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This article is concerned with the numerical solution of subspace optimization problems, consisting of minimizing a smooth functional over the set of orthogonal projectors of fixed rank. Such problems are encountered in particular in…

数值分析 · 数学 2022-10-17 Eric Cancès , Gaspard Kemlin , Antoine Levitt

The complete active space self-consistent field (CASSCF) method is the principal approach employed for studying strongly correlated systems. However, exact CASSCF can only be performed on small active spaces of ~20 electrons in ~20 orbitals…

The thorough treatment of electron-lattice interactions from first principles is one of the main goals in condensed matter physics. While the commonly applied adiabatic Born-Oppenheimer approximation is sufficient for describing many…

Discovery of material properties at extremes, which are essential for high energy density physics development, requires the most advanced experimental facilities, theories, and computations. Nowadays it is possible to model properties of…

等离子体物理 · 物理学 2023-02-28 A. S. Polyukhin , S. A. Dyachkov , P. R. Levashov

A single-term density functional model for nondynamic and strong correlation is presented, based on single-determinant Kohn-Sham density functional theory. It is derived from modeling the adiabatic connection and contains only two nonlinear…

化学物理 · 物理学 2015-12-21 Jing Kong , Emil Proynov

We explore an asymmetric two-fermion Hubbard dimer to test the accuracy of the adiabatic approximation of time-dependent density functional theory in modelling time-resolved charge transfer. We show that the model shares essential features…

化学物理 · 物理学 2014-05-13 Johanna I. Fuks , Neepa T. Maitra

Within many-body perturbation theory, Hedin's formalism offers a systematic way to iteratively compute the self-energy $\Sigma$ of any interacting system, provided one can evaluate the interaction vertex $\Gamma$ exactly. This is however…

化学物理 · 物理学 2022-11-04 Carlos Mejuto-Zaera , Vojtěch Vlček

This thesis considers out-of-equilibrium dynamics of strongly interacting non-relativistic Fermi gases in several two and three dimensional geometries. The tools of second-order hydrodynamics and gauge-gravity duality will be utilized to…

量子气体 · 物理学 2018-04-30 William Lewis

Under the second-order degenerate perturbation theory, we show that the physics of $N$ particles with arbitrary spin confined in a one dimensional trap in the strongly interacting regime can be described by super-exchange interaction. An…

量子气体 · 物理学 2015-04-30 Li Yang , Liming Guan , Han Pu

Semilocal exchange-correlation functionals are the most accurate, realistic and widely used ones to describe the complex many-electron effects of two-dimensional quantum systems. Beyond local density approximation, the generalized gradient…

材料科学 · 物理学 2017-04-12 Subrata Jana , Prasanjit samal

Continuous glucose monitoring (CGM) generates dense data streams critical for diabetes management, but most used forecasting models lack interpretability for clinical use. We present SSM-CGM, a Mamba-based neural state-space forecasting…

机器学习 · 计算机科学 2025-10-07 Shakson Isaac , Yentl Collin , Chirag Patel

We explore the simplification of widely used meta-generalized-gradient approximation (mGGA) exchange-correlation functionals to the Laplacian level of refinement by use of approximate kinetic energy density functionals (KEDFs). Such…

化学物理 · 物理学 2017-12-01 Daniel Mejia-Rodriguez , S. B. Trickey

Qualitatively incorrect results are obtained for the Mn dimer in density functional theory calculations using the generalized gradient approximation (GGA) and similar results are obtained from local density and meta-GGA functionals. The…

化学物理 · 物理学 2021-05-18 Aleksei V. Ivanov , Tushar K. Ghosh , Elvar Ö. Jónsson , Hannes Jónsson

The Adiabatic Connection Integrand Interpolation (ACII) method represents a general path for calculating correlation energies in electronic systems within the Den sity Functional Theory. ACII functionals include both exact-exchange and the…

材料科学 · 物理学 2024-03-13 Lucian A. Constantin , Szymon Śmiga , Fabio Della Sala

The correlation energy in density functional theory can be expressed exactly in terms of the change in the probability of finding two electrons at a given distance $r_{12}$ (intracule density) when the electron-electron interaction is…

其他凝聚态物理 · 物理学 2017-08-23 Paola Gori-Giorgi , Michael Seidl , Andreas Savin

Our general interest is in self-consistent-field (scf) theories of disordered fermions. They generate physically relevant sub-ensembles ("scf-ensembles") within a given Altland-Zirnbauer class. We are motivated to investigate such ensembles…

无序系统与神经网络 · 物理学 2020-04-22 Matthias Stosiek , Bruno Lang , Ferdinand Evers

Interacting electrons in a semiconductor quantum dot at strong magnetic fields exhibit a rich set of states, including correlated quantum fluids and crystallites of various symmetries. We develop in this paper a perturbative scheme based on…

介观与纳米尺度物理 · 物理学 2007-05-23 Gun Sang Jeon , Chia-Chen Chang , Jainendra K. Jain

We introduce a size-consistent and orbital-invariant formalism for constructing correlation functionals based on the adiabatic connection for density functional theory (DFT). By constructing correlation energy matrices for the weak and…

化学物理 · 物理学 2025-11-05 Kyle Bystrom , Timothy C. Berkelbach

In the self-consistent continuum solvation (SCCS) approach ($\textit{J. Chem. Phys.}$ 136, 064102 (2012)), the analytical expressions of the local solute-solvent interface functions determine the interface function and dielectric function…

化学物理 · 物理学 2024-07-31 Ziwei Chai , Sandra Luber

The asymmetric quantum Rabi model (AQRM), which describes the interaction between a quantum harmonic oscillator and a biased qubit, arises naturally in circuit quantum electrodynamic circuits and devices. The existence of hidden symmetry in…

量子物理 · 物理学 2021-09-10 Zi-Min Li , Devid Ferri , David Tilbrook , Murray T. Batchelor