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The probability distribution of a function of a subsystem conditioned on the value of the function of the whole, in the limit when the ratio of their values goes to zero, has a limit law: It equals the unconditioned marginal probability…

数学物理 · 物理学 2021-01-18 Yu-Chen Cheng , Hong Qian , Yizhe Zhu

The canonical ensemble describes an open system in equilibrium with a heat bath of fixed temperature. The probability distribution of such a system, the Boltzmann distribution, is derived from the uniform probability distribution of the…

统计力学 · 物理学 2015-06-05 Julian Lee

The standard Large Deviation Theory (LDT) is mathematically illustrated by the Boltzmann-Gibbs factor which describes the thermal equilibrium of short-range-interacting many-body Hamiltonian systems, the velocity distribution of which is…

统计力学 · 物理学 2021-12-24 Ugur Tirnakli , Constantino Tsallis , Nihat Ay

The Boltzmann distribution predicts the collective behavior of systems at thermodynamic equilibrium as a function of their constituent parts. Yet most systems in nature are not at equilibrium, and a unified theory of their behavior does not…

统计力学 · 物理学 2018-10-16 Milo M. Lin

A multicanonical formalism is applied to the problem of statistical equilibrium in a complex system with a hierarchy of dynamical structures. At the small scales the system is in quasi-equilibrium and follows a Maxwell-Boltzmann…

统计力学 · 物理学 2012-08-29 G. L. Vasconcelos , D. S. P. Salazar

The Boltzmann distribution describes a single parameter (temperature) family of probability distributions over a state space; at any given temperature, the ratio of probabilities of two states depends on their difference in energy. The same…

The Boltzmann distribution (the most probable distribution) is one of the most important concepts used in physics, chemistry and biology. Suppose we put the system initially in one of the less probable state then the system will find the…

统计力学 · 物理学 2015-09-23 Aniruddha Chakraborty

In ordinary statistical mechanics the Boltzmann-Shannon entropy is related to the Maxwell-Bolzmann distribution $p_i$ by means of a twofold link. The first link is differential and is offered by the Jaynes Maximum Entropy Principle. The…

统计力学 · 物理学 2009-10-02 G. Kaniadakis

We propose a general approach, named by us hyperstatistics, to treat complex systems, in which Boltzmann-Gibbs statistics breaks down in domains of the system. Hyperstatistics preserves the concavity of nonadditive $q$-entropy. We obtain…

统计力学 · 物理学 2026-04-29 Lucas Squillante , Samuel M. Soares , Constantino Tsallis , Mariano de Souza

It is shown that time reversibility of Hamiltonian microscopic dynamics and Gibbs canonical statistical ensemble of initial conditions for it together produce an exact virial expansion for probability distribution of path of molecular…

统计力学 · 物理学 2008-03-04 Yu. E. Kuzovlev

Boltzmann's principleS=k*ln W is generalized to non-equilibrium Hamiltonian systems with possibly fractal distributions in phase space by the box-counting volume. The probabilities P(M) of macroscopic observables M are given by the ratio…

统计力学 · 物理学 2007-05-23 D. H. E. Gross

Starting from microcanonical basis with the principle of equal a priori probability, it is found that, besides ordinary Boltzmann-Gibbs theory with the exponential distribution, a theory describing systems with power-law distributions can…

统计力学 · 物理学 2009-10-31 Sumiyoshi Abe , and A. K. Rajagopal

Boltzmann's principle is used to select the "most probable" realization (macrostate) of an isolated or closed thermodynamic system, containing a small number of particles ($N \llsp \infty$), for both classical and quantum statistics. The…

统计力学 · 物理学 2015-05-13 Robert K. Niven

We determine the asymptotic distribution of the sum of correlated variables described by a matrix product ansatz with finite matrices, considering variables with finite variances. In cases when the correlation length is finite, the law of…

统计力学 · 物理学 2014-01-08 Florian Angeletti , Eric Bertin , Patrice Abry

Tsallis has suggested a nonextensive generalization of the Boltzmann-Gibbs entropy, the maximization of which gives a generalized canonical distribution under special constraints. In this brief report we show that the generalized canonical…

统计力学 · 物理学 2021-04-28 Brian R. La Cour , William C. Schieve

Superstatistics generalizes Boltzmann statistics by assuming spatio-temporal fluctuations of the intensive variables. It has many applications in the analysis of experimental and simulated data. The fluctuation of the intensity variable is…

统计力学 · 物理学 2024-06-21 Shaohua Guan , Qiang Chang , Wen Yao

The main interest of the present work is the generalization of the Boltzmann-Gibbs distributions and the fluctuation theory based on the consideration of the reparametrization invariance of the microcanonical ensemble. This approach allows…

统计力学 · 物理学 2007-05-23 L. Velazquez

The family of Boltzmann distributions is used in statistical mechanics to describe the distribution of states in systems with a given temperature. We give a novel characterization of this family as the unique one satisfying independence for…

概率论 · 数学 2025-08-07 Fedor Sandomirskiy , Omer Tamuz

The paper demonstrates that the canonical probability distribution of the occupancy numbers of a bosonic system is multinomial, and shows how the thermodynamics of the canonical system descends from this distribution. The categorical…

统计力学 · 物理学 2025-11-25 Arnaldo Spalvieri

A multicanonical formalism is introduced to describe statistical equilibrium of complex systems exhibiting a hierarchy of time and length scales, where the hierarchical structure is described as a set of nested "internal heat reservoirs"…

统计力学 · 物理学 2012-11-15 Domingos S. P. Salazar , Giovani L. Vasconcelos
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