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In this article it is shown that in an equilibrium classical canonical ensemble of molecules with two-body interaction and external field full Gibbs distribution can be uniquely expressed in terms of a reduced two-particle distribution…

统计力学 · 物理学 2008-10-28 M. I. Kalinin

It is shown that in equilibrium a canonical ensemble of particles with two-particle interaction the Gibbs distribution function may be expressed uniquely through a pair distribution function. It means, that for given values of the particle…

统计力学 · 物理学 2007-05-23 M. I. Kalinin

The probability distribution of a function of a subsystem conditioned on the value of the function of the whole, in the limit when the ratio of their values goes to zero, has a limit law: It equals the unconditioned marginal probability…

数学物理 · 物理学 2021-01-18 Yu-Chen Cheng , Hong Qian , Yizhe Zhu

It is well known that a system, S, weakly coupled to a heat bath, B, is described by the canonical ensemble when the composite, S+B, is described by the microcanonical ensemble corresponding to a suitable energy shell. This is true both for…

统计力学 · 物理学 2007-05-23 Sheldon Goldstein , Joel L. Lebowitz , Roderich Tumulka , Nino Zanghi

It is demonstrated that the canonical distribution for a subsystem of a closed system follows directly from the solution of the time-reversible Newtonian equation of motion in which the total energy is strictly conserved. It is shown that…

In systems with long-range interactions, since energy is a non-additive quantity, ensemble inequivalence can arise: it is possible that different statistical ensembles lead to different equilibrium descriptions, even in the thermodynamic…

统计力学 · 物理学 2018-09-05 Marco Baldovin

This work explores fundamental statistical and thermodynamic properties of short-and long-range-interacting systems. The purpose of this study is twofold. Firstly, we rigorously prove that the probability distribution of arbitrary few-body…

统计力学 · 物理学 2020-08-19 Tomotaka Kuwahara , Keiji Saito

An exact closed equation for s - particle equilibrium distribution function (s<N) of the system of N>>1 interacting particles is obtained. This integra-differential {\beta} - convolution equation ({\beta}=1/k_{B}T) follows from the Bloch…

统计力学 · 物理学 2013-07-23 Victor F. Los

Models of quantum and classical particles on the d-dimensional cubic lattice with pair interparticle interactions are considered. The classical model is obtained from the corresponding quantum one when the reduced physical mass of the…

数学物理 · 物理学 2007-05-23 Sergio Albeverio , Yuri Kondratiev , Yuri Kozitsky

We discuss the possibility of using generalized canonical distributions, i.e. using other factors than $\exp(-\beta E)$, in order to compute the equilibrium properties of physical systems. It will be show that some other choices can, in…

统计力学 · 物理学 2007-05-23 Raul Toral

We show that an arbitrary probability distribution can be represented in exponential form. In physical contexts, this implies that the equilibrium distribution of any classical or quantum dynamical system is expressible in grand canonical…

统计力学 · 物理学 2007-10-25 Dorje C. Brody

Consider a quantum system $S$ weakly interacting with a very large but finite system $B$ called the heat bath, and suppose that the composite $S\cup B$ is in a pure state $\Psi$ with participating energies between $E$ and $E+\delta$ with…

量子物理 · 物理学 2014-02-25 Viraj Pandya , Roderich Tumulka

The paper develop a new approach to the justification of Gibbs canonical distribution for Hamiltonian systems with finite number of degrees of freedom. It uses the condition of nonintegrability of the ensemble of weak interacting…

可精确求解与可积系统 · 物理学 2007-05-23 V. V. Kozlov

The Statistical Model has to be formulated in the canonical ensemble with respect to strangeness conservation if the number of strange particles becomes small. However, the canonical suppression under the assumption of strangeness chemical…

高能物理 - 唯象学 · 物理学 2009-09-29 Ingrid Kraus , Helmut Oeschler , Krzysztof Redlich

The distribution of the initial short-time displacements of particles is considered for a class of classical systems under rather general conditions on the dynamics and with Gaussian initial velocity distributions, while the positions could…

统计力学 · 物理学 2007-05-23 R. van Zon , E. G. D. Cohen

In this paper we derive the canonical distribution as a stationary solution of the Liouville equation for the classical dissipative system. Dissipative classical systems can have stationary states look like canonical Gibbs distributions.…

统计力学 · 物理学 2009-11-10 Vasily E. Tarasov

Traditional derivation of Gibbs canonical distribution and the justification of thermodynamics are based on the assumption concerning an isoenergetic ergodicity of a system of $n$ weakly interacting identical subsystems and passage to the…

可精确求解与可积系统 · 物理学 2007-05-23 V. V. Kozlov

After reviewing some fundamental results derived from the introduction of the generalized Gibbs canonical ensemble, such as the called thermodynamic uncertainty relation, it is described a physical scenario where such a generalized ensemble…

统计力学 · 物理学 2007-05-23 L. Velazquez

A pedagogical approach for deriving the statistical mechanical partition function, in a manner that emphasizes the key role of entropy in connecting the microscopic states to thermodynamics, is introduced. The connections between the…

统计力学 · 物理学 2013-09-10 Jonathan L. Belof , Brian Space

We study the relation between quantum mechanical and classical Gibbs states of spin systems with spin quantum number $s$. It is known that quantum states and observables can be represented by functions defined on the phase space ${\mathcal…

数学物理 · 物理学 2023-02-17 Heinz-Jürgen Schmidt
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