相关论文: The mean-field dividing interface is united with t…
In this work we define a mean-field crossover generated by the Maxwell construction as the dividing interface for the vapor-liquid interface area. A highly accurate density-profile equation is thus derived, which is physically favorable and…
In this work the interface system of the van der Waals fluid is investigated by using the density gradient theory incorporated with the mean-field theory. Based on the mean-field dividing interface generated by the Maxwell construction, we…
The well-known Maxwell construction[1] (the equal-area rule, EAR) was devised for vapor liquid equilibrium (VLE) calculation with the van der Waals (vdW) equation of state (EoS)[2]. The EAR generates an intermediate volume between the…
We consider the scaling limit of a generic ferromagnetic system with a continuous phase transition, on the half plane with boundary conditions leading to the equilibrium of two different phases below criticality. We use general properties…
We present a series of theoretical studies of the boundary between a superfluid and normal region in a partially polarized gas of strongly interacting fermions. We present mean-field estimates of the surface energy in this boundary as a…
The celebrated van der Waals model describes simple fluids in the thermodynamic limit and predicts the existence of a critical point associated to the gas-liquid phase transition. However the behaviour of critical isotherms according to the…
We study the asymptotic limit of diffused surface energy in the van der Waals--Cahn--Hillard theory when an advection term is added and the energy is uniformly bounded. We prove that the limit interface is an integral varifold and the…
We present a thermodynamic theory of plane coherent solid-solid interfaces in multicomponent systems subject to nonhydrostatic mechanical stresses. The interstitial and substitutional chemical components are treated separately using…
We construct a mean-field formulation of the thermodynamics of ion solvation in immiscible polar binary mixtures. Assuming an equilibrium planar interface separating two semi-infinite regions of different constant dielectric medium, we…
In the present paper we propose the van der Waals-like model, which allows a purely analytical study of fluid properties including the equation of state, phase behavior and supercritical fluctuations. We take a square-well system as an…
We analyze the ground state properties of Bose-Fermi mixtures using a mean-field treatment of the boson-fermion interaction on a simple cubic lattice. In the deep superfluid limit of the bosonic sector and the BCS regime of the fermion…
In mean-field theory, the non-local state of fluid molecules can be taken into account using a statistical method. The molecular model combined with a density expansion in Taylor series of the fourth order yields an internal energy value…
A new diffuse interface model has been proposed in this study for simulating binary alloy solidification under universal cooling conditions, involving both equilibrium and non-equilibrium solute partitioning. Starting from the Gibbs-Thomson…
We consider simple mean field continuum models for first order liquid-liquid demixing and solid-liquid phase transitions and show how the Maxwell construction at phase coexistence emerges on going from finite-size closed systems to the…
It is difficult to derive the solid-fluid transition theoretically from microscopic models, although this phenomenon itself has been investigated for a long time. We previously constructed an exactly-solvable model with the solid-fluid…
The paper is devoted to the thermodynamics of normal surface electromagnetic fields within a nonuniform dispersive and absorptive system. This system is formed by vacuum and lossy medium separated by a plane interface. As a medium, we used…
A phase-field model that allows for quantitative simulations of low-speed eutectic and peritectic solidification under typical experimental conditions is developed. Its cornerstone is a smooth free-energy functional, designed so that the…
The experimentally established phase diagram of the half-filled Hubbard model features the existence of three distinct finite-temperature regimes, separated by extended crossover regions. A number of crossover lines can be defined to span…
We investigate generalized potentials for a mean-field density functional theory of a three-phase contact line. Compared to the symmetrical potential introduced in our previous article [1], the three minima of these potentials form a small…
In this work, a thermodynamically consistent and conservative diffuse-interface model for gas-liquid-solid multiphase flows is proposed. In this model, a novel free energy for the gas-liquid-solid multiphase flows is established according…