相关论文: Mpemba Effect in Crystallization of Polybutene-1
The classical Mpemba effect is the counterintuitive phenomenon where hotter water freezes faster than colder water due to the breakdown of Newton's law of cooling after a sudden temperature quench. The genuine nonequilibrium post-quench…
For quicker formation of ice, before inserting inside a refrigerator, heating up of a body of water can be beneficial. We report first observation of a counterpart of this intriguing fact, referred to as the Mpemba effect (ME), during…
Performing molecular dynamics simulations for all-atom models, we characterize the conformational and structural relaxations of poly(ethylene oxide) and poly(propylene oxide) melts. The temperature dependence of these relaxation processes…
Complex and even non-monotonic responses to external control can be found in many thermodynamic systems. In such systems, non-equilibrium shortcuts can rapidly drive the system from an initial state to a desired final state. One example is…
The phenomenon where a quantum system can be exponentially accelerated to its stationary state has been referred to as the Quantum Mpemba Effect (QMpE). Due to its analogy with the classical Mpemba effect, hot water freezes faster than cold…
An analysis of glass formation for polymer melts that are diluted by structured molecular additives is derived by using the generalized entropy theory, which involves a combination of the Adam-Gibbs model and the direct computation of the…
Inspired by responses to the work (arXiv:1310.6514), we solved the one-dimensional, nonlinear Fourier initial and boundary condition problem using the finite element method. Examination of all possible parameters reveals the following: 1.…
We study a granular gas of viscoelastic particles (kinetic energy loss upon collision is a function of the particles' relative velocities at impact) subject to a stochastic thermostat. We show that the system displays anomalous cooling and…
Low frequency dielectric measurements on plexiglass (PMMA) show that cooling and heating the sample at constant rate give an hysteretic dependence on temperature of the dielectric constant $\epsilon$. A temporary stop of cooling produces a…
The advances in new technologies have prompted the need for functional systems smaller than the gyration radius of polymer chains. Thus, understanding how nanoconfinement affects polymer properties has been the focus of a lot of research…
Entanglement asymmetry, which serves as a diagnostic tool for symmetry breaking and a proxy for thermalization, has recently been proposed and studied in the context of symmetry restoration for quantum many-body systems undergoing a quench.…
The formation of chain-folded structures from the melt is observed in molecular dynamics simulations resembling the lamellae of polymer crystals. Crystallization and subsequent melting temperatures are related linearly to the inverse…
The work discusses specifics of phase transitions for metastable states of substances. The objects of condensed media physics are primarily equilibrium states of substances with metastable phases viewed as an exception, while the…
The thermosensitive behavior of microgel particles suspended in solvents, i.e. their temperature-dependent swelling properties, has triggered ongoing interest in industry and academia over the past forty years. The most-studied polymer is…
We study the local relaxation of closed quantum systems through the relative entropy between the reduced density matrix and its long time limit. We show, using analytic arguments combined with numerical checks, that this relative entropy…
Monte Carlo simulation on the crystallization of double crystalline diblock copolymer unravels an intrinsic relationship between block asymmetry and crystallization behaviour. We model crystalline A-B diblock copolymer, wherein the melting…
We show that there are two distinct mechanisms that can cause the symmetry-restoration Mpemba effect in spin chains with \textit{weakly broken} integrability, such that the asymptotic equilibration is diffusive, but the lifetime of…
Effect of small additive molecules on the structural relaxation of polymer melts is investigated via molecular dynamics simulations. At a constant external pressure and a fixed number concentration of added molecules, the variation of…
We find analytically the complete set of eigenvalues and eigenvectors associated with Metropolis dynamics on a complete graph. As an application, we use this information to study a counter-intuitive relaxation phenomenon, called the Mpemba…
The isothermal, isobaric spontaneous crystallization of a supercooled polymer melt is investigated by MD simulation of an ensemble of fully-flexible linear chains. Frustration is introduced via two incommensurate length scales set by the…