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The time evolution of the thermally activated decay rates is considered. This evolution is of particular importance for the recent nanoscale experiments discussed in the literature, where the potential barrier is relatively low (or the…

统计力学 · 物理学 2021-04-21 Maria Chushnyakova , Igor Gontchar , Natalya Khmyrova

This work presents a new modeling approach to macroscopic, polycrystalline elasto-plasticity starting from first principles and a few well-defined structural assumptions, incorporating the mildly rate-dependent (viscous) nature of plastic…

材料科学 · 物理学 2015-12-21 Filip Rindler

A dynamical study of the decay of a metastable state by quantum tunneling through an anisotropic, non separable, two-dimensional potential barrier is performed by the numerical solution of the time-dependent Schrodinger equation. Initial…

核理论 · 物理学 2008-11-26 P. Talou , N. Carjan , D. Strottman

Driven diffusive systems have provided simple models for non-equilibrium systems with non-trivial structures. Steady state behaviour of these systems with constant boundary conditions have been studied extensively. Comparatively less work…

统计力学 · 物理学 2015-12-09 Ayse Ferhan Yesil , M. Cemal Yalabik

We consider a suspended elastic rod under longitudinal compression. The compression can be used to adjust potential energy for transverse displacements from harmonic to double well regime. As compressional strain is increased to the…

软凝聚态物质 · 物理学 2011-07-15 Aniruddha Chakraborty

A scarcity of known chemical kinetic parameters leads to the use of many reaction rate estimates, which are not always sufficiently accurate, in the construction of detailed kinetic models. To reduce the reliance on these estimates and…

We consider the existence of invariant manifolds in phase space governing reaction dynamics in situations where there are no saddle points on the potential energy surface in the relevant regions of configuration space. We point out that…

化学物理 · 物理学 2010-11-04 Gregory S. Ezra , Stephen Wiggins

We study the phase space geometry associated with index 2 saddles of a potential energy surface and its influence on reaction dynamics for $n$ degree-of-freedom (DoF) Hamiltonian systems. For index 1 saddles of potential energy surfaces…

混沌动力学 · 物理学 2015-05-13 Gregory S. Ezra , Stephen Wiggins

In this article we present the influence of a Hamiltonian saddle-node bifurcation on the high-dimensional phase space structures that mediate reaction dynamics. To achieve this goal, we identify the phase space invariant manifolds using…

混沌动力学 · 物理学 2020-05-20 Víctor J. García-Garrido , Shibabrat Naik , Stephen Wiggins

Given two distinct subsets $A,B$ in the state space of some dynamical system, Transition Path Theory (TPT) was successfully used to describe the statistical behavior of transitions from $A$ to $B$ in the ergodic limit of the stationary…

动力系统 · 数学 2020-11-03 Luzie Helfmann , Enric Ribera Borrell , Christof Schütte , Péter Koltai

Although the roll/streak structure is ubiquitous in pre-transitional wall-bounded shear flow, this structure is linearly stable if the idealization of laminar flow is made. Lacking an instability, the large transient growth of the…

流体动力学 · 物理学 2017-04-05 Brian F. Farrell , Petros J. Ioannou , Marios-Andreas Nikolaidis

Models such as those involving abrupt changes in the Earth's reflectivity due to ice melt and formation often use nonlinear terms (e.g., hyperbolic tangent) to model the transition between two states. For various reasons, these models are…

动力系统 · 数学 2015-04-21 Julie Leifeld , Kaitlin Hill , Andrew Roberts

Escape from a potential well through an index-1 saddle can be widely found in some important physical systems. Knowing the criteria and phase space geometry that govern escape events plays an important role in making use of such phenomenon,…

混沌动力学 · 物理学 2026-02-24 Jun Zhong , Shane D. Ross

Metadynamics is a commonly used and successful enhanced sampling method. By the introduction of a history dependent bias which depends on a restricted number of collective variables(CVs) it can explore complex free energy surfaces…

统计力学 · 物理学 2013-12-06 Pratyush Tiwary , Michele Parrinello

The main goal of this paper is to understand the formation of hexagonal patterns from the dynamical transition theory point of view. We consider the transitions from a steady state of an abstract nonlinear dissipative system. To shed light…

数学物理 · 物理学 2020-08-26 Taylan Şengül

We consider solid state phase transformations that are caused by free energy densities with domains of non-convexity in strain-composition space; we refer to the non-convex domains as mechano-chemical spinodals. The non-convexity with…

计算物理 · 物理学 2016-09-19 Koki Sagiyama , Shiva Rudraraju , Krishna Garikipati

We use Shear Transformation Zone (STZ) theory to develop a deformation map for amorphous solids as a function of the imposed shear rate and initial material preparation. The STZ formulation incorporates recent simulation results [Haxton and…

软凝聚态物质 · 物理学 2009-11-13 M. L. Manning , E. G. Daub , J. S. Langer , J. M. Carlson

This paper introduces a linear state-space model with time-varying dynamics. The time dependency is obtained by forming the state dynamics matrix as a time-varying linear combination of a set of matrices. The time dependency of the weights…

机器学习 · 统计学 2014-10-06 Jaakko Luttinen , Tapani Raiko , Alexander Ilin

Studying time-dependent behavior in lasers is analytically difficult due to the saturating non-linearity inherent in the Maxwell-Bloch equations and numerically demanding because of the computational resources needed to discretize both time…

光学 · 物理学 2015-12-23 O. Malik , K. G. Makris , H. E. Türeci

The decay process of the schematic one-dimensional three-body system is considered. A time-dependent approach is used in combination with a one-dimensional three-body model, which is composed of a heavier core nucleus and two nucleons, with…

核理论 · 物理学 2018-04-12 Tomohiro Oishi , Lorenzo Fortunato