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We perform local nanoscale studies of the surface and interface structure of hydrogen intercalated graphene on 4H-SiC(1000). In particular, we show that intercalation of the interfacial layer results in the formation of quasi-free standing…

The atomistic structure of the graphene buffer layer on Si-terminated SiC is studied using a modified environment-dependent interatomic potential (EDIP). The investigation of equilibrium state by conjuguate gradients suffers from a complex…

材料科学 · 物理学 2011-07-26 Evelyne Lampin , Catherine Priester , Christophe Krzeminski , Laurence Magaud

Cross-sectional transmission electron microscopy (TEM) is used to characterize an amorphous layer observed at the interface in graphite and graphene films grown via thermal decomposition of C-face 4H-SiC. The amorphous layer does not to…

材料科学 · 物理学 2015-05-28 R. Colby , M. L. Bolen , M. A. Capano , E. A. Stach

Annealing the Ru metal that typically contains residual carbon impurities offers a facile way to grow graphene on Ru(0001) at the macroscopic scale. Two superstructures of the graphene/Ru(0001) interface with periodicities of 3.0-nm and…

材料科学 · 物理学 2011-11-09 De-en Jiang , Mao-Hua Du , Sheng Dai

Angle-resolved photoemission and X-ray diffraction experiments show that multilayer epitaxial graphene grown on the SiC(000-1) surface is a new form of carbon that is composed of effectively isolated graphene sheets. The unique rotational…

Quasi-free standing epitaxial graphene is obtained on SiC(0001) by hydrogen intercalation. The hydrogen moves between the 6root3 reconstructed initial carbon layer and the SiC substrate. The topmost Si atoms which for epitaxial graphene are…

材料科学 · 物理学 2009-12-11 C. Riedl , C. Coletti , T. Iwasaki , A. A. Zakharov , U. Starke

We present a structural analysis of the multi-layer graphene-4HSiC(000-1}) system using Surface X-Ray Reflectivity. We show for the first time that graphene films grown on the C-terminated (000-1}) surface have a graphene-substrate bond…

材料科学 · 物理学 2009-11-13 J. Hass , R. Feng , J. E. Millan-Otoya , X. Li , M. Sprinkle , P. N. First , C. Berger , W. A. de Heer , E. H. Conrad

Terrace-sized, single-orientation graphene can be grown on top of a carbon buffer layer on silicon carbide by thermal decomposition. Despite its homogeneous appearance, a surprisingly large variation in electron transport properties is…

介观与纳米尺度物理 · 物理学 2023-03-21 Tobias A. de Jong , Luuk Visser , Johannes Jobst , Ruud M. Tromp , Sense Jan van der Molen

We present a systematical study via scanning tunneling microscopy (STM) and low-energy electron diffraction (LEED) on the effect of the exposure of Lithium (Li) on graphene on silicon carbide (SiC). We have investigated Li deposition both…

材料科学 · 物理学 2017-09-29 Sara Fiori , Yuya Murata , Stefano Veronesi , Antonio Rossi , Camilla Coletti , Stefan Heun

We use scanning tunneling microscopy and spectroscopy to study epitaxial graphene grown on a C-face 4H-SiC(000-1) substrate. The results reveal amazing nano-objects at the graphene/SiC interface leading to electronic interface states. Their…

介观与纳米尺度物理 · 物理学 2009-11-12 S. Vizzini , H. Enriquez , S. Chiang , H. Oughaddou , P. Soukiassian

We develop a strategy for graphene growth on Ru(0001) followed by silicon-layer intercalation that not only weakens the interaction of graphene with the metal substrate but also retains its superlative properties. This G/Si/Ru architecture,…

We present a scanning tunneling spectroscopy (STS) study of the local electronic structure of single and bilayer graphene grown epitaxially on a SiC(0001) surface. Low voltage topographic images reveal fine, atomic-scale carbon networks,…

The morphology of graphene formed on the (000-1) surface (the C-face) and the (0001) surface (the Si-face) of SiC, by annealing in ultra-high vacuum or in an argon environment, is studied by atomic force microscopy and low-energy electron…

材料科学 · 物理学 2015-05-20 Luxmi , N. Srivastava , Guowei He , R. M. Feenstra

Recent transport measurements on thin graphite films grown on SiC show large coherence lengths and anomalous integer quantum Hall effects expected for isolated graphene sheets. This is the case eventhough the layer-substrate epitaxy of…

Graphene on SiC intercalated with two-dimensional metal layers, such as Pt, offers a versatile platform for applications in spintronics, catalysis, and beyond. Recent studies have demonstrated that Pt atoms can intercalate at the…

材料科学 · 物理学 2025-02-28 Letizia Ferbel , Stefano Veronesi , Antonio Rossi , Stiven Forti , Camilla Coletti , Stefan Heun

We address the energetic stability of the graphene/SiC(0001) interface and the associated binding mechanism by studying a series of low-strain commensurate interface structures within a density functional scheme. Among the structures with…

介观与纳米尺度物理 · 物理学 2012-05-23 Gabriele Sclauzero , Alfredo Pasquarello

Two-dimensional silicon carbide stands out among 2D materials, primarily due to its notable band gap, unlike its carbon-based counterparts. However, the binary nature and non-layered structure of bulk SiC present challenges in fabricating…

材料科学 · 物理学 2024-11-26 Arushi Singh , Vikram Mahamiya , Alok Shukla

We demonstrate a technique to produce thin graphene layers on C-face of SiC under ultra high vacuum conditions. A stack of two SiC substrates comprising a half open cavity at the interface is used to partially confine the depleted Si atoms…

材料科学 · 物理学 2013-04-23 C. Celebi , C. Yanik , A. G. Demirkol , Ismet I. Kaya

We present an investigation of large, isolated, graphene ribbons grown on the C-face of on-axis semi-insulating 6H-SiC wafers. Using a graphite cap to cover the SiC sample, we modify the desorption of the Si species during the Si…

材料科学 · 物理学 2013-05-29 N. Camara , G. Rius , J-R. Huntzinger , A. Tiberj , N. Mestres , F. Perez-Murano , P. Godignon , J. Camassel

We propose a table-top method to obtain bilayer quasi-free-standing epitaxial-graphene (QFSEG) on SiC(0001). By applying a microwave annealing in air to a monolayer epitaxial graphene (EG) grown on SiC(0001), the buffer layer is decoupled…

介观与纳米尺度物理 · 物理学 2017-05-19 Kwan-Soo Kim , Goon-Ho Park , Hirokazu Fukidome , Someya Takashi , Iimori Takushi , Komori Fumio , Matsuda Iwao , Maki Suemitsu