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This paper describes a mixed direct-iterative method for boundary integral formulations of dielectric solvation models. We give an example for which a direct solution at thermal accuracy is nontrivial and for which Gauss-Seidel iteration…

chem-ph · 物理学 2008-02-03 S. A. Corcelli , J. D. Kress , L. R. Pratt , G. J. Tawa

This review describes the theory and implementation of implicit solvation models based on continuum electrostatics. Within quantum chemistry this formalism is sometimes synonymous with the polarizable continuum model, a particular…

化学物理 · 物理学 2022-03-15 John M. Herbert

Treating water as a linearly responding dielectric continuum on molecular length scales allows very simple estimates of solvation structure and thermodynamics for charged and polar solutes. While this approach can successfully account for…

统计力学 · 物理学 2021-07-07 Stephen J. Cox , Kranthi K. Mandadapu , Phillip L. Geissler

In a continuum model of the solvation of charged molecules in an aqueous solvent, the classical Poisson-Boltzmann (PB) theory is generalized to include the solute point charges and the dielectric boundary that separates the high-dielectric…

最优化与控制 · 数学 2021-09-29 Bo Li , Zhengfang Zhang , Shenggao Zhou

Continuum solvation methods can provide an accurate and inexpensive embedding of quantum simulations in liquid or complex dielectric environments. Notwithstanding a long history and manifold applications to isolated systems in open boundary…

材料科学 · 物理学 2014-12-02 Oliviero Andreussi , Nicola Marzari

Modeling the chemical, electric, and thermal transport as well as phase transitions and the accompanying mesoscale microstructure evolution within a material in an electronic device setting involves the solution of partial differential…

数值分析 · 数学 2024-09-26 Xiaofeng Xu , Lian Zhang , Yin Shi , Long-Qing Chen , Jinchao Xu

Electrostatic forces play many important roles in molecular biology, but are hard to model due to the complicated interactions between biomolecules and the surrounding solvent, a fluid composed of water and dissolved ions. Continuum model…

数值分析 · 数学 2015-12-29 Jaydeep P. Bardhan , Matthew G. Knepley

This article is the second in a series of two papers concerning the mathematical study of a boundary integral equation of the second kind that describes the interaction of $N$ dielectric spherical particles undergoing mutual polarisation.…

数值分析 · 数学 2020-08-11 Bérenger Bramas , Muhammad Hassan , Benjamin Stamm

Understanding the behavior of biomolecules such as proteins requires understanding the critical influence of the surrounding fluid (solvent) environment--water with mobile salt ions such as sodium. Unfortunately, for many studies, fully…

软凝聚态物质 · 物理学 2015-05-27 J. P. Bardhan , D. A. Tejani , N. S. Wieckowski , A. Ramaswamy , M. G. Knepley

We show that charge-sign-dependent asymmetric hydration can be modeled accurately using linear Poisson theory but replacing the standard electric-displacement boundary condition with a simple nonlinear boundary condition. Using a single…

化学物理 · 物理学 2015-06-23 Jaydeep P. Bardhan , Matthew G. Knepley

We present an efficient numerical method, inspired by transformation optics, for solving the Poisson equation in complex and arbitrarily shaped geometries. The approach operates by mapping the physical domain to a uniform computational…

数值分析 · 数学 2026-02-03 Deepak Gautam , Bhooshan Paradkar

This paper is concerned with boundary integral equation methods for solving the two-dimensional fluid-solid interaction problem. We reduce the problem to three differential systems of boundary integral equations via direct and indirect…

数值分析 · 数学 2016-09-01 Tao Yin , George C. Hsiao , Liwei Xu

The Poisson-Boltzmann equation offers an efficient way to study electrostatics in molecular settings. Its numerical solution with the boundary element method is widely used, as the complicated molecular surface is accurately represented by…

数值分析 · 数学 2021-08-25 Stefan D. Search , Christopher D. Cooper , Elwin van't Wout

A numerical method using implicit surface representations is proposed to solve the linearized Poisson-Boltzmann equations that arise in mathematical models for the electrostatics of molecules in solvent. The proposed method used an implicit…

数值分析 · 数学 2018-04-04 Yimin Zhong , Kui Ren , Richard Tsai

The ion distribution around charged colloids in solution has been investigated intensely during the last decade. However, few theoretical approaches have included the influence of variation in the dielectric permittivity within the system,…

软凝聚态物质 · 物理学 2015-06-18 Florian Fahrenberger , Zhenli Xu , Christian Holm

We study the geometric particle-in-cell methods for an electrostatic hybrid plasma model. In this model, ions are described by the fully kinetic equations, electron density is determined by the Boltzmann relation, and space-charge effects…

数值分析 · 数学 2026-03-26 Yingzhe Li

We present in detail three different quasi-Newton isogeometric algorithms for the treatment of free boundary problems. Two algorithms are based on standard Galerkin formulations, while the third is a fully-collocated scheme. With respect to…

数值分析 · 数学 2018-03-15 Monica Montardini , Filippo Remonato , Giancarlo Sangalli

Computational modeling and simulation of fluid-structure interactions constitute a fundamental cornerstone for advancing aerospace engineering endeavors. This paper addresses the notion and implementation of the immersed boundary method for…

计算物理 · 物理学 2025-12-24 Longqing Ge , Qingdong Cai , Yonghao Zhang , Tianbai Xiao

An integral equation method is presented for the 1D steady-state Poisson-Nernst-Planck equations modeling ion transport through membrane channels. The differential equations are recast as integral equations using Green's 3rd identity…

数值分析 · 数学 2023-04-11 Zhen Chao , Weihua Geng , Robert Krasny

This paper presents a general and robust method for the fluid-structure interaction of membranes and shells undergoing large displacement and large added-mass effects by coupling an immersed-boundary method with a shell finite-element…

流体动力学 · 物理学 2023-08-15 Marin Lauber , Gabriel D. Weymouth , Georges Limbert
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