相关论文: Clausius versus Sackur-Tetrode entropies

Statistical thermodynamics is valuable as a conceptual structure that shapes our thinking about equilibrium thermodynamic states. A cloud of unresolved questions surrounding the foundations of the theory could lead an impartial observer to…

The generalized zeroth law of thermodynamics indicates that the physical temperature in nonextensive statistical mechanics is different from the inverse of the Lagrange multiplier, beta. This leads to modifications of some of thermodynamic…

Thermodynamic entropy, as defined by Clausius, characterizes macroscopic observations of a system based on phenomenological quantities such as temperature and heat. In contrast, information-theoretic entropy, introduced by Shannon, is a…

Meixner's historical remark in 1969 "... it can be shown that the concept of entropy in the absence of equilibrium is in fact not only questionable but that it cannot even be defined...." is investigated from today's insight. Several…

In the context of driven diffusive systems, for thermodynamic transformations over a large but finite time window, we derive an expansion of the energy balance. In particular, we characterize the transformations which minimize the energy…

In his ninth memoir Clausius summarizes the two principles of thermodynamics as follows: "The whole mechanical theory of heat rests on two fundamental theorems: that of equivalence of heat and work, and that of equivalence of…

We propose an expression for the entropy density associated with the Local Causal Horizons in any diffeomorphism invariant theory of gravity. If the black-hole entropy of the theory satisfies the physical process version of the first law of…

Here we develop the connection between thermodynamics, entanglement, and gravity. By attributing thermodynamics to timeslices of a causal diamond, we show that the Clausius relation $T\Delta S_{\text{rev}}=Q$, where $\Delta S_{\text{rev}}$…

The second law of thermodynamics in nonextensive statistical mechanics is discussed in the quantum regime. Making use of the convexity property of the generalized relative entropy associated with the Tsallis entropy indexed by q, Clausius'…

The issue of the Gibbs paradox is that when considering mixing of two gases within classical thermodynamics, the entropy of mixing appears to be a discontinuous function of the difference between the gases: it is finite for whatever small…

Among various possible routes to extend entropy and thermodynamics to nonequilibrium steady states (NESS), we take the one which is guided by operational thermodynamics and the Clausius relation. In our previous study, we derived the…

The entropic form $S_q$ is, for any $q \neq 1$, {\it nonadditive}. Indeed, for two probabilistically independent subsystems, it satisfies $S_q(A+B)/k=[S_q(A)/k]+[S_q(B)/k]+(1-q)[S_q(A)/k][S_q(B)/k] \ne S_q(A)/k+S_q(B)/k$. This form will…

The Clausius inequality for closed systems was deduced from the Riemann integration of closed Carnot cycle loops for irreversible transitions. The corresponding inequalities for the recently developed open system Carnot cycles are derived…

The homogeneous entropy for continuous systems in nonextensive statistics reads $S^{H}_{q}=k_B\,{(1 - (K \int d\Gamma \rho^{1/q}(\Gamma))^{q})}/({1-q})$, where $\Gamma$ is the phase space variable. Optimization of $S^{H}_{q}$ combined with…

We formulate a geometric framework in which physical laws emerge from restricted access to microscopic information. Measurement constraints are modeled as a gauge symmetry acting on density operators, inducing a gauge-reduced space of…

The incomplete nonextensive statistics in the canonical and microcanonical ensembles is explored in the general case and in a particular case for the ideal gas. By exact analytical results for the ideal gas it is shown that taking the…

Carnot's four-part ideal-gas cycle includes both isothermal and adiabatic expansions and compressions. Analyzing this cycle provides the fundamental basis for statistical thermodynamics. We explore the cycle here from a pedagogical view in…

We assess two different non-equilibrium quantum Landauer bounds: the traditional approach based on the change in entropy, referred to as the `entropic bound', and one based on the details of the dynamical map, referred to as the…

In this paper we propose the use of concepts from thermodynamics in the study of crowd dynamics. Our continuous model consists of the continuity equation for the density of the crowd and a kinetic equation for the velocity field. The latter…

The second law of thermodynamics is a fundamental law of Nature. It is almost universally associated with the Clausius inequality that lower bounds a change in entropy by the ratio of supplied heat and temperature. However, this result…