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Determination of defect ionization energy in low-dimensional semiconductors has been a long-standing unsolved problem in first-principles defect calculations because the commonly used methods based on jellium model introduce an unphysical…

材料科学 · 物理学 2020-07-15 Guo-jun Zhu , Xin-Gao Gong , Ji-Hui Yang

Formation energies of charged point defects in semiconductors are calculated using periodic supercells, which entail a divergence arising from long-range Coulombic interactions. The divergence is typically removed by the so-called jellium…

材料科学 · 物理学 2019-11-27 Andrew O'Hara , Blair R. Tuttle , Xiao-Guang Zhang , Sokrates T. Pantelides

Defects on surfaces of semiconductors have a strong effect on their reactivity and catalytic properties. The concentration of different charge states of defects is determined by their formation energies. First-principles calculations are an…

介观与纳米尺度物理 · 物理学 2017-07-05 Dmitry Vinichenko , M. Gokhan Sensoy , Cynthia M. Friend , Efthimios Kaxiras

Defects in 2D materials are becoming prominent candidates for quantum emitters and scalable optoelectronic applications. However, several physical properties that characterize their behavior, such as charged defect ionization energies, are…

材料科学 · 物理学 2018-12-26 Tyler J. Smart , Feng Wu , Marco Govoni , Yuan Ping

In this article we propose and numerically implement a mathematical model for the simulation of three-dimensional semiconductor devices characterized by an heterogeneous material structure. The model consists of a system of nonlinearly…

数值分析 · 数学 2013-07-12 A. Mauri , R. Sacco , M. Verri

Supercell models are often used to calculate the electronic structure of local perturbations from the ideal periodicity in the bulk or on the surface of a crystal or in wires. When the defect or adsorbent is charged, a jellium counter…

The errors arising in ab initio density functional theory studies of semiconductor point defects using the supercell approximation are analyzed. It is demonstrated that a) the leading finite size errors are inverse linear and inverse cubic…

其他凝聚态物理 · 物理学 2009-11-11 C. W. M. Castleton , A. Hoglund , S. Mirbt

Without our ability to model and manipulate the band structure of semiconducting materials, the modern digital computer would be impractically large, hot, and expensive. In the undergraduate QM curriculum, we studied the effect of spatially…

量子物理 · 物理学 2011-05-03 Peter Iannucci

The energetic cost of creating a defect within a host material is given by the formation energy. Here we present a formulation allowing the calculation of formation energies in one-dimensional nanostructures, which overcomes the…

材料科学 · 物理学 2015-05-13 Riccardo Rurali , Xavier Cartoixa

A methodology for calculating the contribution of charged defects to the configurational free energy of an ionic crystal is introduced. The temperature-independent Wang-Landau Monte Carlo technique is applied to a simple model of a solid…

All-solid-state batteries are seen as promising candidates to replace conventional batteries with liquid electrolytes in many applications. However, they are not yet feasible for many relevant applications. One particular question of…

化学物理 · 物理学 2023-07-06 Stephan Sinzig , Thomas Hollweck , Christoph P. Schmidt , Wolfgang A. Wall

We present a virtual ionic crystal (VIC) method to calculate energies of charged point defects on surfaces. No artificial charge but an actual zero-dimensional (0D) species is introduced to charge a defect. Effect of dielectric substrate on…

介观与纳米尺度物理 · 物理学 2016-06-15 Feifei Li , Zhenpeng Hu , Ziping Niu , Lixin Zhang

Three-dimensional charge density maps computed by first-principles methods provide information about atom positions and the bonds between them, data which is particularly valuable when trying to understand the properties of point defects,…

材料科学 · 物理学 2008-10-22 Christoph T. Koch

Modeling point defects at an atomic scale requires careful treatment of the long-range atomic relaxations. This elastic field can strongly affect point defect properties calculated in atomistic simulations because of the finite size of the…

材料科学 · 物理学 2013-10-23 Céline Varvenne , Fabien Bruneval , Mihai-Cosmin Marinica , Emmanuel Clouet

We consider a one-dimensional effective quantum electrodynamics (QED) model of the relativistic hydrogen-like atom using delta-potential interactions. We discuss the general exact theory and the Hartree-Fock approximation. The present…

数学物理 · 物理学 2023-06-27 Timothée Audinet , Julien Toulouse

Recent path-integral Monte Carlo and quantum molecular dynamics simulations have shown that computationally efficient average-atom models can predict thermodynamic states in warm dense matter to within a few percent. One such…

We build a transient multidimensional multiphysical model based on continuum theories, involving the coupled mechanical, thermal and electrochemical phenomena occurring simultaneously in the discharge or charge of lithium-ion batteries. The…

数值分析 · 数学 2024-03-26 Jaime Mora-Paz

This paper presents a generalization of the charge-based model for ultrathin junctionless double-gate (JLDG) field-effect transistors (FETs) by including quantum electron density. The analytical derivation relies on a first-order correction…

应用物理 · 物理学 2018-10-17 Majid Shalchian , Farzan Jazaeri , Jean-Michel Sallese

In this paper, we investigate the dynamical formation and evolution of 2 + 1-dimensional charged black holes. We numerically study dynamical collapses of charged matter fields in an anti de Sitter background and note the formation of black…

广义相对论与量子宇宙学 · 物理学 2015-05-28 Dong-il Hwang , Hongbin Kim , Dong-han Yeom

The potential energy formulation and deep learning are merged to solve partial differential equations governing the deformation in hyperelastic and viscoelastic materials. The presented deep energy method (DEM) is self-contained and…

机器学习 · 计算机科学 2022-05-05 Diab W. Abueidda , Seid Koric , Rashid Abu Al-Rub , Corey M. Parrott , Kai A. James , Nahil A. Sobh
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