相关论文: Second Law in Classical Non-Extensive Systems
The nonextensive statistical ensembles are revisited for the complex systems with long-range interactions and long-range correlations. An approximation, the value of nonextensive parameter (1-q) is assumed to be very tiny, is adopted for…
A heuristic generalization of the Boltzmann-Gibbs microcanonical entropy is proposed, able to describe meta-equilibrium features and evolution of macroscopic systems. Despite its simple-minded derivation, such a function of "collective…
The quest for a microscopic foundation of Thermodynamics is addressed within the Nonunitary Newtonian Gravity model through the study of a specific closed system, namely a three-dimensional harmonic nanocrystal. A numerical calculation of…
We re-interprete the microcanonical conditions in the quantum domain as constraints for the interaction of the "gas-subsystem" under consideration and its environment ("container"). The time-average of a purity-measure is found to equal the…
Some works have appeared in recent accredited literature considering the possibility of macroscopic violations of the second law in simulated as well as really executed experiments. We argue the inexistence of such violations in experiments…
A scheme for treating the Second Law of thermodynamics as a constraint and accounting for the approximate nature of constitutive assumptions in continuum thermomechanics is discussed. An unconstrained, concave, variational principle is…
This work is concerned with our recently developed formalism of non-equilibrium thermodynamics. This formalism extends the classical irreversible thermodynamics which leads to classical thermodynamics and can not describe physical phenomena…
Microcanonical description is characterized by the presence of an internal symmetry closely related with the dynamical origin of this ensemble: the reparametrization invariance. Such symmetry possibilities the development of a non…
We develop a generalized theory of (meta)equilibrium statistical mechanics in the thermodynamic limit valid for both smooth and fractal phase spaces. In the former case, our approach leads naturally to Boltzmann-Gibbs standard…
Descriptions of molecular systems usually refer to two distinct theoretical frameworks. On the one hand the quantum pure state, i.e. the wavefunction, of an isolated system which is determined to calculate molecular properties and to…
We study the statistical mechanics of classical and quantum systems in non-equilibrium steady states. Emphasis is placed on systems in strong thermal gradients. Various measures and functional forms of observables are presented. The quantum…
Time-asymmetric behavior as embodied in the second law of thermodynamics is observed in {\it individual macroscopic} systems. It can be understood as arising naturally from time-symmetric microscopic laws when account is taken of a) the…
In the present paper are considered the self-similarity scaling postulates in order to extend the Thermodynamics to the study of one special class of nonextensive systems: the pseudoextensive, those with exponential behavior for the…
A new microcanonical equilibrium state is introduced for quantum systems with finite-dimensional state spaces. Equilibrium is characterised by a uniform distribution on a level surface of the expectation value of the Hamiltonian. The…
We initially prepare a quantum linear oscillator weakly coupled to a bath in equilibrium at an arbitrary temperature. We disturb this system by varying a Hamiltonian parameter of the coupled oscillator, namely, either its spring constant or…
The essence of the second law of classical thermodynamics is the `entropy principle' which asserts the existence of an additive and extensive entropy function, S, that is defined for all equilibrium states of thermodynamic systems and whose…
It is shown by simple and straightforward considerations that discreteness of basic physical variables is, at least, essential for generalized statistical mechanics with non-logarithmic entropy to be thermodynamically applicable to…
Statistical equilibrium models of coherent structures in two-dimensional and barotropic quasi-geostrophic turbulence are formulated using canonical and microcanonical ensembles, and the equivalence or nonequivalence of ensembles is…
The two-body potential of systems with long-range interactions decays at large distances as $V(r)\sim 1/r^\alpha$, with $\alpha\leq d$, where $d$ is the space dimension. Examples are: gravitational systems, two-dimensional hydrodynamics,…
We give arguments for the existence of a thermodynamics of quantum complexity that includes a "Second Law of Complexity". To guide us, we derive a correspondence between the computational (circuit) complexity of a quantum system of $K$…