相关论文: Multiple Superadiabatic Transitions and Landau-Zen…
We consider non-adiabatic transitions in multiple dimensions, which occur when the Born-Oppenheimer approximation breaks down. We present a general, multi-dimensional algorithm which can be used to accurately and efficiently compute the…
We explain the concept of superadiabatic approximations and show how in the context of the Born- Oppenheimer approximation they lead to an explicit formula that can be used to predict transitions at avoided crossings. Based on this formula,…
The approach by Ettore Majorana for non-adiabatic transitions between two quasi-crossing levels is revisited. We rederive the transition probability, known as the Landau-Zener-St\"{u}ckelberg-Majorana formula, and introduce Majorana's…
A class of surface hopping algorithms is studied comparing two recent Landau-Zener (LZ) formulas for the probability of nonadiabatic transitions. One of the formulas requires a diabatic representation of the potential matrix while the other…
We study the S-matrix for the transitions at an avoided crossing of several energy levels, which is a multilevel generalization of the Landau-Zener problem. We demonstrate that, by extending the Schroedinger evolution to complex time, one…
We study non--adiabatic transitions in scattering theory for the time dependent molecular Schroedinger equation in the Born--Oppenheimer limit. We assume the electron Hamiltonian has finitely many levels and consider the propagation of…
The Landau-Zener formula provides the probability of non-adiabatic transitions occuring when two energy levels are swept through an avoided crossing. The formula is derived here in a simple calculation that emphasizes the physics…
We study a two-level transition probability for a finite number of avoided crossings with a small interaction. Landau-Zener formula, which gives the transition probability for one avoided crossing as $e^{-\pi\frac{\varepsilon^{2}}{h}}$,…
In the paper we derive a semiclassical model for surface hopping allowing quantum dynamical non-adiabatic transition between different potential energy surfaces in which cases the classical Born-Oppenheimer approximation breaks down. The…
We study superadiabatic quantum control of a three-level quantum system whose energy spectrum exhibits multiple avoided crossings. In particular, we investigate the possibility of treating the full control task in terms of independent…
Non-adiabatic transitions in multilevel systems appear in various fields of physics, but it is not easy to analyze their dynamics in general. In this paper, we propose to extend the adiabatic impulse approximation to multilevel systems.…
We show that a simple approximation based on concepts underlying the Kibble-Zurek theory of second order phase transition dynamics can be used to treat avoided level crossing problems. The approach discussed in this paper provides an…
We investigate the transition of a quantum wave-packet through a one-dimensional avoided crossing of molecular energy levels when the energy levels at the crossing point are tilted. Using superadiabatic representations, and an approximation…
This paper presents analytic formulas for various transition times in the Landau-Zener model. Considerable differences are found between the transition times in the diabatic and adiabatic bases, and between the jump time (the time for which…
The Landau--Zener (LZ) model describes a two-level quantum system that undergoes an avoided crossing. In the adiabatic limit, the transition probability vanishes. An auxiliary control field $H_\text{CD}$ can be reverse-engineered so that…
Non-adiabatic transitions are studied in a spin-boson model with multiple scattering points. In order to generalize the Landau-Zener formula, which describes the case of a single scattering point, we define an ``effective gap'' for a set of…
This work identifies geometric effects on dynamics due to nonadiabatic couplings in Born Oppenheimer systems and provides a systematic method for deriving corrections to mixed quantum-classical methods. Specifically, an exact path integral…
We study the dynamics of a quantum two state system driven through an avoided crossing under the influence of a super Ohmic environment, i.e. a longitudinal as well as a transversal one. The crossing time window, in which relaxation…
Trajectory surface hopping (TSH) is one of the most widely used quantum-classical algorithms for nonadiabatic molecular dynamics. Despite its empirical effectiveness and popularity, a rigorous derivation of TSH as the classical limit of a…
The Landau-Zener transition is a fundamental concept for dynamical quantum systems and has been studied in numerous fields of physics. Here we present a classical mechanical model system exhibiting analogous behaviour using two inversely…