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The freely jointed chain is often applied to model the thermodynamics of single polymer chains, but the traditional formulation of the model lacks internal energy changes due to bond stretching. For this reason, the extensible freely…

统计力学 · 物理学 2026-05-13 Michael R. Buche

We performed a series of simulations for a linear polymer chain in a solvent using dissipative particle dynamics to check the scaling relations for the end-to-end distance, radius of gyration and hydrodynamic radius in three dimensions. The…

软凝聚态物质 · 物理学 2009-04-03 J. M. Ilnytskyi , Yu. Holovatch

We derive an exact formula for the covariance of cartesian distances in two simple polymer models, the freely-jointed chain and a discrete flexible model with nearest-neighbor interaction. We show that even in the interaction-free case…

软凝聚态物质 · 物理学 2009-04-17 Johannes-Geert Hagmann , Karol K. Kozlowski , Nikos Theodorakopoulos , Michel Peyrard

The effects of polymer concentration and chain length on aggregation in associative polymer solutions, are studied using self-consistent field lattice model. Only two inhomogenous morphologies, i.e. microfluctuation homogenous (MFH) and…

软凝聚态物质 · 物理学 2012-02-22 X. -G. Han , X. -F. Zhang , Y. -H. Ma , C. -X. Zhang , Y. -B. Guan

A formula is derived for stiffness of a polymer chain in terms of the distribution function of end-to-end vectors. This relationship is applied to calculate the stiffness of Gaussian chains (neutral and carrying electric charges at the…

统计力学 · 物理学 2007-05-23 A. D. Drozdov

We show that in boundary CFTs, there exists a one-to-one correspondence between the boundary operator expansion of the two-point correlation function and a power series expansion of the layer susceptibility. This general property allows the…

高能物理 - 理论 · 物理学 2020-12-11 Parijat Dey , Tobias Hansen , Mykola Shpot

In this paper, we present a new approach to the discrete version of the Wormlike Chain Model (WCM) of semiflexible polymers. Our solution to the model is based on a new computational technique called the Generalized Borel Transform (GBT)…

软凝聚态物质 · 物理学 2007-05-23 Marcelo Marucho , Gustavo A. Carri

We investigate the wormlike polymer chains using self-consistent field theory and take into account the Onsager excluded-volume interaction between polymer segments. The propagator of polymer chain is one of the essential physical…

软凝聚态物质 · 物理学 2020-06-23 Baopi Liu

We consider the adsorption of a semiflexible polymer chain onto interfaces and surfaces by using the differential equation of the distribution function $G(R,L)$ of the end-to-end distance $R$, which is associated with the moment expansion…

软凝聚态物质 · 物理学 2009-11-07 Semjon Stepanow

We characterize the multifractal behavior of Brownian motion in the vicinity of an absorbing star polymer. We map the problem to an O(M)-symmetric phi^4-field theory relating higher moments of the Laplacian field of Brownian motion to…

凝聚态物理 · 物理学 2016-08-31 Christian von Ferber , Yurij Holovatch

Universal relations that hold for any state provide powerful constraints on systems consisting of fermions with two spin states interacting with a large scattering length. In radio-frequency (rf) spectroscopy, the mean shift in the rf…

量子气体 · 物理学 2014-11-20 Eric Braaten , Daekyoung Kang , Lucas Platter

Constitutive modeling of dielectric elastomers has been of long standing interest in mechanics. Over the last two decades rigorous constitutive models have been developed that couple the electrical response of these polymers with large…

软凝聚态物质 · 物理学 2021-10-19 Matthew Grasinger , Kaushik Dayal , Gal deBotton , Prashant K. Purohit

The structural properties of polymers adsorbed onto a surface have been widely investigated using self-consistent mean-field theories. Recently, analytical mean-field theories have been applied to study polymer adsorption on curved surfaces…

软凝聚态物质 · 物理学 2009-11-10 K. I. Skau , E. M. Blokhuis

Topological entanglements in polymers are mimicked by sliding rings (slip-links) which enforce pair contacts between monomers. We study the force-extension curve for linear polymers in which slip-links create additional loops of variable…

统计力学 · 物理学 2009-11-07 Ralf Metzler , Yacov Kantor , Mehran Kardar

We investigated the influence of short- and long-range correlated quenched disorder introduced into the medium on the process of adsorption of long-flexible polymer chains on a wall by using the field theoretical approach in $d=4-\epsilon$…

无序系统与神经网络 · 物理学 2007-05-23 Z. Usatenko , A. Ciach

A key assumption of polymer physics is that the random chains polymers extend in flow. Recent experimental evidence has shown that polymer chains compress in Couette flow in a manner counter to expectation. Here, scaling arguments developed…

软凝聚态物质 · 物理学 2018-06-05 Dave E. Dunstan

We report grand canonical Monte Carlo simulations of the critical point properties of homopolymers within the Bond Fluctuation model. By employing Configurational Bias Monte Carlo methods, chain lengths of up to N=60 monomers could be…

凝聚态物理 · 物理学 2009-10-28 N. B. Wilding , M. Mueller , K. Binder

The breakage of a polymer chain of segments, coupled by anharmonic bonds with applied constant external tensile force is studied by means of Molecular Dynamics simulation. We show that the mean life time of the chain becomes progressively…

软凝聚态物质 · 物理学 2015-05-27 J. Paturej , A. Milchev , V. G. Rostiashvili , T. A. Vilgis

Colloidal patchy particles with divalent attractive interaction can self-assemble into linear polymer chains. Their equilibrium properties in 2D and 3D are well described by Wertheim's thermodynamic perturbation theory which predicts a…

软凝聚态物质 · 物理学 2022-09-21 H. J. Jonas , P. Schall , P. G. Bolhuis

We study the propagation of tension caused by an external force along a long polymeric molecule in two different settings, namely along a free polymer in 3d space being pulled from one end, and along a pre-stretched circular polymer,…

软凝聚态物质 · 物理学 2013-06-20 Payam Rowghanian , Alexander Y. Grosberg