相关论文: A semi empirical expression of the virial coeffici…
The fourth virial coefficient is calculated exactly for a fluid of hard spheres in odd dimensions up to 11.
The problem of demixing in a binary fluid mixture of highly asymmetric additive hard spheres is revisited. A comparison is presented between the results derived previously using truncated virial expansions for three finite size ratios with…
A simple recipe to derive the compressibility factor of a multicomponent mixture of d-dimensional additive hard spheres in terms of that of the one-component system is proposed. The recipe is based (i) on an exact condition that has to be…
We propose an improved viscosity model accounting for experiments of emulsions of two immiscible liquids at arbitrary volume fractions and low shear rates. The model is based on a recursive-differential method formulated in terms of the…
A recently derived method [R. D. Rohrmann and A. Santos, Phys. Rev. E. {\bf 76}, 051202 (2007)] to obtain the exact solution of the Percus-Yevick equation for a fluid of hard spheres in (odd) $d$ dimensions is used to investigate the…
We present the full thermodynamics of a fluid confined by an arbitrary external potential based on the virial expansion of the grand potential. The fluid may be classical or quantum and it is assumed that interatomic interactions are…
We compute the fourth virial coefficient of a binary nonadditive hard-sphere mixture over a wide range of deviations from diameter additivity and size ratios. Hinging on this knowledge, we build up a $y$ expansion [B. Barboy and W. N.…
Hard sphere systems in two dimensions are examined for arbitrary density. Simulation results are compared to the theoretical predictions for both the low and the high density limit, where the system is either disordered or ordered,…
In the spirit of the White-Bear version of fundamental measure theory we derive a new density functional for hard-sphere mixtures which is based on a recent mixture extension of the Carnahan-Starling equation of state. In addition to the…
A correlation between maxima in virial coefficients (Bn), and "kissing" numbers for hard hyper-spheres up to dimension D=5, indicates a virial equation and close-packing relationship. Known virial coefficients up to B7, both for hard…
Two-component, ideal, self-gravitating fluids are conceived as macrogases, and the related equation of state is expressed using the virial theorem for subsystems, under the restriction of homeoidally striated density profiles. Shallower…
In this article we report on a study of the near-wall dynamics of suspended colloidal hard spheres over a broad range of volume fractions. We present a thorough comparison of experimental data with predictions based on a virial…
The fourth virial coefficient is calculated exactly for a fluid of hard spheres in even dimensions. For this purpose the complete star cluster integral is expressed as the sum of two three-folded integrals only involving spherical angular…
In this note, we propose a simple derivation of the one dimensional hard rod equation of state, with and without a Kac tail (appended long range and weak potential). The case of hard spheres in higher dimension is also addressed and it is…
A new method of estimating high-order virial coefficients for fluids composed of equal three-dimensional rigid spheres is proposed. The predicted $B_{11}$ and $B_{12}$ values are in good agreement with reliable estimates previously…
Hard spheres are a central and important model reference system for both homogeneous and inhomogeneous fluid systems. In this paper we present new high-precision molecular-dynamics computer simulations for a hard sphere fluid at a planar…
Here we present new results obtained for the equation of state with induced surface and curvature tensions. The explicit formulas for the first five virial coefficients of system pressure and for the induced surface and curvature tension…
The exact transfer-matrix solution for the longitudinal equilibrium properties of the single-file hard-disk fluid is used to study the limiting low- and high-pressure behaviors analytically as functions of the pore width. In the…
Model of hard sphere system is important part of modern theories of liquids. Radial distribution function of hard sphere fluid represented in form of explicit analytical expression allows to obtain thermodynamic potentials in analytical…
The structural properties of single component fluids of hard hyperspheres in odd space dimensionalities $d$ are studied with an analytical approximation method that generalizes the Rational Function Approximation earlier introduced in the…