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We address questions posed by experiments which show that most small-chain alcohols reduce the miscibility transition temperature when added to giant plasma membrane vesicles, but increase that temperature when added to giant unilamellar…

统计力学 · 物理学 2017-11-22 D. W. Allender , M. Schick

We have investigated the dynamics of water confined in mesostructured porous silicas (SBA-15, MCM-41) and four periodic mesoporous organosilicas (PMOs) by dielectric relaxation spectroscopy. The influence of water-surface interaction has…

We have investigated the dynamics of liquid water confined in mesostructured porous silica (MCM-41) and periodic mesoporous organosilicas (PMOs) by incoherent quasielastic neutron scattering experiments. The effect of tuning the…

Room temperature ionic liquids (ILs) at solid surfaces have been recognized for their significant interfacial properties in electrochemical and electronic devices. To ascertain the interface effects, we investigate dynamical and structural…

化学物理 · 物理学 2017-10-27 Tamisra Pal , Constantin Beck , Dominik Lessnich , Michael Vogel

The key parameter controlling the glass transition of colloidal suspensions is $\varphi$, the fraction of the sample volume occupied by the particles. Unfortunately, changing $\varphi$ by varying an external parameter, \textit{e.g.}…

软凝聚态物质 · 物理学 2022-04-20 J. S. Behra , A. Thiriez , D. Truzzolillo , L. Ramos , L. Cipelletti

In this paper, we investigated the annealing experiments of poly(mercaptopropylmethylsiloxane, PMMS) confined within two types of porous templates (anodic aluminium oxide, AAO, and silica) characterized by different pore diameter, d=…

介观与纳米尺度物理 · 物理学 2023-07-19 Sara Zimny , Magdalena Tarnacka , Monika Geppert-Rybczyńska , Kamil Kamiński

We perform systematic molecular dynamics simulations of water confined between two nanoscale plates at T=300 K. We investigate the effect of pressure (-0.15 GPa <= P <= 0.2 GPa) and plate separation (0.4 nm <= d <= 1.6 nm) on the phase…

化学物理 · 物理学 2016-09-08 Nicolas Giovambattista , Peter J. Rossky , Pablo G. Debenedetti

The confinement of silver selenide was investigated using mesoporous silica. Results from x-ray diffraction and electron microscopy show that the confined material still exhibits a \beta to \alpha transition similar to the one that takes…

材料科学 · 物理学 2009-11-13 Vincent Leon , Yang Ren , Marie-Louise Saboungi

Interfacial interactions significantly alter the fundamental properties of water confined in mesoporous structures, with crucial implications for geological, physicochemical, and biological processes. Herein, we focused on the effect of…

I consider the effect of a small concentration of a molecule, such as a short-chain alcohol, on the miscibility transition temperature of a giant plasma membrane vesicle. For concentrations sufficiently small such that the system can be…

软凝聚态物质 · 物理学 2016-12-21 M. Schick

Lipid structures exhibit complex and highly dynamic lateral structure; and changes in lipid density and fluidity are believed to play an essential role in membrane targeting and function. The dynamic structure of liquids on the molecular…

软凝聚态物质 · 物理学 2016-12-21 Neda Dadashvand , Christina M. Othon

We use molecular dynamics computer simulations and nuclear magnetic resonance experiments to investigate the dynamics of water at interfaces of molecular roughness and low mobility. We find that, when approaching such interfaces, the…

软凝聚态物质 · 物理学 2014-07-22 Markus Rosenstihl , Kerstin Kämpf , Felix Klameth , Matthias Sattig , Michael Vogel

To investigate the effect of wettability on multiphase flow in porous media, hydrophilic glass surfaces are typically modified through a silanization process. This study examines the nanoscale chemical and structural modifications of glass…

In this study, the effect of alumina and modified alumina nanoparticles in a PMMA/alumina nanocomposite was investigated. To attain this goal, the glass transition behavior of poly methyl methacrylate (PMMA), PMMA/alumina and…

材料科学 · 物理学 2018-03-02 Maryam Mohammadi , Jamal Davoodi , Mahdi Javanbakht , Hamidreza Rezaei

The role of interface states and dielectric mismatch is studied in ultrathin P-doped silicon-on-insulator (SOI) films with thickness of the device layer ($H_{SOI}$) varying from 30 to 8 nm and dopant concentration ($n_{D}$) ranging from…

We have studied the temperature induced $0 -\pi $ thermodynamic transition in Nb/PdNi/Nb Superconductor/Ferromagnetic/Superconductor (SFS) heterostructures by microwave measurements of the superfluid density. We have observed a shift in the…

超导电性 · 物理学 2015-12-09 R. Loria , C. Meneghini , K. Torokhtii , L. Tortora , N. Pompeo , C. Cirillo , C. Attanasio , E. Silva

Seismology of stars is strongly developing. To address this question we have formed an international collaboration OPAC to perform specific experimental measurements, compare opacity calculations and improve the opacity calculations in the…

In the present work, we employ broadband dielectric spectroscopy to study the molecular dynamics of the prototypical glass former glycerol confined in two microporous zeolitic imidazolate frameworks (ZIF-8 and ZIF-11) with well-defined pore…

无序系统与神经网络 · 物理学 2019-01-16 M. Uhl , J. K. H. Fischer , P. Sippel , H. Bunzen , P. Lunkenheimer , D. Volkmer , A. Loidl

The detailed nature of spatially heterogeneous dynamics of glycerol-silica nanocomposites is unraveled by combining dielectric spectroscopy with atomistic simulation and statistical mechanical theory. Analysis of the spatial mobility…

Atomic diffusion at nanometer length scale may differ significantly from bulk diffusion, and may sometimes even exhibit counterintuitive behavior. In the present work, taking Cu/Ni as a model system, a general phenomenon is reported which…

材料科学 · 物理学 2019-05-15 Atul Tiwari , M. K. Tiwari , Mukul Gupta , H. -C. Wille , Ajay Gupta
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