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We introduce a method to obtain one-dimensional collective variables for studying rarely occurring transitions between two metastable states separated by a high free energy barrier. No previous information, not even approximated, on the…

计算物理 · 物理学 2018-03-09 Dan Mendels , GiovanniMaria Piccini , Michele Parrinello

The current study investigates possible neural mechanisms underling autonomous shifts between focus state and mind-wandering by conducting model simulation experiments. On this purpose, we modeled perception processes of continuous sensory…

神经元与认知 · 定量生物学 2024-12-23 Henrique Oyama , Jun Tani

We analyze phase transitions in the conditional entropy of a sequence caused by a change in the conditional variables. Such transitions happen, for example, when training to learn the parameters of a system, since the transition from the…

信息论 · 计算机科学 2021-01-07 Kang Gao , Bertrand Hochwald

When studying high-dimensional dynamical systems such as macromolecules, quantum systems and polymers, a prime concern is the identification of the most probable states and their stationary probabilities or free energies. Often, these…

数据分析、统计与概率 · 物理学 2013-01-01 Hao Wu , Frank Noé

Simulations with an adaptive time-dependent bias, such as metadynamics, enable an efficient exploration of the conformational space of a system. However, the dynamic information of the system is altered by the bias. With infrequent…

In recent years, significant advancements in computational methods have dramatically enhanced the precision in determining the energetic ranking of different phases of molecular crystals. The developments mainly focused on providing…

Predicting structural and energetic properties of a molecular system is one of the fundamental tasks in molecular simulations, and it has use cases in chemistry, biology, and medicine. In the past decade, the advent of machine learning…

化学物理 · 物理学 2022-08-23 Sajjad Heydari , Stefano Raniolo , Lorenzo Livi , Vittorio Limongelli

We previously developed an algorithm, called resolution exchange, which improves canonical sampling of atomic resolution models by swapping conformations between high- and low-resolution simulations[1]. Here, we demonstrate a generally…

生物物理 · 物理学 2007-05-23 Edward Lyman , Daniel M. Zuckerman

The thesis is aimed to solve the template-free protein folding problem by tackling two important components: efficient sampling in vast conformation space, and design of knowledge-based potentials with high accuracy. We have proposed the…

机器学习 · 计算机科学 2013-11-13 Feng Zhao

Using results from neurobiology on perceptual decision making and value-based decision making, the problem of decision making between lotteries is reformulated in an abstract space where uncertain prospects are mapped to corresponding…

神经元与认知 · 定量生物学 2020-01-03 Adnan Rebei

We propose an adiabatic reweighting algorithm for computing the free energy along an external parameter from adaptive molecular dynamics simulations. The adaptive bias is estimated using Bayes identity and information from all the sampled…

统计力学 · 物理学 2014-04-08 Lingling Cao , Gabriel Stoltz , Tony Lelièvre , Mihai-Cosmin Marinica , Manuel Athènes

The overlap, or similarity, between liquid configurations is at the core of the mean-field description of the glass transition, and remains a useful concept when studying three-dimensional glass-forming liquids. In liquids, however, the…

统计力学 · 物理学 2021-01-05 Benjamin Guiselin , Gilles Tarjus , Ludovic Berthier

Free energy calculation is critical in predictive tasks such as protein folding, docking and design. However, rigorous calculation of free energy change is prohibitively expensive in these practical applications. The minimum potential…

生物大分子 · 定量生物学 2016-03-08 Kai Wang , Lanru Liu , Pu Tian

Popular methods for identifying transition paths between energy minima, such as the nudged elastic band and string methods, typically do not incorporate potential energy curvature information, leading to slow relaxation to the minimum…

计算物理 · 物理学 2019-03-11 Stela Makri , Christoph Ortner , James R. Kermode

A central goal of protein-folding theory is to predict the stochastic dynamics of transition paths --- the rare trajectories that transit between the folded and unfolded ensembles --- using only thermodynamic information, such as a…

生物大分子 · 定量生物学 2018-08-09 William M. Jacobs , Eugene I. Shakhnovich

Jarzynski's equality [1] allows us to investigate free energy landscapes (FELs) by constructing distributions of work performed on a system from an initial ensemble of states to final states. This work is experimentally measured by…

生物物理 · 物理学 2011-05-24 Van Ngo

In this note, conditions for the existence and uniqueness of the maximum likelihood estimate for multidimensional predictor, binary response models are introduced from a sensitivity testing point of view. The well known condition of…

统计计算 · 统计学 2020-11-17 Paul A. Roediger

We present a technique designed for parallelizing large rigid body simulations, capable of exploiting multiple CPU cores within a computer and across a network. Our approach can be applied to simulate both unilateral and bilateral…

图形学 · 计算机科学 2024-03-27 Manas Kale , Paul G. Kry

Empirical force fields employed in molecular dynamics simulations of complex systems can be optimised to reproduce experimentally determined structural and thermodynamic properties. In contrast, experimental knowledge about the rates of…

统计力学 · 物理学 2022-07-12 P. G. Bolhuis , Z. F. Brotzakis , B. G. Keller

We consider a model of two (fully) compact polymer chains, coupled through an attractive interaction. These compact chains are represented by Hamiltonian paths (HP), and the coupling favors the existence of common bonds between the chains.…

统计力学 · 物理学 2009-10-31 S. Franz , T. Garel , H. Orland