit of the Fokker-Planck equation with double-well potential. The convergence proof is based on the Rayleigh principle of the underlying Wasserstein gradient structure and complements a recent result…
A popular approach to modeling bimolecular reactions between diffusing molecules is through the use of reactive boundary conditions. One common model is the Smoluchowski partial absorption condition, which uses a Robin boundary condition in…
We present a classical, mesoscopic derivation of the Fokker-Planck equation for diffusion in an expanding medium. To this end, we take a conveniently generalized Chapman-Kolmogorov equation as the starting point. We obtain an analytical…
Many processes in chemistry, physics, and biology depend on thermally activated events in which the system changes its state by surmounting an activation barrier. Examples range from chemical reactions, protein folding, and nucleation…
A pointlike particle of finite mass m, moving in a one-dimensional viscous environment and biased by a spatially dependent force, is considered. We present a rigorous mapping of the Fokker-Planck equation, which determines evolution of the…
We use the Chapman-Enskog method to derive the Smoluchowski equation from the Kramers equation in a high friction limit. We consider two main extensions of this problem: we take into account a uniform rotation of the background medium and…
Single molecule chemical reactions yield new insight into fluctuation phenomena which are obscured in measurement of ensemble of molecules. Kramers escape problem is investigated here in a framework suitable for single molecule reactions.…
We present a unified approach to characterising fast-reaction limits of systems of either two reaction-diffusion equations, or one reaction-diffusion equation and one ordinary differential equation, on unbounded domains, motivated by models…
We study kinetics of diffusion-limited catalytically-activated $A + B \to B$ reactions taking place in three dimensional systems, in which an annihilation of diffusive $A$ particles by diffusive traps $B$ may happen only if the encounter of…
We give an example of a mathematical model describing quantum mechanical processes interacting with medium. As a model, we consider the process of heat scattering of a wave function defined on the phase space. We consider the case when the…
The Gamma-limit of higher-order singular perturbations of the Perona-Malik functional is analyzed. The energies considered combine the critically scaled logarithmic term with a k-th order regularization designed to balance bulk and…
Theories that are used to extract energy-landscape information from single-molecule pulling experiments in biophysics are all invariably based on Kramers' theory of thermally-activated escape rate from a potential well. As is well known,…
Aim of this note is to analyse branching Brownian motion within the class of models introduced in the recent paper [4] and called chemical diffusion master equations. These models provide a description for the probabilistic evolution of…
We derive a diffusion approximation for the kinetic Vlasov-Fokker-Planck equation in bounded spatial domains with specular reflection type boundary conditions. The method of proof involves the construction of a particular class of test…
Variational models of phase transitions take into account double-well energies singularly perturbed by gradient terms, such as the Cahn-Hilliard free energy. The derivation by $\Gamma$-convergence of a sharp-interface limit for such energy…
A formalism is presented in which the radiation of photons off high energy electrons during a multiple scattering process with finite condensed media can be evaluated for a general interaction. We show that the arising…
The usual derivations of the S and K matrices for two-particle reactions proceed through the Lippmann-Schwinger equation with formal definitions of the incoming and outgoing scattering states. Here we present an alternative derivation that…
We present a Master Equation formulation based on a Markovian random walk model that exhibits sub-diffusion, classical diffusion and super-diffusion as a function of a single parameter. The non-classical diffusive behavior is generated by…
We develop the kinetic theory of Hamiltonian systems with weak long-range interactions. Starting from the Klimontovich equation and using a quasilinear theory, we obtain a general kinetic equation that can be applied to spatially…