相关论文: Mpemba Effect in Crystallization of Polybutene-1
Relaxation towards equilibrium is often assumed to be slower when a system starts farther from equilibrium, but this intuition fails in the Mpemba effect. Recent advances in controllable quantum platforms have enabled the exploration of its…
We study the thermalization dynamics of a quantum system embedded in an incommensurate potential and coupled to a Markovian thermal reservoir. The dephasing induced by the bath drives the system toward an infinite-temperature steady state,…
The stability of the disordered glassy phase in the relaxors PbMg1/3Nb2/3O3 and (PbMg1/3Nb2/3O3)0.88(PbTiO3)0.12, called PMN and PMN-PT, was investigated by preparing partially polarized samples and allowing them to age at zero field in the…
We investigate the crystallization of crosslinked and entangled polymers under external deformation using a coarse-grained poly(vinyl alcohol) (CG-PVA) model and molecular dynamics simulations. Following uniaxial deformation, the systems…
Diblock copolymers by virtue of the chemical dissimilarity between the constituting blocks exhibit microphase separation in the melt state. The phase separated melt can successfully be exploited to control the morphology of the final semi…
Dielectric spectroscopy measurements over a broad range of temperature and pressure were carried out on poly(oxybutylene) (POB), a type-A polymer (dielectrically-active normal mode). There are three dynamic processes appearing at lower…
We study a one-dimensional quasiperiodic tight-binding model with simultaneous off-diagonal (hopping) and diagonal (onsite) modulations. Using the inverse participation ratio and the wave-packet centroid, we construct…
In this paper, we report dynamic Monte Carlo simulation results on the crystallization of crystalline/crystalline (A/B) symmetric binary polymer blend, wherein the melting temperature of A-polymer is higher than B-polymer. Crystallization…
Structural transitions and the melting behavior of crystalline poly(ethylene oxide),(CH2-CH2-O)n, (PEO) has been investigated using fully atomistic, constant pressure-constant temperature (NPT) molecular dynamics (MD) simulations. Melting…
Vapor pressures were measured for the system chloroform/polyethylene oxide (peo, weight average molar mass = 1000 kg/mol) at 25 degrees centigrade as a function of the weight fraction w of the polymer by means of a combination of head space…
The effect of polydispersity on the freezing transition of hard spheres is examined within a moment description. At low polydispersities a single fluid-to-crystal transition is recovered. With increasing polydispersity we find a density…
The Mpemba Effect can be studied with Markovian dynamics in a non-equilibrium thermodynamics framework. The Markovian Mpemba Effect can be observed in a variety of systems including the Ising model. We demonstrate that the Markovian Mpemba…
Hybrid molecular dynamics/Monte Carlo simulations used to study melts of unentangled, thermoreversibly associating supramolecular polymers. In this first of a series of papers, we describe and validate a model that is effective in…
In a recent paper in Scientific Reports, Burridge \& Linden misinterpret the Mpemba effect as a statement about the rate of cooling of liquid water, when it is in fact a statement about the rate of freezing of water. Debunking an obviously…
We show that non-entangled polymers display an elastic-like behaviour at a macroscopic scale (probed at some 0.100 mm thickness) up to at least hundred degrees above the glass transition temperature. This observation, found under…
During fast diffusion-influenced polymerization, nonequilibrium behavior of the polymer chains and the surrounding reactive monomers has been reported recently. Based on the laws of thermodynamics, the emerging nonequilibrium structures…
We present a kinetic model of crystal growth of polymers of finite molecular weight. Experiments help to classify polymer crystallization broadly into two kinetic regimes. One is observed in melts or in high molar mass polymer solutions and…
Local relaxation after a quench in 1-D quantum many-body systems is a well known and very active problem with rich phenomenology. Except for pathological cases, the local relaxation is accompanied by the local restoration of the symmetries…
A new kind of memory effect on low frequency dielectric measurements on plexiglass (PMMA) is described. These measurements show that cooling and heating the sample at constant rate give an hysteretic dependence on temperature of the…
The finite parts of a large, locally interacting many-body system prepared out-of-equilibrium eventually equilibrate. Characterising the underlying mechanisms of this process and its timescales, however, is particularly hard as it requires…