相关论文: Polymer pinning at an interface
We consider a directed walk model of a homopolymer (in two dimensions) which is self-interacting and can undergo a collapse transition, subject to an applied tensile force. We review and interpret all the results already in the literature…
The results obtained from molecular dynamics simulations of the friction at an interface between polymer melts and weakly attractive crystalline surfaces are reported. We consider a coarse-grained bead-spring model of linear chains with…
Monolayers of colloidal particles at oil-water interfaces readily crystalize owing to electrostatic repulsion, which is often mediated through the oil. However, little attempts exist to control it using oil-soluble electrolytes. We probe…
We discuss the generalization of a classical problem involving an $N$-step ideal polymer adsorption at a sticky boundary (potential well of depth $U$). It is known that as $N$ approaches infinity, the path undergoes a 2nd-order localization…
We study the localization/delocalization phase transition in a class of directed models for a homogeneous linear chain attracted to a defect line. The self-interaction of the chain is of mixed gradient and Laplacian kind, whereas the…
We consider the flow-driven translocation of single polymer chains through nanochannels. Using analytical calculations based on the de Gennes blob model and mesoscopic numerical simulations, we estimate the threshold flux for the…
A self-interacting polymer with one end attached to a sticky surface has been studied by means of a flat-histogram stochastic growth algorithm known as FlatPERM. We examined the four-dimensional parameter space of the number of monomers up…
Processes on different length scales affect the dynamics of chain molecules. In this work, we focus on structures on the scale of a monomer and investigate polyolefins, i.e. hydrocarbon chains with different small scale architectures. We…
This paper considers an undirected polymer chain on $\mathbb{Z}^d$, $d \geq 2$, with i.i.d.\ random charges attached to its constituent monomers. Each self-intersection of the polymer chain contributes an energy to the interaction…
Hydrophobically modified polymers are good candidates for the stabilization of liquid interfaces thanks to the high anchoring energy of the hydrophobic parts. In this article we probe the interfacial anchoring of a series of home-made…
The origin of the apparent negative charge at hydrophobic-water interfaces has fueled one of the biggest debates in physical chemistry for several decades. The most common interpretation given to explain this observation is that negatively…
We consider the phase transition in the system of n simultaneously developing random walks on the halfline x>=0. All walks are independent on each others in all points except the origin x=0, where the point well is located. The well depth…
Lattice model of directed self avoiding walk has been solved analytically to investigate adsorption desorption phase transition behaviour of a semiflexible sequential copolymer chain on a two dimensional impenetrable surface perpendicular…
Contact electrification, or contact charging, refers to the process of static charge accumulation after rubbing, or even simple touching, of two materials. Despite its relevance in static electricity, various natural phenomena, and numerous…
We consider the model of a directed polymer pinned to a line of i.i.d. random charges, and focus on the interior of the delocalized phase. We first show that in this region, the partition function remains bounded. We then prove that for…
Taking $P^0$ to be the measure induced by simple, symmetric nearest neighbor continuous time random walk on ${\bf{Z^d}}$ starting at $0$ with jump rate $2d$ define, for $\beta\ge 0,\,t>0,$ the Gibbs probability measure $P_{\beta,t}$ by…
We investigate a lattice model of polymers where the nearest-neighbour monomer-monomer interaction strengths differ according to whether the local configurations have so-called ``hydrogen-like'' formations or not. If the interaction…
We consider d-dimensional random surface models which for d=1 are the standard (tied-down) random walks (considered as a random ``string''). In higher dimensions, the one-dimensional (discrete) time parameter of the random walk is replaced…
Conformational transitions of flexible molecules, especially those driven by hydrophobic effects, tend to be hindered by desolvation barriers. For such transitions, it is thus important to characterize and understand the interplay between…
We employ a three-dimensional molecular dynamics to simulate translocation of a polymer through a nanopore driven by an external force. The translocation is investigated for different three pore diameter and two different external forces.…