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We improve on our version of the second law of thermodynamics as a deterministic theorem for quantum spin systems in two basic aspects. The first concerns the general statement of the second law: spontaneous changes in an adiabatically…

量子物理 · 物理学 2026-04-14 Walter F. Wreszinski

In quantum statistical mechanics, equilibrium states have been shown to be the typical states for a system that is entangled with its environment, suggesting a possible identification between thermodynamic and von Neumann entropies. In this…

量子物理 · 物理学 2017-06-28 Thibaut Josset

The second law of thermodynamics states that the entropy of an isolated system can only increase over time. This appears to conflict with the reversible evolution of isolated quantum systems under the Schr\"odinger equation, which preserves…

量子物理 · 物理学 2025-01-16 Florian Meier , Tom Rivlin , Tiago Debarba , Jake Xuereb , Marcus Huber , Maximilian P. E. Lock

We treat a quantum mechanical system with certain general properties which are expected to be common in macroscopic quantum systems. Starting from a PURE initial state (which may not describe an equilibrium) in which energy is mildly…

统计力学 · 物理学 2007-05-23 Hal Tasaki

The essence of the second law of classical thermodynamics is the `entropy principle' which asserts the existence of an additive and extensive entropy function, S, that is defined for all equilibrium states of thermodynamic systems and whose…

数学物理 · 物理学 2007-05-23 Elliott H. Lieb , Jakob Yngvason

The 2nd law of thermodynamics yields an irreversible increase in entropy until thermal equilibrium is achieved. This irreversible increase is often assumed to require large and complex systems to emerge from the reversible microscopic laws…

统计力学 · 物理学 2023-11-21 Ralph V. Chamberlin

It exists a large class of systems for which the traditional notion of extensivity breaks down. From experimental examples we induce two general hypothesis concerning such systems. In the first the existence of an internal coordinate system…

统计力学 · 物理学 2015-03-09 J-P. Badiali , A. El Kaabouchi

In a macroscopic (quantum or classical) Hamiltonian system, we prove the second law of thermodynamics in the forms of the minimum work principle and the law of entropy increase, under the assumption that the initial state is described by a…

统计力学 · 物理学 2007-05-23 Hal Tasaki

A microscopic definition of the thermodynamic entropy in an isolated quantum system must satisfy (i) additivity, (ii) extensivity and (iii) the second law of thermodynamics. We show that the diagonal entropy, which is the Shannon entropy in…

统计力学 · 物理学 2015-03-30 Tatsuhiko N. Ikeda , Naoyuki Sakumichi , Anatoli Polkovnikov , Masahito Ueda

We re-interprete the microcanonical conditions in the quantum domain as constraints for the interaction of the "gas-subsystem" under consideration and its environment ("container"). The time-average of a purity-measure is found to equal the…

量子物理 · 物理学 2009-11-07 Jochen Gemmer , Alexander Otte , Guenter Mahler

Based on quantum statistical mechanics and microscopic quantum dynamics, we prove Planck's and Kelvin's principles for macroscopic systems in a general and realistic setting. We consider a hybrid quantum system that consists of the…

统计力学 · 物理学 2016-05-04 Hal Tasaki

In the scientific and engineering literature, the second law of thermodynamics is expressed in terms of the behavior of entropy in reversible and irreversible processes. According to the prevailing statistical mechanics interpretation the…

量子物理 · 物理学 2007-05-23 Elias P. Gyftopoulos , Gian Paolo Beretta

The irreversible entropy increase described by the second law of thermodynamics is fundamentally tied to thermalization and the emergence of equilibrium. In the first part of our work (Ref: arXiv.2503.04152), we constructed an isolated gas…

量子物理 · 物理学 2025-11-24 Xue-Yi Guo

This thesis investigates the connection between quantum theory, thermodynamics and information theory. Theories with structure similar to that of quantum theory are considered, mathematically described by the framework of "Generalized…

量子物理 · 物理学 2015-08-14 Marius Krumm

The second law of thermodynamics states that for a thermally isolated system entropy never decreases. Most physical processes we observe in nature involve variations of macroscopic quantities over spatial and temporal scales much larger…

高能物理 - 理论 · 物理学 2017-02-20 Paolo Glorioso , Hong Liu

We show that the conservation and the non-additivity of the information, together with the additivity of the entropy make the entropy increase in an isolated system. The collapse of the entangled quantum state offers an example of the…

量子物理 · 物理学 2009-11-13 Qi-Ren Zhang

A system composed of identical spins and described by a quantum mechanical pure state is analyzed within the statistical framework presented in Part I of this work. We explicitly derive the typical values of the entropy, of the energy, and…

量子物理 · 物理学 2010-07-22 Barbara Fresch , Giorgio J. Moro

The second law of thermodynamics is discussed and reformulated from a quantum information theoretic perspective for open quantum systems using relative entropy. Specifically, the relative entropy of a quantum state with respect to…

量子物理 · 物理学 2020-11-11 Neil Dowling , Stefan Floerchinger , Tobias Haas

The second law of ordinary thermodynamics and the second law of steady state thermodynamics, as proposed by Oono and Paniconi, are investigated from the microscopic point of view for the open quantum system. Based on the H-theorem of…

统计力学 · 物理学 2007-05-23 Satoshi Yukawa

The second law of thermodynamics states that the entropy of an isolated system is almost always increasing. We propose combinatorial formalizations of the second law and explore their conditions of possibilities.

组合数学 · 数学 2017-06-27 Rafael Diaz , Sergio Villamarin
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