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We present a massive-parallel implementation of the resolution-of-identity (RI) coupled-cluster approach that includes single, double and perturbatively triple excitations, namely RI-CCSD(T), in the FHI-aims package for molecular systems. A…

计算物理 · 物理学 2018-10-19 Tonghao Shen , Igor Ying Zhang , Matthias Scheffler

This paper proposes a novel higher-order multi-scale (HOMS) computational method, which is highly targeted for efficient, high-accuracy and low-computational-cost simulation of hygro-thermo-mechanical (H-T-M) coupling problems in…

数值分析 · 数学 2025-12-11 Hao Dong , Yifei Ding , Jiale Linghu , Yufeng Nie , Yaochuang Han

Quantum Hamiltonian identification is important for characterizing the dynamics of quantum systems, calibrating quantum devices and achieving precise quantum control. In this paper, an effective two-step optimization (TSO) quantum…

量子物理 · 物理学 2018-06-05 Yuanlong Wang , Daoyi Dong , Bo Qi , Jun Zhang , Ian R. Petersen , Hidehiro Yonezawa

The congruent transformation of the electronic Hamiltonian is developed to address the electron correlation problem in many-electron systems. The central strategy presented in this method is to perform transformation on the electronic…

化学物理 · 物理学 2012-12-21 Jennifer M. Elward , Johannes Hoja , Arindam Chakraborty

A stochastic resolution of identity approach (sRI) is applied to the second-order coupled cluster singles and doubles (CC2) model to calculate the ground-state energy. Utilizing a set of stochastic orbitals to optimize the expensive tensor…

化学物理 · 物理学 2022-10-25 Chongxiao Zhao , Wenjie Dou

We investigate the computational performance of various numerical methods for the integration of the equations of motion and the variational equations for some typical classical many-body models of condensed matter physics: the…

计算物理 · 物理学 2019-05-07 Carlo Danieli , Bertin Many Manda , Mithun Thudiyangal , Charalampos Skokos

Computationally efficient and accurate quantum mechanical approximations to solve the many-electron Schr\"odinger equation are at the heart of computational materials science. In that respect the coupled cluster hierarchy of methods plays a…

The identifiability of a system is concerned with whether the unknown parameters in the system can be uniquely determined with all the possible data generated by a certain experimental setting. A test of quantum Hamiltonian identifiability…

量子物理 · 物理学 2020-11-18 Yuanlong Wang , Daoyi Dong , Akira Sone , Ian R. Petersen , Hidehiro Yonezawa , Paola Cappellaro

Asymptotics-based configuration-interaction (CI) methods [G. Friesecke and B. D. Goddard, Multiscale Model. Simul. 7, 1876 (2009)] are a class of CI methods for atoms which reproduce, at fixed finite subspace dimension, the exact…

量子物理 · 物理学 2012-04-06 Christian Mendl , Gero Friesecke

In this work, we design and analyze a novel, provably conditionally stable, weakly coupled partitioned scheme to solve the conjugate heat transfer (CHT) problem. We consider a model CHT problem consisting of linear advection-diffusion and…

数值分析 · 数学 2026-02-23 Sarah Nataj , David C. Del Rey Fernández , David Brown , Rajeev Jaiman

Efficient implementations of electronic structure methods are essential for first-principles modeling of molecules and solids. We here present a particularly efficient common framework for methods beyond semilocal density-functional theory,…

This study develops a novel multiscale computational method for heat conduction problems of composite structures with diverse periodic configurations in different subdomains. Firstly, the second-order two-scale (SOTS) solutions for these…

数值分析 · 数学 2017-12-08 Hao Dong , Junzhi Cui , Yufeng Nie , Zihao Yang

Four-center two-electron Coulomb integrals routinely appear in electronic structure algorithms. The resolution-of-the-identity (RI) is a popular technique to reduce the computational cost for the numerical evaluation of these integrals in…

化学物理 · 物理学 2024-01-17 Francisco A. Delesma , Moritz Leucke , Dorothea Golze , Patrick Rinke

This paper proposes a novel optimization framework for discrete phase shifts of a reconfigurable intelligent surface (RIS) using a coherent Ising machine (CIM). Unlike conventional methods based on iterative convex approximation or…

The quantum many-body bound-state problem in its computationally successful coupled cluster method (CCM) representation is reconsidered. In conventional practice one factorizes the ground-state wave functions $|\Psi\rangle= e^S…

量子物理 · 物理学 2014-05-02 Raymond F. Bishop , Miloslav Znojil

In this work, we develop a fully implicit Hybrid High-Order algorithm for the Cahn-Hilliard problem in mixed form. The space discretization hinges on local reconstruction operators from hybrid polynomial unknowns at elements and faces. The…

数值分析 · 数学 2016-07-01 Florent Chave , Daniele A. Di Pietro , Fabien Marche , Franck Pigeonneau

The computational cost of simulating quantum many-body systems can often be reduced by taking advantage of physical symmetries. While methods exist for specific symmetry classes, a general algorithm to find the full permutation symmetry…

量子物理 · 物理学 2025-12-01 Saumya Shah , Patrick Rebentrost

It is observed that the Cauchy integral formula (CIF) can be used to represent holomorphic functions of diagonalizable operators on a finite domain. This forms the theoretical foundation for applying various operators in the form of a…

化学物理 · 物理学 2025-07-09 Ke Liao

The recently developed Doubles Connected Moments (DCM) expansion offers a tractable approach for computing correlation energy, exhibiting an noniterative O(N^6) scaling with system size N. Benchmark calculations on a set of molecules…

化学物理 · 物理学 2026-05-12 Chongxiao Zhao , Wenjie Dou

We explore a separable resolution-of-the-identity formalism built on quadratures over limited sets of real-space points designed for all-electron calculations. Our implementation preserves in particular the use of common atomic orbitals and…

化学物理 · 物理学 2019-05-22 Ivan Duchemin , Xavier Blase
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