相关论文: Synthesis and characterisation of LixBC - hole dop…

Following the recent theoretical prediction of superconductivity in hole doped LiBC by Rosner et al [1], we have attempted to synthesise Li deficient LixBC (x = 1, 0.8, 0.6 and 0.4) and look for superconductivity in this system. Our…

Polycrystalline samples of LiBC compounds, which were predicted as possible candidate for high-Tc superconductivity, have been synthesised by a flux method and investigated by means of electrical resistivity and magnetic susceptibility.…

We report the preparation of Mg1-xLixB2 compounds. Nearly single phased samples were obtained for x<0.3. The in-plane lattice parameter a decreases with Li doping, while the lattice parameter c does not show obvious change. The…

Superconductivity with Tc above 9 K was found in metal-deficient NbB2 prepared under 5 GPa, while no clear superconductivity was observed down to 3 K in stoichiometric NbB2. The superconductivity was observed above x = 0.04 in Nb1-xB2. and…

We report synthesis and superconductivity at 3.7K in PrO0.5F0.5BiS2. The newly discovered material belongs to the layered sulfide based REO0.5F0.5BiS2 compounds having ZrCuSiAs type structure. The bulk polycrystalline compound is…

We have systematically studied the structural and physical properties of the superconducting hydrated Lix(H2O)yTaS2. The powder X-ray diffraction patterns suggest that all the samples are single-phase compounds, and the crystal structure is…

The search for superconductivity in materials iso-structural and iso-electronic with magnesium diboride, MgB2, has not yielded results with Tc near 39K. In particular, Lithium borocarbide, LiBC, and its modification Li0.5BC, proved to be…

LiBC, a semiconducting ternary borocarbide constituted of the lightest elements only, has been synthesized and characterized by x-ray powder diffraction, dielectric spectroscopy, and conductivity measurements. Utilizing an infrared…

The Y1-xLixBa2Cu3O7-d polycrystalline bulk superconductors doped with Li substituting at the Y site at different concentrations (x = 0, 0.01, 0.02, 0.1) were prepared using the citrate-gel method to study the effects of doping on the…

CeNi0.8Bi2 is very recent entrant in superconductivity kitchen [1], and the same seeks reproduction from other groups. We report synthesis, structural details and superconductivity in CeNi0.8Bi2 compound. The CeNi0.8Bi2 compound is…

We report the synthesis, magnetic susceptibility and crystal structure analysis for NbB2+x (x = 0.0 to 1.0) samples. The study facilitates in finding a correlation among the lattice parameters, chemical composition and the superconducting…

The layered lithium borocarbide LiBC, isovalent with and structurally similar to the superconductor MgB2, is an insulator due to the modulation within the hexagonal layers (BC vs. B2). We show that hole-doping of LiBC results in Fermi…

The layered compound LaOBiSSe was successfully synthesized by a two-step solid-state reaction method, which is isostructural with the quaternary compound LaOBiS2 indicated by the powder X-ray diffraction characterization, and the crystal…

Dense pure and doped (Mg1-xAx)B2 samples with A = Na, Ca, Cu, Ag, Zn and Al were synthesized at high pressure - high temperature in a multi anvils press (3.5-6 GPa, 900-1000C) for x up to 0.20. They were studied by x-ray diffraction,…

Delithiation of the known layered LiBC compound was predicted to induce conventional superconductivity at liquid nitrogen temperatures but extensive experimental work over the past two decades has detected no signs of the expected…

We report on the synthesis and the physical properties of Ba1-xRbxTi2Sb2O (x < 0.4) by x-ray diffraction, SQUID magnetometery, resistivity and specific heat measurements. Upon hole doping by substituting Ba with Rb, we find…

We have investigated the lattice dynamics of LiBC. Experimental Raman and inelastic neutron scattering results are confronted with density functional calculations. The excellent agreement between experiment and theory indicates that we have…

Two single crystalline samples with the same nominal composition of Rb0.8Fe2Se2 prepared via slightly different precursor routes under the same thermal processing conditions were investigated at ambient and high pressures. One sample was…

We successfully synthesized the nickel-based compound GdONiBi with superconducting transition temperature about 4.5 K. By partially substituting the element Gd with Sr to introduce holes into the material, we got new superconductor…

A new electron-doped superconductor Li_x_Sr_2_CuO_2_Br_2_ with x = 0.15 has successfully been synthesized by an electrochemical Li-intercalation technique. The magnetic susceptibility shows superconductivity of bulk with the superconducting…