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相关论文: Identifying the Catalytic Descriptor of Single-Ato…

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The discovery of metals as catalytic centers for nitrogen reduction reactions has stimulated great enthusiasm for single-atom catalysts. However, the poor activity and low selectivity of available SACs are far away from the industrial…

材料科学 · 物理学 2022-12-28 Tingting Bo , Shiqian Cao , Nan Mu , Ruixin Xu , Yanyu Liu , Wei Zhou

Electrochemical nitrate reduction reaction(NO3RR)offers a sustainable route for ambient ammonia synthesis. While metal-nitrogen-carbon (M-N-C) single-atom catalysts have emerged as promising candidates for NO3RR, the structure-activity…

化学物理 · 物理学 2026-04-21 Qiuling Jiang , Mingyao Gu , Tianyi Wang , Fangzhou Liu , Xin Yang , Di Zhang , Zhijian Wu , Ying Wang , Li Wei , Hao Li

Electrocatalysts of nitrogen reduction reaction (NRR) have attracted ever-growing attention due to its application for renewable energy alternative to fossil fuels. However, activation of inert N-N bond requires multiple complex charge…

材料科学 · 物理学 2022-04-20 Zheng Shu , Hejin Yan , Hongfei Chen , Yongqing Cai

Single-atom catalysts (SACs) with metal-nitrogen-carbon (M-N-C) structures are widely recognized as promising candidates in oxygen reduction reactions (ORR). According to the classical Sabatier principle, optimal 3d metal catalysts, such as…

化学物理 · 物理学 2026-04-21 Di Zhang , Fangxin She , Jiaxiang Chen , Li Wei , Hao Li

Transforming CO$_2$ into methanol represents a crucial step towards closing the carbon cycle, with thermoreduction technology nearing industrial application. However, obtaining high methanol yields and ensuring the stability of…

化学物理 · 物理学 2025-07-08 Prajwal Pisal , Ondrej Krejci , Patrick Rinke

Establishing a mapping between nanocatalysts structure and their catalytic properties is essential for efficient design. To this end, we demonstrate the accuracy of a general machine learning framework on a representative and challenging…

介观与纳米尺度物理 · 物理学 2025-09-16 Sofia Zinzani , Francesca Baletto , Kevin Rossi

Alloy nanocatalysts have found broad applications ranging from fuel cells to catalytic converters and hydrogenation reactions. Despite extensive studies, identifying the active sites of nanocatalysts remains a major challenge due to the…

Ammonia (NH3) is mainly produced through the traditional Haber-Bosch process under harsh conditions with huge energy consumption and massive carbon dioxide (CO2) emission. The nitrogen electroreduction reaction (NERR), as an…

介观与纳米尺度物理 · 物理学 2020-02-18 Yanling Zhai , Zhijun Zhu , Chengzhou Zhu , Kyle Chen , Xueji Zhang , Jing Tang , Jun Chen

Nitrate reduction to ammonia has attracted much attention for nitrate (NO3-) removal and ammonia (NH3) production. Identifying promising catalyst for active nitrate electroreduction reaction (NO3RR) is critical to realize efficient…

材料科学 · 物理学 2023-08-29 Zheng Shu , Hongfei Chen , Xing Liu , Huaxian Jia , Hejin Yan , Yongqing Cai

The hydrogen evolution reaction (HER) is central to sustainable hydrogen production, and nitrogen coordinated dual atom catalysts (DACs) offer a promising route to noble metal activity at low cost. Yet their vast compositional and…

Converting earth-abundant dinitrogen into value-added chemical ammonia is a significant yet challenging topic. Electrocatalytic nitrogen reduction reaction (NRR), compared with conventional Haber-Bosch process, is an energy-saving and…

化学物理 · 物理学 2020-08-19 Yiran Ying , Ke Fan , Xin Luo , Haitao Huang

Catalysis has entered everyday life through a number of technological processes relying on different catalytic systems. The increasing demand for such systems requires rationalization of the use of their expensive components, like noble…

材料科学 · 物理学 2019-10-29 A. S. Dobrota , I. A. Pašti , A. Z. Jovanović , B. Johansson , N. V. Skorodumova

Single-atom catalysts (SACs) have emerged as frontiers for catalyzing chemical reactions, yet the diverse combinations of active elements and support materials, the nature of coordination environments, elude traditional methodologies in…

材料科学 · 物理学 2024-02-07 Haoyu Yang , Juanli Zhao , Qiankun Wang , Bin Liu , Wei Luo , Ziqi Sun , Ting Liao

The nitrogen reduction reaction (NRR), as an efficient and green pathway for ammonia synthesis, plays a crucial role in achieving on-demand ammonia production. This study proposes a novel design concept based on dual-iron atomic sites and…

材料科学 · 物理学 2025-03-06 Zhe Zhang , Wenxin Ma , Jiajie Qiao , Xiaoliang Wu , Shaowen Yu , Weiye Hou , Xiang Huang , Rubin Huo , Hongbo Wu , Yusong Tu

Understanding and predicting the activity of oxide perovskite catalysts for the oxygen evolution reaction (OER) requires descriptors that are both accurate and physically interpretable. While symbolic regression (SR) offers a path to…

数据分析、统计与概率 · 物理学 2025-07-17 Yeming Xian , Xiaoming Wang , Yanfa Yan

Single-atom metal alloy catalysts (SAACs) have recently become a very active new frontier in catalysis research. The simultaneous optimization of both facile dissociation of reactants and a balanced strength of intermediates' binding make…

材料科学 · 物理学 2021-04-14 Zhong-Kang Han , Debalaya Sarker , Runhai Ouyang , Yi Gao , Sergey V. Levchenko

Catalyst design is crucial for materials synthesis, especially for complex reaction networks. Strategies like collaborative catalytic systems and multifunctional catalysts are effective but face challenges at the nanoscale. Carbon nanotube…

材料科学 · 物理学 2025-12-19 Liu Qian , Yue Li , Ying Xie , Jian Zhang , Pai Li , Yue Yu , Zhe Liu , Feng Ding , Jin Zhang

The electrocatalytic CO2 reduction reaction (CO2RR) is a complex multi-proton-electron transfer process that generates a vast network of reaction intermediates. Accurate prediction of free energy changes (G) of these intermediates and…

化学物理 · 物理学 2025-04-23 Xuxin Kang , Wenjing Zhou , Ziyuan Li , Zhaoqin Chu , Hanqin Yin , Shan Gao , Aijun Du , Xiangmei Duan

In this work, we provide a computational methodological framework using the single-atom systems as an example material class for ammonia synthesis that is robust towards parameter selection. Applying this to Pt$_1$/g-C$_3$N$_4$,…

材料科学 · 物理学 2020-07-21 Lance Kavalsky , Venkatasubramanian Viswanathan

Single-atom catalysts (SACs) have garnered significant interest due to their ability to reduce metal particles to the atomic scale, enabling finely tunable local environments and enhanced catalytic properties in terms of reactivity and…

介观与纳米尺度物理 · 物理学 2025-03-13 G. S. Priyanga , S. K. Behera
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