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Besides perturbation theory, which requires, of course, the knowledge of the exact unperturbed solution, variational techniques represent the main tool for any investigation of the eigenvalue problem of some semibounded operator H in…

高能物理 - 唯象学 · 物理学 2016-12-28 Wolfgang Lucha , F. F. Schoberl

Variational algorithms are promising candidates to be implemented on near-term quantum computers. The variational quantum eigensolver (VQE) is a prominent example, where a parametrized trial state of the quantum mechanical wave function is…

Variational algorithms for strongly correlated chemical and materials systems are one of the most promising applications of near-term quantum computers. We present an extension to the variational quantum eigensolver that approximates the…

量子物理 · 物理学 2020-08-26 William J. Huggins , Joonho Lee , Unpil Baek , Bryan O'Gorman , K. Birgitta Whaley

In quantum theory, bound states are described by eigenvalue equations, which usually cannot be solved exactly. However, some simple general theorems allow to derive rigorous statements about the corresponding solutions, that is, energy…

高能物理 - 唯象学 · 物理学 2011-04-15 Wolfgang Lucha , F. F. Schoberl

A variational method is studied based on the minimum of energy variance. The method is tested on exactly soluble problems in quantum mechanics, and is shown to be a useful tool whenever the properties of states are more relevant than the…

高能物理 - 唯象学 · 物理学 2009-01-07 Luca Marotta , Fabio Siringo

An exactly solvable time-dependent quantum mechanical problem is employed to study the convergence properties of transition amplitudes calculated by using the Schwinger variational principle. A detailed comparison between the amplitudes…

原子物理 · 物理学 2016-05-09 V. D. Rodríguez

A powerful method for calculating the eigenvalues of a Hamiltonian operator consists of converting the energy eigenvalue equation into a matrix equation by means of an appropriate basis set of functions. The convergence of the method can be…

量子物理 · 物理学 2007-05-23 Paolo Amore , Alfredo Aranda , Francisco Fernandez , Hugh Jones

Determining quantum excited states is crucial across physics and chemistry but presents significant challenges for variational methods, primarily due to the need to enforce orthogonality to lower-energy states, often requiring…

量子物理 · 物理学 2025-05-01 Shi-Xin Zhang , Lei Wang

Solutions to many-body problem instances often involve an intractable number of degrees of freedom and admit no known approximations in general form. In practice, representing quantum-mechanical states of a given Hamiltonian using available…

量子物理 · 物理学 2020-11-10 Andrey Kardashin , Alexey Uvarov , Dmitry Yudin , Jacob Biamonte

The problem of the harmonic oscillator with a centrally located delta function potential can be exactly solved in one dimension where the eigenfunctions are expressed as superpositions of the Hermite polynomials or as confluent…

量子物理 · 物理学 2021-08-18 Indrajit Ghose , Parongama Sen

The variational quantum eigensolver (or VQE) uses the variational principle to compute the ground state energy of a Hamiltonian, a problem that is central to quantum chemistry and condensed matter physics. Conventional computing methods are…

We present a generalization of the variational principle that is compatible with any Hamiltonian eigenstate that can be specified uniquely by a list of properties. This variational principle appears to be compatible with a wide range of…

化学物理 · 物理学 2020-02-07 Jacqueline A. R. Shea , Elise Gwin , Eric Neuscamman

By application of a straightforward variational procedure we derive a simple, analytic upper bound on the ground-state energy eigenvalue of a semirelativistic Hamiltonian for (one or two) spinless particles which experience some…

高能物理 - 唯象学 · 物理学 2009-10-28 Wolfgang Lucha , Franz F. SCHÖberl

The variational approach is a cornerstone of computational physics, considering both conventional and quantum computing computational platforms. The variational quantum eigensolver (VQE) algorithm aims to prepare the ground state of a…

量子物理 · 物理学 2022-12-16 Nikita Astrakhantsev , Guglielmo Mazzola , Ivano Tavernelli , Giuseppe Carleo

We develop a variational principle to determine the quantum controls and initial state which optimizes the quantum Fisher information, the quantity characterizing the precision in quantum metrology. When the set of available controls is…

量子物理 · 物理学 2022-04-27 Jing Yang , Shengshi Pang , Zekai Chen , Andrew N. Jordan , Adolfo del Campo

Key properties of physical systems can be described by the eigenvalues of matrices that represent the system. Computational algorithms that determine the eigenvalues of these matrices exist, but they generally suffer from a loss of…

量子物理 · 物理学 2023-10-31 T. Powers , R. M. Rajapakse

We introduce variational methods for finding approximate eigenfunctions and eigenvalues of quantum Hamiltonians by constructing a set of orthogonal wave functions which approximately solve the eigenvalue equation.

数学物理 · 物理学 2013-07-16 Farrokh Atai , Jens Hoppe , Mariusz Hynek , Edwin Langmann

Variational methods play an important role in the study of quantum many-body problems, both in the flavor of classical variational principles based on tensor networks as well as of quantum variational principles in near-term quantum…

量子物理 · 物理学 2026-02-18 J. Eisert

This paper presents a hybrid variational quantum algorithm that finds a random eigenvector of a unitary matrix with a known quantum circuit. The algorithm is based on the SWAP test on trial states generated by a parametrized quantum…

量子物理 · 物理学 2025-01-14 Juan Carlos Garcia-Escartin

Quantum simulators offer the potential to utilize the quantum nature of a physical system to study another physical system. In contrast to conventional simulation, which experiences an exponential increase in computational complexity,…

量子物理 · 物理学 2024-07-24 Xuliang Du , Yang Shen , Zipeng Wu , Bei Zeng , Sen Yang
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