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Optimal transport (OT) compares probability distributions by computing a meaningful alignment between their samples. CO-optimal transport (COOT) takes this comparison further by inferring an alignment between features as well. While this…

The predictive ability of stochastic chemical reactions is currently limited by the lack of closed form solutions to the governing chemical master equation. To overcome this limitation, this paper proposes a computational method capable of…

定量方法 · 定量生物学 2019-01-08 Yuta Sakurai , Yutaka Hori

The dynamics of the reaction H + OH $\to$ O (3P) + H2 have been studied in a series of quasi-classical trajectory (QCT) calculations and transition state theory (TST) methods using high quality 3A' and 3A'' potential energy surfaces (PESs).…

太阳与恒星天体物理 · 物理学 2014-02-27 Xiaohu Li , Carina Arasa , Marc C. van Hemert , Ewine F. van Dishoeck

Transition path sampling (TPS), which involves finding probable paths connecting two points on an energy landscape, remains a challenge due to the complexity of real-world atomistic systems. Current machine learning approaches use…

机器学习 · 计算机科学 2025-06-27 Sanjeev Raja , Martin Šípka , Michael Psenka , Tobias Kreiman , Michal Pavelka , Aditi S. Krishnapriyan

One of the most important and difficult parts of constructing a multidimensional numerical simulation of flame acceleration and deflagration-to-detonation transition (DDT) in a reacting flow is finding a reliable and affordable model of the…

流体动力学 · 物理学 2017-09-04 Carolyn R. Kaplan , Alp Ozgen , Elaine S. Oran

Optimal Transport (OT) is a mathematical framework that first emerged in the eighteenth century and has led to a plethora of methods for answering many theoretical and applied questions. The last decade has been a witness to the remarkable…

机器学习 · 计算机科学 2024-03-25 Abdelwahed Khamis , Russell Tsuchida , Mohamed Tarek , Vivien Rolland , Lars Petersson

A practical method for finding free energy barriers for transitions in high-dimensional classical and quantum systems is presented and used to calculate the dissociative sticking probability of H2 on a metal surface within transition state…

chem-ph · 物理学 2009-10-22 Gregory Mills , Hannes Jonsson

Finding representative reaction pathways is necessary for understanding mechanisms of molecular processes, but is considered to be extremely challenging. We propose a new method to construct reaction paths based on mean first-passage times.…

化学物理 · 物理学 2015-06-26 Sanghyun Park , Klaus Schulten

Neural network-based optimal transport (OT) is a recent and fruitful direction in the generative modeling community. It finds its applications in various fields such as domain translation, image super-resolution, computational biology and…

机器学习 · 计算机科学 2026-02-25 Roman Tarasov , Petr Mokrov , Milena Gazdieva , Evgeny Burnaev , Alexander Korotin

Deep topological data analysis (TDA) offers a principled framework for capturing structural invariants such as connectivity and cycles that persist across scales, making it a natural fit for anomaly segmentation (AS). Unlike thresholdbased…

计算机视觉与模式识别 · 计算机科学 2026-01-29 Ali Zia , Usman Ali , Umer Ramzan , Abdul Rehman , Abdelwahed Khamis , Wei Xiang

A new database of collisional rate coefficients for transitions between the rotational states of H$_2$O collided with H$_2$ background gas is developed. The goal is to expand over the other existing databases in terms of the rotational…

量子物理 · 物理学 2024-12-18 Carolin Joy , Dulat Bostan , Bikramaditya Mandal , Dmitri Babikov

In order to estimate the reactivity of a large number of potentially complex heterogeneous catalysts while searching for novel and more efficient materials, physical as well as data-centric models have been developed for a faster evaluation…

材料科学 · 物理学 2021-06-28 Lucas Foppa , Luca M. Ghiringhelli

Unbalanced optimal transport (UOT) provides a flexible way to match or compare nonnegative finite Radon measures. However, UOT requires a predefined ground transport cost, which may misrepresent the data's underlying geometry. Choosing such…

机器学习 · 统计学 2026-01-09 Emanuele Pardini , Katerina Papagiannouli

Measuring Sentence Textual Similarity (STS) is a classic task that can be applied to many downstream NLP applications such as text generation and retrieval. In this paper, we focus on unsupervised STS that works on various domains but only…

计算与语言 · 计算机科学 2022-10-06 Zihao Wang , Jiaheng Dou , Yong Zhang

A central object in the computational studies of rare events is the committor function. Though costly to compute, the committor function encodes complete mechanistic information of the processes involving rare events, including reaction…

统计力学 · 物理学 2022-11-23 Muhammad R. Hasyim , Clay H. Batton , Kranthi K. Mandadapu

Efficient and reliable identification and optimization of transition state structures is a longstanding challenge in computational chemistry. Popular chain-of-states methods require hundreds if not thousands of ab initio calculations to…

化学物理 · 物理学 2025-11-27 Diptarka Hait , Jan D. Estrada Pabón , Martin Stöhr , Todd J. Martínez

Transition interface sampling (TIS) and replica exchange TIS (RETIS) are powerful methods for computing rates of rare events inaccessible to straightforward molecular dynamics (MD) simulations. Path reweighting extends their output,…

化学物理 · 物理学 2026-05-15 Titus S. van Erp , Daniel T. Zhang , Elias Wils , Sina Safaei , An Ghysels

A machine learned (ML) model for predicting product state distributions from specific initial states (state-to-distribution or STD) for reactive atom-diatom collisions is presented and quantitatively tested for the N($^4$S)+O$_{2}$(X$^3…

TiCoSb1+x (x=0.0, 0.01, 0.02, 0.03, 0.04, 0.06) samples have been synthesized, employing solid state reaction method followed by arc menting. Theoretical calculations, using Density Functional Theory (DFT) have been performed to estimate…

Optimal transport (OT) is a powerful geometric and probabilistic tool for finding correspondences and measuring similarity between two distributions. Yet, its original formulation relies on the existence of a cost function between the…

机器学习 · 统计学 2020-11-09 Ievgen Redko , Titouan Vayer , Rémi Flamary , Nicolas Courty