相关论文: Ludwig Boltzmann, Transport Equation and the Secon…

In the last quarter of the nineteenth century, Ludwig Boltzmann explained how irreversible macroscopic laws, in particular the second law of thermodynamics, originate in the time-reversible laws of microscopic physics. Boltzmann's analysis,…

Boltzmann's struggle with a derivation of the Second Law of Thermodynamics is sketched. So is his first derivation of the connection between entropy and probability in 1877. Planck's derivation and quantum mechanical modifications of…

Well before the atomistic nature of matter was experimentally established, Ludwig Boltzmann's audacious effort to explain the macroscopic world of human experience in terms of the workings of an unseen microscopic world met with vigorous…

In textbooks on statistical mechanics, one finds often arguments based on classical mechanics, phase space and ergodicity in order to justify the second law of thermodynamics. However, the basic equations of motion of classical mechanics…

I will argue, pace a great many of my contemporaries, that there's something right about Boltzmann's attempt to ground the second law of thermodynamics in a suitably amended deterministic time-reversal invariant classical dynamics, and that…

Boltzmann's principle S=k ln W allows to extend equilibrium thermo-statistics to ``Small'' systems without invoking the thermodynamic limit. The clue is to base statistical probability on ensemble averaging and not on time averaging. It is…

We derive the second-order hydrodynamic equation and the microscopic formulae of the relaxation times as well as the transport coefficients systematically from the relativistic Boltzmann equation. Our derivation is based on a novel…

In two respects Ludwig Boltzmann was a pioneer of quantum mechanics. First because in his statistical interpretation of the second law of thermodynamics he introduced the theory of probability into a fundamental law of physics and thus…

A heuristic generalization of the Boltzmann-Gibbs microcanonical entropy is proposed, able to describe meta-equilibrium features and evolution of macroscopic systems. Despite its simple-minded derivation, such a function of "collective…

In this manuscript we present a brief life history of Ludwig Edward Boltzmann and his achivements. Particularly, we discuss his H-theorem, his work on entropy and statistical interpretation of second-law of thermodynamics. We point out his…

It will be shown, how the Boltzmannian ideas on statistical physics can be naturally applied to nonequilibrium thermodynamics. A similar approach for treating nonequilibrium phenomena has been successfully used by Einstein and Smoluchowski…

Nonequilibrium thermodynamics of a general second-order stochastic system is investigated. We prove that at steady state, under inversion of velocities, the condition of time-reversibility over the phase space is equivalent to the…

Boltzmann's Principle S = k ln W was repeatedly criticized by Einstein since it lacked a proper dynamical foundation in view of the thermal motion of the particles, out of which a physical system consists. This suggests, in particular, that…

We consider the kinetic theory of dilute gases in the Boltzmann--Grad limit. We propose a new perspective based on a large deviation estimate for the probability of the empirical distribution dynamics. Assuming Boltzmann molecular chaos…

Boltzmann's principleS=k*ln W is generalized to non-equilibrium Hamiltonian systems with possibly fractal distributions in phase space by the box-counting volume. The probabilities P(M) of macroscopic observables M are given by the ratio…

In the second half of the 19th century, the kinetic theory of gases has probably raised one of the most impassioned debates in the history of science. The so-called reversibility paradox around which intense polemics occurred reveals the…

A numerical experiment of ideal stochastic motion of a particle subject to conservative forces and Gaussian noise reveals that the path probability depends exponentially on action. This distribution implies a fundamental principle…

We study a mechanical system that was considered by Boltzmann in 1868 in the context of the derivation of the canonical and microcanonical ensembles. This system was introduced as an example of ergodic dynamics, which was central to…

Regardless of studies and debates over a century, the statistical origin of the second law of thermodynamics still remains illusive. One essential obstacle is the lack of a proper theoretical formalism for non-equilibrium entropy. Here I…

In the last decades the theory of large deviations has become a main tool in statistical mechanics especially in the study of non--equilibrium. In a rational reconstruction of the story one must recognize the ideal connection and debt of…