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When liquids are cooled sufficiently rapidly below their melting temperature, they may bypass crystalization and, instead, enter a long-lived metastable supercooled state that has long been the focus of intense research. Although they…

统计力学 · 物理学 2023-12-05 Zohar Nussinov

The problem of metastability for a stochastic dynamics with a parallel updating rule is addressed in the Freidlin--Wentzel regime, namely, finite volume, small magnetic field, and small temperature. The model is characterized by the…

统计力学 · 物理学 2015-05-13 Emilio N. M. Cirillo , Cristian Spitoni , Francesca R. Nardi

The element of metastability is incorporated in the fluctuating nonlinear hydrodynamic description of the mode coupling theory (MCT) of the liquid-glass transition. This is achieved through the introduction of the defect density variable…

凝聚态物理 · 物理学 2009-10-22 Joonhyun Yeo , Gene F. Mazenko

Water shows intriguing thermodynamic and dynamic anomalies in the supercooled liquid state. One possible explanation of the origin of these anomalies lies in the existence of a metastable liquid-liquid phase transition (LLPT) between two…

统计力学 · 物理学 2016-05-04 Rakesh S. Singh , John W. Biddle , Pablo G. Debenedetti , Mikhail A. Anisimov

We numerically study a nondisordered lattice spin system with a first order liquid-crystal transition, as a model for supercooled liquids and glasses. Below the melting temperature the system can be kept in the metastable liquid phase, and…

统计力学 · 物理学 2009-11-07 Andrea Cavagna , Irene Giardina , Tomas S. Grigera

When we lower the temperature of a liquid, at some point we meet a first order phase transition to the crystal. Yet, under certain conditions it is possible to keep the system in its metastable phase and to avoid crystallization. In this…

统计力学 · 物理学 2009-05-12 Andrea Cavagna

In this paper we analyze a PDE system modelling (non-isothermal) phase transitions and damage phenomena in thermoviscoelastic materials. The model is thermodynamically consistent: in particular, no {\em small perturbation assumption} is…

偏微分方程分析 · 数学 2014-11-20 Elisabetta Rocca , Riccarda Rossi

In this paper we present a new thermodynamically consistent phase transition model describing the evolution of a liquid substance, e.g., water, in a rigid container $\Omega$ when we freeze the container. Since the density $\varrho_{2}$ of…

偏微分方程分析 · 数学 2014-01-10 Michel Fremond , Elisabetta Rocca

Stochastic systems often exhibit multiple viable metastable states that are long-lived. Over very long timescales, fluctuations may push the system to transition between them, drastically changing its macroscopic configuration. In realistic…

统计力学 · 物理学 2023-04-14 Tobias Grafke , Alessandro Laio

This thesis consists of two separate parts: in each we study the stability under small perturbations of certain probability models in different contexts. In the first, we study small random perturbations of a deterministic dynamical system…

概率论 · 数学 2017-03-21 Santiago Saglietti

This paper extends our earlier studies of free energy functions of density and crystalline order parameters for models of supercooled water, which allows us to examine the possibility of two distinct metastable liquid phases [J. Chem. Phys.…

统计力学 · 物理学 2015-06-15 David T. Limmer , David Chandler

Metastability is a physical phenomenon ubiquitous in first order phase transitions. A fruitful mathematical way to approach this phenomenon is the study of rare transitions Markov chains. For Metropolis chains associated with Statistical…

概率论 · 数学 2015-09-30 Emilio Cirillo , Francesca Nardi , Julien Sohier

In many mean-field glassy systems, the low-temperature Gibbs measure is dominated by exponentially many metastable states. We analyze the evolution of the metastable states as temperature changes adiabatically in the solvable case of the…

无序系统与神经网络 · 物理学 2012-07-09 YiFan Sun , Andrea Crisanti , Florent Krzakala , Luca Leuzzi , Lenka Zdeborová

We discuss metastable states in the mean-field version of the strong coupling BCS-model and study the evolution of a superconducting equilibrium state subjected to a dynamical semi-group with Lindblad generator in detailed balance w.r.t.…

数学物理 · 物理学 2009-11-07 Joris Lauwers , Andre Verbeure

This is the second part of our series of papers on metastability results for parabolic equations with drift. The aim is to present a self-contained study, using partial differential equations methods, of the metastability properties of…

偏微分方程分析 · 数学 2020-04-21 Hitoshi Ishii , Panagiotis E. Souganidis

A liquid can exist under conditions of thermodynamic stability or metastability within boundaries defined by the liquid-gas spinodal and the glass transition line. The relationship between these boundaries has been investigated previously…

软凝聚态物质 · 物理学 2009-11-11 S. S. Ashwin , Gautam I. Menon , Srikanth Sastry

Metastability in open system dynamics describes the phenomena of initial relaxation to longlived metastable states before decaying to the asymptotic stable states. It has been predicted in continuous-time stochastic dynamics of both…

量子物理 · 物理学 2024-04-10 Yuan-De Jin , Chu-Dan Qiu , Wen-Long Ma

We introduce the concept of stationary metastable states (SMS's) in the presence of another more stable state. The stationary nature allows us to study SMS's by using a restricted partition function formalism as advocated by Penrose and…

统计力学 · 物理学 2007-05-23 P. D. Gujrati

We consider a strongly nonlinear PDE system describing solid-solid phase transitions in shape memory alloys. The system accounts for the evolution of an order parameter (related to different symmetries of the crystal lattice in the phase…

偏微分方程分析 · 数学 2013-07-08 Elena Bonetti , Pierluigi Colli , Mauro Fabrizio , Gianni Gilardi

The local equilibrium thermodynamics is a basic assumption of macroscopic descriptions of the out of equilibrium dynamics for Hamiltonian systems. We numerically analyze the Hamiltonian Potts model in two dimensions to study the violation…

统计力学 · 物理学 2023-06-21 Michikazu Kobayashi , Naoko Nakagawa , Shin-ichi Sasa
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