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We develop a geometric foundation of microcanonical thermodynamics in which entropy and its derivatives are determined from the geometry of phase space, rather than being introduced through an a priori ensemble postulate. Once the minimal…

统计力学 · 物理学 2025-12-30 Loris Di Cairano

The long standing contrast between Boltzmann's and Gibbs' approach to statistical thermodynamics has been recently rekindled by Dunkel and Hilbert [1], who criticize the notion of negative absolute temperature (NAT), as a misleading…

统计力学 · 物理学 2015-08-31 Loris Ferrari

We develop the stochastic approach to thermodynamics based on the stochastic dynamics, which can be discrete (master equation) continuous (Fokker-Planck equation), and on two assumptions concerning entropy. The first is the definition of…

统计力学 · 物理学 2015-06-11 Tânia Tomé , Mário J. de Oliveira

We review the role of zero-temperature entropy in several closely-related contexts in QCD. The first is entropy associated with disordered condensates, including $< G_{\mu\nu}^2>$. The second is vacuum entropy arising from QCD solitons such…

高能物理 - 唯象学 · 物理学 2012-03-30 John M. Cornwall

The physical foundations of a variety of emerging technologies --- ranging from the applications of quantum entanglement in quantum information to the applications of nonequilibrium bulk and interface phenomena in microfluidics, biology,…

量子物理 · 物理学 2014-03-25 Gian Paolo Beretta , Enzo Zanchini

All of the basic microsopic physical laws are time reversible. In contrast, the second law of thermodynamics, which is a macroscopic physical representation of the world, is able to describe irreversible processes in an isolated system…

化学物理 · 物理学 2015-06-19 Roland Riek

A microscopic understanding of the thermodynamic entropy in quantum systems has been a mystery ever since the invention of quantum mechanics. In classical physics, this entropy is believed to be the logarithm of the volume of phase space…

量子物理 · 物理学 2013-05-08 J. M. Deutsch , Haibin Li , Auditya Sharma

We propose an operational definition of the entropy of cosmological perturbations based on a truncation of the hierarchy of Green functions. The value of the entropy is unambiguous despite gauge invariance and the renormalization procedure.…

高能物理 - 理论 · 物理学 2008-11-26 David Campo , Renaud Parentani

During the past dozen years there have been numerous articles on a relation between entropy and probability which is non-additive and has a parameter $q$ that depends on the nature of the thermodynamic system under consideration. For $q=1$…

统计力学 · 物理学 2009-11-07 Michael Nauenberg

The anisotropic quantum Heisenberg model with Curie-Weiss-type interactions is studied analytically in several variants of the microcanonical ensemble. (Non)equivalence of microcanonical and canonical ensembles is investigated by studying…

统计力学 · 物理学 2014-09-25 Gerrit Olivier , Michael Kastner

Many complex systems are characterized by non-Boltzmann distribution functions of their statistical variables. If one wants to -- justified or not -- hold on to the maximum entropy principle for complex statistical systems (non-Boltzmann)…

统计力学 · 物理学 2009-11-13 Stefan Thurner , Rudolf Hanel

We revisit the issue of defining the entropy of a spatial region in a broad class of quantum theories. In theories with explicit regularizations, working within an elementary but general algebraic framework applicable to matter and gauge…

高能物理 - 理论 · 物理学 2018-09-18 Jennifer Lin , Djordje Radicevic

We define a diagonal entropy (d-entropy) for an arbitrary Hamiltonian system as $S_d=-\sum_n \rho_{nn}\ln \rho_{nn}$ with the sum taken over the basis of instantaneous energy states. In equilibrium this entropy coincides with the…

统计力学 · 物理学 2012-08-10 Anatoli Polkovnikov

The postulates of thermodynamics were originally formulated for macroscopic systems. They lead to the definition of the entropy, which, for a homogeneous system, is a homogeneous function of order one in the extensive variables and is…

统计力学 · 物理学 2018-11-14 Dragos-Victor Anghel , Alexandru S. Parvan

A general framework to describe a vast majority of biology-inspired systems is to model them as stochastic processes in which multiple couplings are in play at the same time. Molecular motors, chemical reaction networks, catalytic enzymes,…

统计力学 · 物理学 2020-11-25 Daniel M. Busiello , Deepak Gupta , Amos Maritan

In this work we study the evolution of Boltzmann's entropy in the context of free expansion of a one dimensional interacting gas inside a box. Boltzmann's entropy is defined for single microstates and is given by the phase-space volume…

统计力学 · 物理学 2023-03-29 Subhadip Chakraborti , Abhishek Dhar , Anupam Kundu

Macroscopic nonextensive thermodynamics is studied without recourse to microscopic statistical mechanics. It is shown that if entropy is nonextensive, the concept of physical temperature introduced through the generalized zeroth law of…

统计力学 · 物理学 2007-05-23 Sumiyoshi Abe

In a recent paper, Dunkel and Hilbert [Nature Physics 10, 67-72 (2014)] use an entropy definition due to Gibbs to provide a 'consistent thermostatistics' which forbids negative absolute temperatures. Here we argue that the Gibbs entropy…

统计力学 · 物理学 2015-01-22 Daan Frenkel , Patrick B Warren

We identify and study classes of initial states in integrable quantum systems that, after the relaxation dynamics following a sudden quench, lead to near-thermal expectation values of few-body observables. In the systems considered here,…

统计力学 · 物理学 2011-09-28 Marcos Rigol , Mattias Fitzpatrick

We examine the minimization of information entropy for measures on the phase space of bounded domains, subject to constraints that are averages of grand canonical distributions. We describe the set of all such constraints and show that it…

数学物理 · 物理学 2019-10-02 Stamatis Dostoglou , Alexander Hughes , Jianfei Xue