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The Hartree-Fock approximation of Quantum Electrodynamics provides a rigorous framework for the description of relativistic electrons in external fields. This nonlinear model takes into account the infinitely many virtual electrons of…

数学物理 · 物理学 2012-11-21 Julien Sabin

We review recent results about the derivation and the analysis of two Hartree-Fock-type models for the polarization of vacuum. We pay particular attention to the variational construction of a self-consistent polarized vacuum, and to the…

数学物理 · 物理学 2012-09-28 Philippe Gravejat , Christian Hainzl , Mathieu Lewin , Eric Séré

We study the ground state solutions of the Dirac-Fock model in the case of weak electronic repulsion, using bifurcation theory. They are solutions of a min-max problem. Then we investigate a max-min problem coming from the electron-positron…

数学物理 · 物理学 2009-11-10 Jean-Marie Barbaroux , Maria J. Esteban , Eric Séré

Hartree-Fock theory is supposed to yield a picture of atomic shells which may or may not be filled according to the atom's position in the periodic table. We prove that shells are always completely filled in an exact Hartree-Fock…

凝聚态物理 · 物理学 2009-10-22 V. Bach , E. H. Lieb , M. Loss , J. P. Solovej

The system describing a single Dirac electron field coupled with classically moving point nuclei is presented and studied. The model is a semi-relativistic extension of corresponding time-dependent one-body Hartree-Fock equation coupled…

偏微分方程分析 · 数学 2019-02-05 Federico Cacciafesta , Anne-Sophie de Suzzoni , Diego Noja

Low-energy single-electron dynamics in graphene monolayers and similar nanostructures is described by the Dirac model, being a 2+1 dimensional version of massless QED with the speed of light replaced by the Fermi velocity v_{F}=c/300.…

介观与纳米尺度物理 · 物理学 2017-04-18 S. P. Gavrilov , D. M. Gitman

The Bogoliubov-Dirac-Fock (BDF) model is a no-photon approximation of quantum electrodynamics. It allows to study relativistic electrons in interaction with the Dirac sea. A state is fully characterized by its one-body density matrix, an…

数学物理 · 物理学 2014-09-16 Jérémy Sok

The spherical Hartree-Fock approximation is applied to the $abinitio$ no-core shell model, with a realistic effective nucleon-nucleon interaction in order to investigate the range of its utility. Hartree-Fock results for binding energies,…

核理论 · 物理学 2009-11-10 M. A. Hasan , J. P. Vary , P. Navratil

In this paper we prove well posedness for a system coupling a nonlinear Dirac with a Klein-Gordon equation that represents a toy model for the Helium atom with relativistic corrections: the wave function of the electrons interacts with an…

偏微分方程分析 · 数学 2021-10-19 Federico Cacciafesta , Anne-Sophie de Suzzoni , Long Meng , Jérémy Sok

We study the Bogoliubov-Dirac-Fock model which is a mean-field approximation of QED. It allows to consider relativistic electrons interacting with the Dirac sea. We study the system of two electrons in the vacuum: it has been shown in a…

数学物理 · 物理学 2014-09-16 Jérémy Sok

A comprehensive theoretical understanding of electron-photon correlation is essential for describing the reshaping of molecular orbitals in quantum electrodynamics (QED) environments. The strong coupling QED Hartree-Fock (SC-QED-HF) theory…

化学物理 · 物理学 2024-09-04 Yassir El Moutaoukal , Rosario R. Riso , Matteo Castagnola , Henrik Koch

We study the well-posedness of the reduced Hartree-Fock model for molecules and perfect crystals when taking into account a self-generated magnetic field. We exhibit a critical value $\alpha_c > 0$ such that, if the fine structure constant…

数学物理 · 物理学 2019-09-04 David Gontier , Salma Lahbabi

The Bogoliubov-Dirac-Fock (BDF) model allows to describe relativistic electrons interacting with the Dirac sea. It can be seen as a mean-field approximation of Quantum Electro-dynamics (QED) where photons are neglected. This paper treats…

数学物理 · 物理学 2014-05-16 Jérémy Sok

In this paper, we study the error bound between the Dirac--Fock ground-state energy and the Hartree--Fock ground-state energy, a quantity known as the relativistic effect in quantum mechanics. We confirm that the relativistic effect in the…

数学物理 · 物理学 2026-05-19 Long Meng

Existence of minimizers for the Dirac--Fock model in crystals was recently proved by Paturel and S\'er\'e and the authors \cite{crystals} by a retraction technique due to S\'er\'e \cite{Ser09}. In this paper, inspired by Ghimenti and…

偏微分方程分析 · 数学 2023-07-19 Isabelle Catto , Long Meng

The development of reliable ab initio methods for light-matter strong coupling is necessary for a deeper understanding of molecular polaritons. The recently developed strong coupling quantum electrodynamics Hartree-Fock model (SC-QED-HF)…

化学物理 · 物理学 2025-02-21 Matteo Castagnola , Rosario R. Riso , Yassir El Moutaoukal , Enrico Ronca , Henrik Koch

Building on previous work [N. Read, Phys. Rev. B 58, Z. Dong and T. Senthil, 16262 (1998); Phys. Rev. B 102, 205126 (2020)] on the system of bosons at filling factor $\nu = 1$, we derive the Dirac composite fermion theory for a half-filled…

We study the Hartree-Fock model for pseudorelativistic atoms, that is, atoms where the kinetic energy of the electrons is given by the pseudorelativistic operator \sqrt{(pc)^2+(mc^2)^2}-mc^2. We prove the existence of a Hartree-Fock…

数学物理 · 物理学 2013-10-30 Anna Dall'Acqua , Thomas Østergaard Sørensen , Edgardo Stockmeyer

The familiar unrestricted Hartree-Fock variational principle is generalized to include quasi-free states. As we show, these are in one-to-one correspondence with the one-particle density matrices and these, in turn provide a convenient…

凝聚态物理 · 物理学 2009-10-22 Volker Bach , Elliott H. Lieb , Jan philip Solovej

Searching for new states of matter and unusual quasiparticles in emerging materials and especially low-dimensional systems is one of the major trends in contemporary condensed matter physics. Dirac materials, which host quasiparticles which…

介观与纳米尺度物理 · 物理学 2017-10-13 C. A. Downing , M. E. Portnoi
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