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Absorbing boundary conditions in the form of a complex absorbing potential are routinely introduced in the Schr\"odinger equation to limit the computational domain or to study reactive scattering events using the multi-configurational…

量子物理 · 物理学 2013-05-29 Simen Kvaal

The multi-layer multi-configurational time-dependent Hartree (MCTDH) in optimized second quantization representation (oSQR) approach combines the tensor contraction scheme of the multi-layer MCTDH approach with the use of an optimized…

化学物理 · 物理学 2020-02-19 Thomas Weike , Uwe Manthe

The multiconfigurational time-dependent Hartree method (MCTDH) [Chem. Phys. Lett. {\bf 165}, 73 (1990); J. Chem. Phys. {\bf 97}, 3199 (1992)] is celebrating nowadays entering its third decade of tackling numerically-exactly a broad range of…

We introduce and describe the multiconfigurational time-depenent Hartree for indistinguishable particles (MCTDH-X) software. This powerful tool allows the investigation of ground state properties and dynamics of interacting quantum…

In this Colloquium, the wavefunction-based Multiconfigurational Time-Dependent Hartree approaches to the dynamics of indistinguishable particles (MCTDH-F for Fermions and MCTDH-B for Bosons) are reviewed. MCTDH-B and MCTDH-F or, together,…

The multilayer multiconfiguration time-dependent Hartree (ML-MCTDH) method and the density matrix renormalization group (DMRG) are powerful workhorses applied mostly in different scientific fields. Although both methods are based on tensor…

化学物理 · 物理学 2024-09-05 Henrik R. Larsson

We apply the multiconfigurational time-dependent Hartree method for indistinguishable particles (MCTDH-X) to systems of bosons or fermions in lattices described by Hubbard type Hamiltonians with long-range or short-range interparticle…

量子气体 · 物理学 2016-07-27 Axel U. J. Lode , Christoph Bruder

A matrix product state formulation of the multiconfiguration time-dependent Hartree (MPS-MCTDH) theory is presented. The Hilbert space that is spanned by the direct products of the phonon degree of freedoms, which is linearly parameterized…

化学物理 · 物理学 2018-11-26 Yuki Kurashige

We compare exponential-type integrators for the numerical time-propagation of the equations of motion arising in the multi-configuration time-dependent Hartree-Fock method for the approximation of the high-dimensional multi-particle…

数值分析 · 数学 2019-05-15 Winfried Auzinger , Alexander Grosz , Harald Hofstätter , Othmar Koch

The multilayer multiconfiguration time-dependent Hartree (ML-MCTDH) method is discussed and a fully general implementation for any number of layers based on the recursive ML-MCTDH algorithm given by Manthe [J. Chem. Phys. {\bf 128}, 164116…

化学物理 · 物理学 2011-02-02 Oriol Vendrell , Hans-Dieter Meyer

We develop the multi-layer multi-configuration time-dependent Hartree method for bosons (ML-MCTDHB), a variational numerically exact ab-initio method for studying the quantum dynamics and stationary properties of bosonic systems. ML-MCTDHB…

计算物理 · 物理学 2013-10-21 Lushuai Cao , Sven Krönke , Oriol Vendrell , Peter Schmelcher

This work presents a computational framework for studying reaction dynamics via wavepacket propagation, employing the multiconfiguration time-dependent Hartree (MCTDH) method and its multilayer extension (ML-MCTDH) as the core…

化学物理 · 物理学 2025-07-09 Xingyu Zhang , Qingyong Meng

In this paper the multiconfigurational time-dependent Hartree for bosons method (MCTDHB) is derived for the case of $N$ identical bosons with internal degrees of freedom. The theory for bosons with internal degrees of freedom constitutes a…

量子气体 · 物理学 2016-06-08 Axel U. J. Lode

In this paper we motivate, formulate and analyze the Multi-Configuration Time-Dependent Hartree-Fock (MCTDHF) equations for molecular systems under Coulomb interaction. They consist in approximating the N-particle Schrodinger wavefunction…

数学物理 · 物理学 2015-05-13 C. Bardos , I. Catto , N. Mauser , S. Trabelsi

Modeling the non-equilibrium dissipative dynamics of strongly interacting quantized degrees of freedom is a fundamental problem in several branches of physics and chemistry. We implement a quantum state trajectory scheme for solving…

量子物理 · 物理学 2023-03-17 Johan F. Triana , Felipe Herrera

To solve the many-boson Schr\"odinger equation we utilize the Multiconfigurational time-dependent Hartree method for bosons (MCTDHB). To be able to attack larger systems and/or to propagate the solution for longer times, we implement a…

量子气体 · 物理学 2011-04-19 Alexej I. Streltsov , Kaspar Sakmann , Ofir E. Alon , Lorenz S. Cederbaum

The purpose of the present Comment is to point out the connection between an approach to spawning and regularization that was recently introduced by D. Mendive-Tapia and H.-D. Meyer [J. Chem. Phys. 153, 234114 (2020)] in the context of the…

量子物理 · 物理学 2021-02-25 Rocco Martinazzo , Irene Burghardt

Numerical simulations of quantum spin models are crucial for a profound understanding of many-body phenomena in a variety of research areas in physics. An outstanding problem is the availability of methods to tackle systems that violate…

量子物理 · 物理学 2023-05-31 Fabian Köhler , Rick Mukherjee , Peter Schmelcher

The multiconfiguration time-dependent Hartree-Fock (MCTDHF) method is formulated for treating the coupled electronic and nuclear dynamics of diatomic molecules without the Born- Oppenheimer approximation. The method treats the full…

计算物理 · 物理学 2015-05-27 Daniel J. Haxton , Keith V. Lawler , C. William McCurdy

We report a three-dimensional numerical implementation of multiconfiguration time-dependent Hartree-Fock (MCTDHF) based on a multi-resolution Cartesian grid, with no need to assume any symmetry of molecular structure. We successfully…

计算物理 · 物理学 2016-03-23 Ryohto Sawada , Takeshi Sato , Kenichi L. Ishikawa
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