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To illustrate Boltzmann's construction of an entropy function that is defined for a microstate of a macroscopic system, we present here the simple example of the free expansion of a one dimensional gas of non-interacting point particles.…

We study the time evolution of the Boltzmann entropy of a microstate during the non-equilibrium free expansion of a one-dimensional quantum ideal gas. This quantum Boltzmann entropy, $S_B$, essentially counts the "number" of independent…

We investigate the time evolution of the Boltzmann entropy of a dilute gas of N particles, N>>1, as it undergoes a free expansion doubling its volume. The microstate of the system, a point in the 4N dimensional phase space, changes in time…

统计力学 · 物理学 2024-10-08 P. L. Garrido , S. Goldstein , D. A. Huse , J. L. Lebowitz

Boltzmann defined the entropy of a macroscopic system in a macrostate $M$ as the $\log$ of the volume of phase space (number of microstates) corresponding to $M$. This agrees with the thermodynamic entropy of Clausius when $M$ specifies the…

统计力学 · 物理学 2009-11-10 S. Goldstein , Joel L. Lebowitz

We introduce a high dimensional symplectic map, modeling a large system consisting of weakly interacting chaotic subsystems, as a toy model to analyze the interplay between single-particle chaotic dynamics and particles interactions in…

混沌动力学 · 物理学 2011-11-10 Massimo Falcioni , Luigi Palatella , Simone Pigolotti , Lamberto Rondoni , Angelo Vulpiani

A way to construct Boltzmann entropy, i.e., the entropy as a function of a microscopic pure state, for quantum field systems is proposed. Operators that shift the field in wavevector space are used in the construction. By employing an…

统计力学 · 物理学 2020-03-25 Kyo Yoshida

Observational entropy -- a quantity that unifies Boltzmann's entropy, Gibbs' entropy, von Neumann's macroscopic entropy, and the diagonal entropy -- has recently been argued to play a key role in a modern formulation of statistical…

量子物理 · 物理学 2026-03-24 Teruaki Nagasawa , Kohtaro Kato , Eyuri Wakakuwa , Francesco Buscemi

The Boltzmann kinetic equation is obtained from an integro-differential master equation that describes a stochastic dynamics in phase space of an isolated thermodynamic system. The stochastic evolution yields a generation of entropy,…

统计力学 · 物理学 2019-06-05 Mário J. de Oliveira

On a fine grained scale the Gibbs entropy of an isolated system remains constant throughout its dynamical evolution. This is a consequence of Liouville's theorem for Hamiltonian systems and appears to contradict the second law of…

统计力学 · 物理学 2017-07-05 Renato Pakter , Yan Levin

A restricted Boltzmann machine is a generative probabilistic graphic network. A probability of finding the network in a certain configuration is given by the Boltzmann distribution. Given training data, its learning is done by optimizing…

无序系统与神经网络 · 物理学 2020-05-28 Sangchul Oh , Abdelkader Baggag , Hyunchul Nha

This study investigates the steady Boltzmann equation in one spatial variable for a polyatomic single-component gas in a half-space. Inflow boundary conditions are assumed at the half-space boundary, where particles entering the half-space…

偏微分方程分析 · 数学 2026-02-03 Niclas Bernhoff , Stephane Brull , Eddie Wadbro

We investigate, via computer simulations, the time evolution of the (Boltzmann) entropy of a dense fluid not in local equilibrium. The macrovariables $M$ describing the system are the (empirical) particle density $f=\{f(\un{x},\un{v})\}$…

统计力学 · 物理学 2009-11-10 P. L. Garrido , S. Goldstein , J. L. Lebowitz

Comparison of the thermodynamic entropy with Boltzmann's principle shows that under conditions of constant volume the total number of arrangements in simple thermodynamic systems with temperature-independent heat capacities is TC/k. A…

综合物理 · 物理学 2009-11-13 David Sands

Boltzmann provided a scenario to explain why individual macroscopic systems composed of a large number $N$ of microscopic constituents are inevitably (i.e., with overwhelming probability) observed to approach a unique macroscopic state of…

数学物理 · 物理学 2017-11-23 Stephan De Bievre , Paul E. Parris

The Madelung equations map the non-relativistic time-dependent Schrodinger equation into hydrodynamic equations of a virtual fluid. Here we show that an increase of the Boltzmann entropy of this Madelung fluid is proportional to the…

量子物理 · 物理学 2016-06-10 Eyal Heifetz , Roumen Tsekov , Eliahu Cohen , Zohar Nussinov

The aim of this work is to analyze the entropy, entropy flux and entropy supply rate of granular fluids within the frameworks of the Boltzmann equation and continuum thermodynamics. It is shown that the entropy inequality for a granular gas…

统计力学 · 物理学 2010-11-17 Gilberto M. Kremer

A question that is currently highly debated is whether the microcanonical entropy should be expressed as the logarithm of the phase volume (volume entropy, also known as the Gibbs entropy) or as the logarithm of the density of states…

统计力学 · 物理学 2015-05-28 Michele Campisi

One of the few accepted dynamical foundations of non-additive "non-extensive") statistical mechanics is that the choice of the appropriate entropy functional describing a system with many degrees of freedom should reflect the rate of growth…

统计力学 · 物理学 2017-09-22 Nikolaos Kalogeropoulos

Within its range of applicability, the Boltzmann equation seems unique in its capacity to accurately describe the transition from almost any initial state to a self-equilibrated thermal state. Using information-theoretic methods to rephrase…

统计力学 · 物理学 2025-10-07 Jürgen T. Stockburger

The concept of entropy connects the number of possible configurations with the number of variables in large stochastic systems. Independent or weakly interacting variables render the number of configurations scale exponentially with the…

统计力学 · 物理学 2020-06-25 Sámuel G. Balogh , Gergely Palla , Péter Pollner , Dániel Czégel
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