相关论文: Phase boundaries and the Widom line from the Ruppe…
In the present paper we propose the van der Waals-like model, which allows a purely analytical study of fluid properties including the equation of state, phase behavior and supercritical fluctuations. We take a square-well system as an…
We construct a novel approach, based on thermodynamic geometry, to characterize first-order phase transitions from a microscopic perspective, through the scalar curvature in the equilibrium thermodynamic state space. Our method resolves key…
Thermodynamic geometry of two-dimensional fluids has been investigated using a square-well model as a prototype fluid. A comparison with the three-dimensional case is performed in the subcritical and supercritical domains of thermodynamic…
In the framework of the van-der-Waals model, analytical expressions for the locus of extrema (ridges) for heat capacity, thermal expansion coefficient, compressibility, density fluctuation, and sound velocity in the supercritical region…
The square-well fluid with hard-sphere diameters is studied within the framework of Thermodynamic Geometry (TG). Coexistence and spinodal curves, as well as the Widom line for ranges $\lambda^{*} = 1.25, 1.5, 2.0, 3.0$ for this fluid are…
We establish the parameter space geometry of a fluid system characterized by two constants, whose equation of state mimics that of the RN-AdS black hole. We call this the RN-AdS fluid. We study the scalar curvature on the parameter space of…
Differential geometry is powerful tool to analyze the vapor-liquid critical point on the surface of the thermodynamic equation of state. The existence of usual condition of the critical point $\left( \partial p/\partial V\right) _{T}=0$…
Originally considered for van der Waals fluids and charged black holes [Phys. Rev. Lett. 123, 071103 (2019)], we extend and generalize our approach to higher-dimensional charged AdS black holes. Beginning with thermodynamic fluctuations, we…
The celebrated van der Waals model describes simple fluids in the thermodynamic limit and predicts the existence of a critical point associated to the gas-liquid phase transition. However the behaviour of critical isotherms according to the…
We study information geometry of the thermodynamics of first and second order phase transitions, and beyond criticality, in magnetic and liquid systems. We establish a universal microscopic characterization of such phase transitions via the…
This work proposes a classification algorithm based on the radical Voronoi tessellation to define the Widom delta, supercritical gas-liquid coexistence region, of polyatomic molecules. In specific, we use a weighted mean-field…
A common approach to quantify excess dissipation in slowly driven thermodynamic processes is through the use of a Riemannian metric on the space of control parameters, where optimal driving protocols follow geodesics. Near phase…
In this work the interface system of the van der Waals fluid is investigated by using the density gradient theory incorporated with the mean-field theory. Based on the mean-field dividing interface generated by the Maxwell construction, we…
Critical phenomena emerging from the critical end point of a first-order transition are ubiquitous in nature. Here we bring the concept of a supercritical crossover, the Widom line, initially developed in the context of fluids, into the…
The well-known Maxwell construction[1] (the equal-area rule, EAR) was devised for vapor liquid equilibrium (VLE) calculation with the van der Waals (vdW) equation of state (EoS)[2]. The EAR generates an intermediate volume between the…
The $P$-$V$ phase transition of the FRW (Friedmann-Robertson-Walker) universe with a perfect fluid has recently been investigated, revealing that the four critical exponents near the critical point are consistent with the values predicted…
We study the critical droplet for a close-to-equilibrium Widom-Rowlinson model of interacting particles, represented by disks of radius $1$, in the two-dimensional plane at low temperature. The critical droplet is the set of macroscopic…
The explicit relations between the thermodynamic functions of the Lattice Gas model and the fluid within the framework of approach proposed earlier in [V. L. Kulinskii, J. Phys. Chem. B \textbf{114} 2852 (2010)] are derived. It is shown…
An electronically coarse-grained model for water reveals a persistent vestige of the liquid-gas transition deep into the supercritical region. A crossover in the density dependence of the molecular dipole arises from the onset of…
This work presents a pedagogical derivation of the thermodynamics of a van der Waals fluid by explicitly incorporating pairwise molecular interactions and the finite size of particles into the statistical-mechanical description. Starting…