相关论文: Negative specific heats: where Clausius and Boltzm…
It is shown that there is no proof of negativity of specific heat of the system placed in thermostat. It is proved that for the system of particles placed in the thermostat and interacting with each other via uniform potential energy the…
The second Tisza-Callen postulate of equilibrium thermodynamics states that for any system exists a function of the system's extensive parameters, called entropy, defined for all equilibrium states and having the property that the values…
Recently a novel concise representation of the probability distribution of heat conducting nonequilibrium steady states was derived. The representation is valid to the second order in the ``degree of nonequilibrium'', and has a very…
We study a class of nonequilibrium lattice models which describe local redistributions of a globally conserved energy. A particular subclass can be solved analytically, allowing to define a temperature T_{th} along the same lines as in the…
We consider the generic model of a finite-size quantum electron system connected to two (temperature and particle) reservoirs. The quantum open system is driven out of equilibrium by the presence of both a temperature and a chemical…
We define correlational (von Neumann) entropy for an individual quantum state of a system whose time-independent hamiltonian contains random parameters and is treated as a member of a statistical ensemble. This entropy is representation…
The nonequilibrium thermodynamics of an open (classical or quantum) system in strong contact with a single heat bath can be conveniently described in terms of the Hamiltonian of mean force. However, the conventional formulation is limited…
The Boltzmann factor comes from the linear change in entropy of an infinite heat bath during a local fluctuation; small systems have significant nonlinear terms. We present theoretical arguments, experimental data, and Monte-Carlo…
Use of the extended definition of heat dQ=deQ+diQ converts the Clausius inequality dS greater than or equal to deQ/T0 into an equality dS=dQ/T involving the nonequilibrium temperature T of the system having the conventional interpretation…
Micro-calorimetry offers significant potential as a quantitative method for studying the structure and function of biological systems, for instance, by probing the excess heat released by cellular or sub-cellular structures, isothermal or…
Development of steady state thermodynamics and statistical mechanics depends crucially on our ability to develop notions of equilibrium thermodynamics for nonequilibrium steady states (NESS). The present paper considers the development of…
By using freeze-out properties of multifragmenting hot nuclei produced in quasifusion central $^{129}$Xe+$^{nat}$Sn collisions at different beam energies (32, 39, 45 and 50 AMeV) which were estimated by means of a simulation based on…
A key quantity characterizing a time-periodically forced quantum system coupled to a heat bath is the energy flowing in the steady state through the system into the bath, where it is dissipated. We derive a general expression which allows…
We introduce a new theoretical approach to dissipative quantum systems. By means of a continuous sequence of infinitesimal unitary transformations, we decouple the small quantum system that one is interested in from its thermodynamically…
We take the perspective of open quantum systems and examine from their nonequilibrium dynamics the conditions when the physical quantities, their relations and the laws of thermodynamics become well defined and viable for quantum many body…
We study the relationship between (non-)Markovian evolutions, established correlations, and the entropy production rate. We consider a system qubit in contact with a thermal bath and in addition the system is strongly coupled to an…
Thermodynamic uncertainty principles make up one of the few rare anchors in the largely uncharted waters of nonequilibrium systems, the fluctuation theorems being the more familiar. In this work we aim to trace the uncertainties of…
The proper definition of entropy is fundamental to the relationship between statistical mechanics and thermodynamics. It also plays a major role in the recent debate about the validity of the concept of negative temperature. In this paper,…
The difference between the zero-mass limit of the heat exchanged with a thermal reservoir, and its value as determined from overdamped dynamics, is termed `heat leakage' or `hidden heat' in the Smoluchowski limit. If present, heat leakages…
The housekeeping heat is the energy exchanged between a system and its environment in a nonequilibrium process that results from the violation of detailed balance. We describe fluctuations of the housekeeping heat in mesoscopic systems…