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The progress in high performance computing we are witnessing today offers the possibility of accurate electron density calculations of systems in realistic physico-chemical conditions. In this paper, we present a strategy aimed at…

软凝聚态物质 · 物理学 2018-09-18 Giovanni La Penna , Velia Minicozzi , Silvia Morante , Giancarlo Rossi , Francesco Stellato

Resonant inelastic x-ray scattering (RIXS) is a widely used spectroscopic technique, providing access to the electronic structure and dynamics of atoms, molecules, and solids. However, RIXS requires a narrow bandwidth x-ray probe to achieve…

Further technological advancement of both lithium-ion and emerging battery technologies can be catalyzed by an improved understanding of the chemistry and working mechanisms of the solid electrolyte interphases (SEIs) that form at…

AIMS: We present a sample of candidate quasars selected using the KX-technique. The data cover 0.68 deg^2 of the X-ray Multi-Mirror (XMM) Large-Scale Structure (LSS) survey area where overlapping multi-wavelength imaging data permits an…

A method of using X-ray absorption spectroscopy (XAS) together with resolved grazing incidence geometry for depth profiling atomic, electronic, chemical or magnetic local structures in thin films is presented. The quantitative deconvolution…

Resolving transient atomic configurations in non-crystalline or dynamic environments remains a fundamental bottleneck in the physical sciences. While X-ray absorption spectroscopy (XAS) is a premier probe of local structure, inverting…

材料科学 · 物理学 2026-03-31 Suyang Zhong , Boying Huang , Pengwei Xu , Fanjie Xu , Yuhao Zhao , Jun Cheng , Fujie Tang , Weinan E , Zhong-Qun Tian

We present Fe K$\beta$ X-ray emission (XES) and Fe K X-ray absorption spectra (XAS) of Iron(II)sulfide (FeS) and Iron(II)disulfide (FeS$_2$). While XES and XAS offer different discrimination capabilities for chemical speciation, depending…

The Electron Energy-Loss Spectroscopy (EELS) and X-ray Absorption Spectroscopy (XAS) database has been completely rewritten, with an improved design, user interface and a number of new tools. The database is accessible at https://eelsdb.eu/…

材料科学 · 物理学 2016-03-18 Philip Ewels , Thierry Sikora , Virginie Serin , Chris P. Ewels , Luc Lajaunie

We present here an experimental set-up to perform simultaneously measurements of surface plasmon resonance (SPR) and X-ray absorption spectroscopy (XAS) in a synchrotron beamline. The system allows measuring in situ and in real time the…

仪器与探测器 · 物理学 2015-06-04 A. Serrano , O. Rodríguez de la Fuente , V. Collado , J. Rubio-Zuazo , C. Monton , G. Castro , M. A. García

We use a pump-probe scheme to measure the time evolution of the C K-edge X-ray absorption spectrum (XAS) from CO/Ru(0001) after excitation by an ultrashort high-intensity optical laser pulse. Due to the short duration of the X-ray probe…

Helium atom scattering (HAS) is a well established technique for examining the surface structure and dynamics of materials at atomic sized resolution. The HAS technique Helium spin-echo spectroscopy opens up the possibility of compressing…

材料科学 · 物理学 2015-10-05 Alex Jones , Anton Tamtögl , Irene Calvo-Almazán , Anders Hansen

Electron energy loss spectroscopy (EELS) and X-ray absorption spectroscopy (XAS) provide detailed information about bonding, distributions and locations of atoms, and their coordination numbers and oxidation states. However, analysis of…

材料科学 · 物理学 2024-07-11 Samuel P. Gleason , Deyu Lu , Jim Ciston

Applicability and accuracy of traditional scanned-wavelength direct absorption spectroscopy (SDAS) diagnostic method is largely affected by combustion state such as temperature and pressure. To resolve this problem, an innovative…

仪器与探测器 · 物理学 2021-12-06 Yihong Wang

The advent of the X-ray microcalorimeter spectrometer Resolve onboard the XRISM space telescope opened a new era for high-resolution X-ray spectroscopy of astrophysical plasmas. Many spectral features were newly detected, including the K…

Single-particle methods based on Kohn-Sham unoccupied states to describe near-edge X-ray absorption (XAS) spectra are routinely applied for the description of K-edge spectra, as there is no complication due to spin-orbit (SO) coupling. L-…

材料科学 · 物理学 2026-02-26 Esther A. B. Johnsen , Naoki Horiuchi , Toma Susi , Michael Walter

Widely employed Near-Edge X-Ray Absorption Fine Structure (NEXAFS) spectroscopy probes a system by excitation of core electrons to unoccupied states. A variety of different methodologies are available to simulate corresponding spectra from…

化学物理 · 物理学 2019-02-14 Georg S. Michelitsch , Karsten Reuter

Using low energy electron diffraction (LEED), scanning tunnelling microscopy (STM) and x-ray absorption spectroscopy (XAS) techniques, we have studied the first steps of silicon adsorption onto Cu (001) single crystal substrate. For low…

材料科学 · 物理学 2015-06-16 B. Lalmi , M. Chorro , R. Belkhou

We present X-ray absorption spectroscopy and resonant inelastic X-ray scattering (RIXS) measurements on the iron L-edge of 0.5 mM aqueous ferricyanide. These measurements demonstrate the ability of high-throughput transition-edge-sensor…

We develop a first-principles scheme based on the continued fraction approach an d ultrasoft pseudopotentials to calculate K-edge X-ray absorption spectra in solids. The method allows for calculations of K-edge X-ray absorption spectra in…

材料科学 · 物理学 2009-06-29 Christos Gougoussis , Matteo Calandra , Ari P. Seitsonen , Francesco Mauri

X-ray absorption (XAS) and Resonant Inelastic X-ray Scattering (RIXS) spectra of LaPt$_2$Si$_2$ single crystal at the Si L and La N edges are presented. The data are interpreted in terms of density functional theory, showing that the Si…