相关论文: Exact equations of state for nematics
We study a discrete version of a biaxial nematic liquid crystal model with external fields via an approach based on the solution of differential identities for the partition function. In the thermodynamic limit, we derive the free energy of…
A thermodynamic phase transition denotes a drastic change of state of a physical system due to a continuous change of thermodynamic variables, as for instance pressure and temperature. The classical van der Waals equation of state is the…
We demonstrate that a first order isotropic-to-nematic phase transition in liquid crystals can be succesfully modeled within the generalized Landau-de Gennes theory by selecting an appropriate combination of elastic constants. The numerical…
Recent experiments report that the long looked for thermotropic biaxial nematic phase has been finally detected in some thermotropic liquid crystalline systems. Inspired by these experimental observations we concentrate on some elementary…
We apply a recently developed technique to determine adapted coordinates for the sixth degree Landau-deGennes potential, in which the potential is specially simple, to analyze the possibility of a direct transition between the fully…
Motivated by the search for quantum liquid crystal phases in a gas of ultracold atoms and molecules, we study the density wave and nematic instabilities of dipolar fermions on the two-dimensional square lattice (in the $x-y$ plane) with…
Nematic liquid crystals possess three different phases: isotropic, uniaxial, and biaxial. The ground state of most nematics is either isotropic or uniaxial, depending on the external temperature. Nevertheless, biaxial domains have been…
With the aim of investigating the stability conditions of biaxial nematic liquid crystals, we study the effect of adding a non-adsorbing ideal depletant on the phase behavior of colloidal hard boardlike particles. We take into account the…
We investigate the phase behavior of colloidal suspensions of board-like particles under the effect of an external field and assess the still disputed occurrence of the biaxial nematic (N$_\text{B}$) liquid crystal phase. The external field…
In this paper we revisit and extend some mathematical aspects of Onsager's theory of liquid crystals that have been investigated in recent years by different communities (statistical mechanics, analysis and probability). We introduce a…
We study motion of a phase transition front at a constant temperature between stable and metastable states in fluids with the universal Van der Waals equation of state (which is valid sufficiently close to the fluid's critical point). We…
In this work, we study the nematic-isotropic phase transition based on the dynamics of the Landau--De Gennes theory of liquid crystals. At the critical temperature, the Landau--De Gennes bulk potential favors the isotropic phase and nematic…
Both uniaxial and biaxial nematic liquid crystals are defined by orientational ordering of their building blocks. While uniaxial nematics only orient the long molecular axis, biaxial order implies local order along three axes. As the…
Pattern formation in uniaxial polymeric liquid crystals is studied for different dynamic closure approximations. Using the principles of mesoscopic non-equilibrium thermodynamics in a mean-field approach, we derive a Fokker-Planck equation…
In nematic liquid crystals (NLCs), topological defects of a chiral origin play a role in phase transitions and lead to phase configurations of nontrivial topology, like those in neutron stars and helium in the A-phase. In the…
We introduce a new class of non-isothermal models describing the evolution of nematic liquid crystals and prove their consistency with the fundamental laws of classical Thermodynamics. The resulting system of equations captures all…
We study the kinetics of the nematic-isotropic transition in a two-dimensional liquid crystal by using a lattice Boltzmann scheme that couples the tensor order parameter and the flow consistently. Unlike in previous studies, we find the…
We propose an approach to a multiscale problem in the theory of thermotropic uniaxial nematics based on the method of statistical field theory. This approach enables us to relate the coefficients $A$, $B$, $C$, $L_1$ and $L_2$ of the…
The biaxial phase in nematic liquid crystals has been elusive for several decades after its prediction in the 1970s. A recent experimental breakthrough was achieved by Liu et al. [PNAS 113, 10479 (2016)] in a liquid crystalline medium with…
Spontaneous onset of a low temperature topologically ordered phase in a 2-dimensional (2D) lattice model of uniaxial liquid crystal (LC) was debated extensively pointing to a suspected underlying mechanism affecting the RG flow near the…