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To illustrate Boltzmann's construction of an entropy function that is defined for a microstate of a macroscopic system, we present here the simple example of the free expansion of a one dimensional gas of non-interacting point particles.…

Entropy production is often interpreted as a proxy for microscopic disorder or environmental roughness in stochastic systems. We test this interpretation using controlled simulations of overdamped stochastic dynamics on curved surfaces in…

统计力学 · 物理学 2026-02-23 Patrick Romanescu

Entropy, its production, and its change in a dynamical system can be understood from either a fully stochastic dynamic description or from a deterministic dynamics exhibiting chaotic behavior. By taking the former approach based on the…

数学物理 · 物理学 2025-08-26 Hong Qian , Zhongwei Shen

It is always some constraint that yields any nontrivial structure from statistical averages. As epitomized by the Boltzmann distribution, the energy conservation is often the principal constraint acting on mechanical systems. Here, we…

统计理论 · 数学 2016-07-06 Naoki Sato , Zensho Yoshida

Active matter systems operate far from equilibrium due to the continuous energy injection at the scale of constituent particles. At larger scales, described by coarse-grained models, the global entropy production rate S quantifies the…

The stochastic entropy generated during the evolution of a system interacting with an environment may be separated into three components, but only two of these have a non-negative mean. The third component of entropy production is…

统计力学 · 物理学 2013-05-30 Ian J. Ford , Richard E. Spinney

We investigate, via computer simulations, the time evolution of the (Boltzmann) entropy of a dense fluid not in local equilibrium. The macrovariables $M$ describing the system are the (empirical) particle density $f=\{f(\un{x},\un{v})\}$…

统计力学 · 物理学 2009-11-10 P. L. Garrido , S. Goldstein , J. L. Lebowitz

IIt is demonstrated that the entropy of statistical mechanics and of information theory, $S({\bf p}) = -\sum p_i \log p_i $ may be viewed as a measure of correlation. Given a probability distribution on two discrete variables, $p_{ij}$, we…

数学物理 · 物理学 2007-05-23 John H. Van Drie

Through the consideration of spherically symmetric gravitating systems consisting of perfect fluids with linear equation of state constrained to be in a finite volume, an account is given of the properties of entropy at conditions in which…

广义相对论与量子宇宙学 · 物理学 2008-11-26 Alessandro Pesci

Entropy in thermodynamics is an extensive quantity, whereas standard methods in statistical mechanics give rise to a non-extensive expression for the entropy. This discrepancy is often seen as a sign that basic formulas of statistical…

物理学史与哲学 · 物理学 2012-09-06 Dennis Dieks

Regardless of studies and debates over a century, the statistical origin of the second law of thermodynamics still remains illusive. One essential obstacle is the lack of a proper theoretical formalism for non-equilibrium entropy. Here I…

统计力学 · 物理学 2017-10-18 Xiangjun Xing

The dynamics of molecular collisions in a macroscopic body are encoded by the parameter Thermodynamic entropy - a statistical measure of the number of molecular configurations that correspond to a given macrostate. Directionality in the…

种群与进化 · 定量生物学 2020-05-22 Lloyd Demetrius , Christian Wolf

In this paper, we extend the concept of generalized entropy to uniform spaces, allowing computations beyond metrizable settings. We apply this to parabolic dynamics - systems with a unique fixed point uniformly attracting all compact…

动力系统 · 数学 2025-07-02 Frederico A. C. L. Marinho , Hellen de Paula , Lucas H. R. de Souza

For stochastic non-equilibrium dynamics like a Langevin equation for a colloidal particle or a master equation for discrete states, entropy production along a single trajectory is studied. It involves both genuine particle entropy and…

统计力学 · 物理学 2012-05-21 Udo Seifert

Tsallis' non-extensive entropy is extended to incorporate the dependence on affinities between the microstates of a system. At the core of our construction of the extended entropy ($\mathcal{H}$) is the concept of the effective number of…

定量方法 · 定量生物学 2022-02-08 Keisuke Okamura

Despite substantial progress in non-equilibrium physics, steady-state (s.s.) probabilities remain intractable to analysis. For a Markov process, s.s. probabilities can be expressed in terms of transition rates using the Matrix-Tree theorem…

统计力学 · 物理学 2021-09-07 Ugur Cetiner , Jeremy Gunawardena

The log-periodic equation for the entropy $S = - (k/a) \sum_{i=1}^{N} p_{i} \sin(a \ln p_{i})$, based on the forgotten Sharma-Taneja entropy measure, is studied for the first time with $N$ the total number of system states and $p_{i}$ the…

数据分析、统计与概率 · 物理学 2014-01-21 E. Canessa

We study the entropy production in a macroscopic nonequilibrium system that undergoes an order-disorder phase transition. Entropy production is a characteristic feature of nonequilibrium dynamics with broken detailed balance. It is found…

统计力学 · 物理学 2016-01-20 Pyoung-Seop Shim , Hyun-Myung Chun , Jae Dong Noh

The aim of this work is to analyze the entropy, entropy flux and entropy supply rate of granular fluids within the frameworks of the Boltzmann equation and continuum thermodynamics. It is shown that the entropy inequality for a granular gas…

统计力学 · 物理学 2010-11-17 Gilberto M. Kremer

Entropy plays a key role in statistical physics of complex systems, which in general exhibit diverse aspects of emergence on different scales. However, it still remains not fully resolved how entropy varies with the coarse-graining level…

统计力学 · 物理学 2017-08-07 Segun Goh , Jungzae Choi , MooYoung Choi , Byung-Gook Yoon
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