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We study the boundary layer solution to singular perturbation problems involving Poisson-Boltzmann (PB) type equations with a small parameter $\epsilon$ in general bounded smooth domains (including multiply connected domains) under the…

偏微分方程分析 · 数学 2025-06-27 Jhih-Hong Lyu , Tai-Chia Lin

With a small parameter $\epsilon$, Poisson-Nernst-Planck (PNP) systems over a finite one-dimensional (1D) spatial domain have steady state solutions, called 1D boundary layer solutions, which profiles form boundary layers near boundary…

偏微分方程分析 · 数学 2015-06-30 Chia-Yu Hsieh , Tai-Chia Lin

In a continuum model of the solvation of charged molecules in an aqueous solvent, the classical Poisson-Boltzmann (PB) theory is generalized to include the solute point charges and the dielectric boundary that separates the high-dielectric…

最优化与控制 · 数学 2021-09-29 Bo Li , Zhengfang Zhang , Shenggao Zhou

In this chapter we review the electrostatic properties of charged membranes in aqueous solutions, with or without added salt, employing simple physical models. The equilibrium ionic profiles close to the membrane are governed by the…

软凝聚态物质 · 物理学 2023-01-05 Tomer Markovich , David Andelman , Rudi Podgornik

The Poisson-Boltzmann (PB) equation provides a mean-field theory of electrolyte solutions at interfaces and in confinement, describing how ions reorganize close to charged surfaces to form the so-called electrical double layer (EDL), with…

软凝聚态物质 · 物理学 2024-09-10 Cecilia Herrero , Laurent Joly

We consider the Poisson-Boltzmann equation in a periodic cell, representative of a porous medium. It is a model for the electrostatic distribution of $N$ chemical species diluted in a liquid at rest, occupying the pore space with charged…

偏微分方程分析 · 数学 2015-04-24 Gregoire Allaire , Jean-Francois Dufreche , Andro Mikelic , Andrey Piatnitski

We study steady Boltzmann equation in half-space, which arises in the Knudsen boundary layer problem, with diffusive reflection boundary conditions. Under certain admissible conditions and the source term decaying exponentially, we…

偏微分方程分析 · 数学 2021-04-09 Yong Wang , Feimin Huang

Poisson-Boltzmann theory is the cornerstone for soft matter electrostatics. We provide novel exact analytical solutions to this non-linear mean-field approach, for the diffuse layer of ions in the vicinity of a planar or a cylindrical…

软凝聚态物质 · 物理学 2020-01-29 L. Samaj , E. Trizac

The Poisson--Boltzmann equation is widely used to model electrostatics in molecular systems. Available software packages solve it using finite difference, finite element, and boundary element methods, where the latter is attractive due to…

计算物理 · 物理学 2025-12-24 Michal Bosy , Matthew W. Scroggs , Timo Betcke , Erik Burman , Christopher D. Cooper

The description of a conducting medium in thermal equilibrium, such as an electrolyte solution or a plasma, involves nonlinear electrostatics, a subject rarely discussed in the standard electricity and magnetism textbooks. We consider in…

化学物理 · 物理学 2018-08-01 C. G. Gray , P. J. Stiles

Consider the steady Boltzmann equation with slab symmetry for a monatomic, hard sphere gas in a half space. At the boundary of the half space, it is assumed that the gas is in contact with its condensed phase. The present paper discusses…

偏微分方程分析 · 数学 2021-03-19 Niclas Bernhoff , François Golse

A numerical method using implicit surface representations is proposed to solve the linearized Poisson-Boltzmann equations that arise in mathematical models for the electrostatics of molecules in solvent. The proposed method used an implicit…

数值分析 · 数学 2018-04-04 Yimin Zhong , Kui Ren , Richard Tsai

In this work a dynamical system approach is taken to systematically investigate the one-dimensional classical Poisson-Boltzmann (PB) equation with various boundary conditions. This framework, particularly, the phase space portrait, has a…

经典分析与常微分方程 · 数学 2024-07-01 Kaiyin Huang , Weishi Liu

Numerical solution of the Poisson equation in metallic enclosures, open at one or more ends, is important in many practical situations such as High Power Microwave (HPM) or photo-cathode devices. It requires imposition of a suitable…

计算物理 · 物理学 2015-10-16 Debabrata Biswas , Gaurav Singh , Raghwendra Kumar

The present work deals with the resolution of the Poisson equation in a bounded domain made of a thin and periodic layer of finite length placed into a homogeneous medium. We provide and justify a high order asymptotic expansion which takes…

偏微分方程分析 · 数学 2015-06-24 Bérangère Delourme , Kersten Schmidt , Adrien Semin

For the structure of the thin electrical double layer~(EDL) and the property related to the EDL capacitance, we analyze boundary layer solutions (corresponding to the electrostatic potential) of a non-local elliptic equation which is a…

偏微分方程分析 · 数学 2018-07-31 Chiun-Chang Lee

The non-linear Poisson-Boltzmann equation for a circular, uniformly charged platelet, confined together with co- and counter-ions to a cylindrical cell, is solved semi-analytically by transforming it into an integral equation and solving…

软凝聚态物质 · 物理学 2009-10-31 R. J. F. Leote de Carvalho , E. Trizac , J. P Hansen

The classical problem of two uniformly charged infinite planes in electrochemical equilibrium with an infinite monovalent salt reservoir is solved exactly at the mean-field nonlinear Poisson-Boltzmann (PB) level, including an explicit…

软凝聚态物质 · 物理学 2009-11-07 M. N. Tamashiro , H. Schiessel

Given a smooth bounded domain $\mathcal{D}$ in $\mathbb{R}^N$ with $N\geq3$, we study the existence and the profile of positive solutions for the following elliptic Nenumann problem $$\begin{cases}-\Delta…

偏微分方程分析 · 数学 2021-10-12 Yibin Zhang

The Poisson-Boltzmann equation offers an efficient way to study electrostatics in molecular settings. Its numerical solution with the boundary element method is widely used, as the complicated molecular surface is accurately represented by…

数值分析 · 数学 2021-08-25 Stefan D. Search , Christopher D. Cooper , Elwin van't Wout
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