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The nucleation of graphene on a transition metal (TM) surface, either on a terrace or near a step edge, is systematically explored using density functional theory (DFT) calculations and applying the two-dimensional (2D) crystal nucleation…

材料科学 · 物理学 2011-04-04 Junfeng Gao , Joanne Yip , Jijun Zhao , Boris I. Yakobson , Feng Ding

The properties of polycrystalline materials are often dominated by the size of their grains and by the atomic structure of their grain boundaries. These effects should be especially pronounced in 2D materials, where even a line defect can…

Precise control over thin film morphology is critical for optimizing material properties across diverse technological applications, as the growth mode (whether 2D layer-by-layer or 3D island formation)determines key functional properties…

材料科学 · 物理学 2025-11-21 Samuel Aldana , Michael Nolan

The strong interest in graphene has motivated the scalable production of high quality graphene and graphene devices. Since large-scale graphene films synthesized to date are typically polycrystalline, it is important to characterize and…

In crystal growth, surfactants are additive molecules used in dilute amount or as dense, permeable layers to control surface morphologies. Here, we investigate the properties of a strikingly different surfactant: a two-dimensional and…

We report on a large improvement in the wetting of Al2O3 thin films grown by un-seeded atomic layer deposition on monolayer graphene, without creating point defects. This enhanced wetting is achieved by greatly increasing the nucleation…

材料科学 · 物理学 2014-11-14 Bruno Dlubak , Piran R. Kidambi , Robert S. Weatherup , Stephan Hofmann , John Robertson

Gallium nitride nanowire and nanorod substrates with different morphology are prospective platforms allowing to control the local strain distribution in graphene films top of them, resulting in an induction of pseudomagnetic fields. Atomic…

Control of water ice formation on surfaces is of key technological and economic importance, but the fundamental understanding of ice nucleation and growth mechanisms and the design of surfaces for controlling water freezing behaviour remain…

We show the merits of plasma enhanced atomic layer deposition (PEALD) of catalytic substrate for chemical vapour deposition (CVD) graphene growth. The high quality multilayer graphene (MLG) on molybdenum carbide ($MoC_{x}$) thin film…

应用物理 · 物理学 2019-12-06 Eldad Grady , W. M. M. Kessels , Ageeth A. Bol

Graphene, a hexagonal sheet of $sp^2$-bonded carbon atoms, has extraordinary properties which hold immense promise for future nanoelectronic applications. Unfortunately, the popular preparation methods of micromechanical cleavage and…

介观与纳米尺度物理 · 物理学 2015-05-20 Andrew Zangwill , Dimitri D. Vvedensky

Atomically thin, perforated graphene on $c$-plane sapphire functions as a nanoscale mask that enables GaN growth through thru-holes. We tune the perforated-area fraction $f_p$ by controlled O$_2$-plasma exposure and quantify its impact on…

材料科学 · 物理学 2025-09-11 Su Young An , Chinkyo Kim

The remarkable electronic properties of graphene have fueled the vision of a graphene-based platform for lighter, faster and smarter electronics and computing applications. One of the challenges is to devise ways to tailor its electronic…

We have demonstrated that the island nucleation in the initial stage of epitaxial thin film growth can be tuned by substrate surface charge doping. This charge effect was investigated using spin density functional theory calculation in…

材料科学 · 物理学 2015-06-19 Wenmei Ming , Feng Liu

Atomic modulations of two-dimensional materials using scanning tunneling microscope (STM) tip-induced forces modifies their mechanical and electrical properties. In situ topographic and spectroscopic probing through electrical tunneling has…

材料科学 · 物理学 2022-02-02 N. Sarkar , P. R. Bandaru , R. C. Dynes

As undesirable defects, grain boundaries (GBs) are widespread in epitaxial graphene using existing growth methods on metal substrates. Employing density functional theory calculations, we first identify that the misorientations of carbon…

材料科学 · 物理学 2015-06-03 Wei Chen , Hua Chen , Haiping Lan , Ping Cui , Tim P. Schulze , Wenguang Zhu , Zhenyu Zhang

We delineate a general theoretical framework to determine the substrate-regulated graphene morphology through energy minimization. We then apply such a framework to study the graphene morphology on a substrate with periodic surface grooves.…

材料科学 · 物理学 2010-02-05 Teng Li , Zhao Zhang

Two experimental studies reported the spontaneous formation of amorphous and crystalline structures of C60 intercalated between graphene and a substrate. They observed interesting phenomena ranging from reaction between C60 molecules under…

介观与纳米尺度物理 · 物理学 2019-10-21 Alexandre F. Fonseca , Sócrates O. Dantas , Douglas S. Galvão , Difan Zhang , Susan B. Sinnott

Pristine, single-crystalline graphene displays a unique collection of remarkable electronic properties that arise from its two-dimensional, honeycomb structure. Using in-situ low-energy electron microscopy, we show that when deposited on…

The recent emergence of strain gradient engineering directly affects the nanomechanics, optoelectronics and thermal transport fields in 2D materials. More specifically, large suspended graphene under very high stress represents the…

We demonstrate high-resolution modification of suspended multi-layer graphene sheets by controlled exposure to the focused electron beam of a transmission electron microscope. We show that this technique can be used to realize, on…

介观与纳米尺度物理 · 物理学 2009-11-13 Michael D. Fischbein , Marija Drndic
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