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An algebraic model based on Lie-algebraic techniques is applied to the analysis of thermodynamic vibrational properties of diatomic molecules. The local anharmonic effects are described by a Morse-like potential and corresponding anharmonic…

统计力学 · 物理学 2007-05-23 Maia Angelova , A. Frank

In this work, improvements are introduced to the current models of the ideal Fermi gas and the ideal Bose gas by incorporating the quantum nature of phase space, which is directly linked to the uncertainty principle. These improved models…

We derive an integral-free thermodynamic perturbation series expansion for quantum partition functions which enables an analytical term-by-term calculation of the series. The expansion is carried out around the partition function of the…

统计力学 · 物理学 2018-05-23 Itay Hen

We introduce a model of the quantum Brownian motion coupled to a classical neat bath by using the operator differential proposed in the quantum analysis. We then define the heat operator by adapting the idea of the stochastic energetics.…

统计力学 · 物理学 2017-09-18 T. Koide

We develop an analytical technique to derive explicit forms of thermodynamical quantities within the asymptotic approach to non-extensive quantum distribution functions. Using it, we find an expression for the number of particles in a boson…

统计力学 · 物理学 2009-10-31 Ugur Tirnakli , Diego F. Torres

We describe a method to compute thermodynamic quantities in the harmonic approximation for identical bosons and fermions in an external confining field. We use the canonical partition function where only energies and their degeneracies…

量子物理 · 物理学 2012-02-16 J. R. Armstrong , N. T. Zinner , D. V. Fedorov , A. S. Jensen

In this work, we present a compact analytical approximation for the quantum partition function of systems composed of quantum oscillators. The proposed formula is general and applicable to an arbitrary number of oscillators described by a…

统计力学 · 物理学 2025-07-08 Michel Caffarel

This work deals with the physical system governed by a Hamiltonian operator, in two-dimensional space, of spinless charged particles subject to a perpendicular magnetic field B, coupled with a harmonic potential in the context of…

统计力学 · 物理学 2025-04-30 Bienvenu Gnim Adewi , Isiaka Aremua , Laure Gouba

The quantum states representing classical phase space are given, and these are used to formulate quantum statistical mechanics as a formally exact double perturbation expansion about classical statistical mechanics. One series of quantum…

量子物理 · 物理学 2016-11-03 Phil Attard

Quantum computing raises the possibility of solving a variety of problems in physics that are presently intractable. A number of such problems involves the physics of systems in or near thermal equilibrium. There are two main ways to…

量子物理 · 物理学 2023-08-16 Carter Ball , Thomas D. Cohen

We study the possibility of applying statistical mechanics to generally covariant quantum theories with a vanishing Hamiltonian. We show that (under certain appropiate conditions) this makes sense, in spite of the absence of a notion of…

广义相对论与量子宇宙学 · 物理学 2009-10-31 Merced Montesinos , Carlo Rovelli

In this article, we investigate the thermal properties of non-relativistic many-body systems at finite temperature and chemical potential. We compute the one-point function of various operators constructed out of the basic fields in ideal…

高能物理 - 理论 · 物理学 2025-03-11 Rajesh Kumar Gupta , Meenu

The non-commutativity of the position and momentum operators is formulated as an effective potential in classical phase space and expanded as a series of successive many-body terms, with the pair term being dominant. A non-linear partial…

量子物理 · 物理学 2020-08-11 Phil Attard

The new scheme employed (throughout the thermodynamic phase space), in the statistical thermodynamic investigation of classical systems, is extended to quantum systems. Quantum Nearest Neighbor Probability Density Functions are formulated…

统计力学 · 物理学 2015-06-25 U. F. Edgal , D. L. Huber

We devise automated workflows for the calculation of Helmholtz and Gibbs free energies and their temperature and pressure dependence and provide the corresponding computational tools. We employ non-equilibrium thermodynamics for evaluating…

材料科学 · 物理学 2021-10-13 Sarath Menon , Yury Lysogorskiy , Jutta Rogal , Ralf Drautz

In this work we reexamine quantum electrodynamics of atomic eletrons in the Coulomb gauge in the dipole approximation and calculate the shift of atomic energy levels in the context of Dalibard, Dupont-Roc and Cohen-Tannoudji (DDC) formalism…

原子物理 · 物理学 2009-11-07 J. L. Tomazelli , L. C. Costa

Nonunitary quantum operations generating thermostatistical states and forming positive operator-valued measures (POVMs) are of current interest as a useful tool for operational approach to quantum thermodynamics. Here, two different…

统计力学 · 物理学 2015-01-23 Yasuyuki Matsuo , Sumiyoshi Abe

In this work, I propose a statistical mechanical framework, for the evaluation of the free energy in molecular systems, by "deleting" all the molecules in a "single" step. The approach can be considered as the statistical mechanics…

统计力学 · 物理学 2011-08-16 Georgios C. Boulougouris

The non extensive thermodynamics of an ideal gas composed by bosons and/or fermions is derived from its partition function for systems with finite chemical potentials. It is shown that the thermodynamical quantities derived in the present…

高能物理 - 唯象学 · 物理学 2014-11-19 Eugenio Megias , Debora P. Menezes , Airton Deppman

Gibbsian statistical mechanics is extended into the domain of non-negligible {though non-specified} correlations in phase space while respecting the fundamental laws of thermodynamics. The appropriate Gibbsian probability distribution is…

统计力学 · 物理学 2014-06-26 R. A. Treumann , W. Baumjohann
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