相关论文: Excluded Volume Effects of Branched Molecules
The excluded volume effects of randomly branched polymers are investigated. To approach this problem we assume the Gaussian distribution of segments around the center of gravity. Once this approximation is introduced, we can make use of the…
We discuss the extension of the empirical equation: $\left\langle s_{N}^{2}\right\rangle_{0}\propto g\,l^{2}$, where the subscript 0 denotes the ideal value with no excluded volume and $g$ the generation number from the root to the youngest…
Molecular weight dependence of excluded volume effects is examined. The swollen-to-unperturbed coil transition point shifts to lower concentration range with increasing molecular weight (Mw). It is shown that in the limit of the infinite…
We investigate the excluded volume effects in good solvents for the isolated comb polymers having $\nu_{0}=1/4$. In particular, we investigate the change of the size exponent, $\nu$, defined by $\langle s_{N}^{2}\rangle\propto N^{2\nu}$,…
We present the alternative derivation of the excluded volume equation. The resulting equation is mathematically identical to the one proposed in the preceding paper. As a result, the theory reproduces well the observed points by SANS (small…
Excluded-volume effects can play an important role in determining transport properties in diffusion of particles. Here, the diffusion of finite-sized hard-core interacting particles in two or three dimensions is considered systematically…
On the basis of the thermodynamic theory of the excluded volume effects, we show that the size exponent varies abruptly, depending on the change of the segment concentration. For linear polymers, the exponent changes discontinuously from…
We provide a refinement of the sphere-packing bound for constant composition codes over asymmetric discrete memoryless channels that improves the pre-factor in front of the exponential term. The order of our pre-factor is…
Using results on soft-collinear factorization for inclusive B-meson decay distributions, a systematic study of the partial B->Xs+gamma decay rate with a cut E_gamma<E_0 on photon energy is performed. For values E_0<1.9 GeV the rate can be…
The large $N$ asymptotic expansion of the partition function for the normal matrix model is predicted to have special features inherited from its interpretation as a two-dimensional Coulomb gas. However for the latter, it is most natural to…
Branching ratios of $\alpha $-decay to members of the ground state rotational band and excited 0$^{+}$ states of even-even nuclei are calculated in the framework of the generalized liquid drop model (GLDM) by taking into account the angular…
The effect of introducing a mass dependent diffusion rate ~ m^{-alpha} in a model of coagulation with single-particle break up is studied both analytically and numerically. The model with alpha=0 is known to undergo a nonequilibrium phase…
The attenuation factor F responsible for the decay out of a superdeformed (SD) band is calculated with the help of a statistical model. This factor is given by 1/F = (1 + Gamma(down) / Gamma(S)). Here, Gamma(S) is the width for the…
A double stranded DNA molecule when pulled with a force acting on one end of the molecule can become either partially or completely unzipped depending on the magnitude of the force F. For a random DNA sequence, the number M of unzipped base…
Methods for estimating the correlation energy of molecules and other electronic systems are discussed based on the assumption that the correlation energy can be partitioned between atomic regions. In one method, the electron density is…
It is known in thin-film deposition that the density of nucleated clusters $N$ varies with the deposition rate $R$ as a power law, $N \sim R^\alpha$. The exponent $\alpha$ is a function of the critical nucleus size $i$ in a way that changes…
The large momentum expansion for the inverse propagator of the auxiliary field $\lambda(x)$ in the conformally invariant O(N) vector model is calculated to leading order in 1/N, in a strip-like geometry with one finite dimension of length…
Following Flory's ideality hypothesis the chemical potential of a test chain of length $n$ immersed into a dense solution of chemically identical polymers of length distribution P(N) is extensive in $n$. We argue that an additional…
The complex optical potential and inelastic form factor given by the folding model for the $\alpha+^{12}$C scattering are used to calculate the ($\alpha,\alpha'$) cross sections for the known isoscalar states of $^{12}$C in an elaborate…
We consider the spectral problem \begin{equation*} \left\{\begin{array}{ll} -\Delta u_{\varepsilon}=\lambda(\varepsilon)\rho_{\varepsilon}u_{\varepsilon} & {\rm in}\ \Omega\\ \frac{\partial u_{\varepsilon}}{\partial\nu}=0 & {\rm on}\…